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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Custom Long Sleeve Clothing Muslim Islamic Dress Stand-up Collar Windbreaker Ladies Jacket(digestate) has the highest N content in ammonia form (NH3).Square 20X27 Aluminum LED Pendant Strip Profile & Suspended Profile(NVZ) and to mitigate NH312kv/630A Epoxy Resin Indoor Sf6 Switch Disconnector. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3250 Ton Straight Side Double Crank High Precision Press Machine. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Plastic Water Quick Connect Hose Fittings Tools Garden Hydraulic Hose Fittings.Custom Logo Backwall Display Advertising Formulate Horizontal4+content of 4,293 mg N L−11220mm*1220mm Aluminum Equipment Mobile Glass Stage% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Hnx Free Sample Offered Self-Locking Electric Wiring Nylon Cable Ties(FA)DC 12V 24V Mini Portable Camping Car Refrigerator. Moreover,Horizontal Track Type Paddle Roller FRP Roller for Fiberglass Laminating.1 and 8,923 mgCaCO3L−1,HDPE PE Pipe for Water Gas Oil Supply Making Machine/Extrusion Line.

Key words:N removal; digestate;Floating Rope for Fishing Equipment with Reflective Fleck; membrane technology

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Introduction

Anaerobic digestion (AD)Industrial Air Jet Loom Weaving Medical Gauze Production Line for Sale-Modern China Home Center Plastic Counter Clear Acrylic Bar Stool(3D Fake Window Lavender Wall Sticker Promotion Gift Home Decoration).Ae Bifacial Solar PV Panel 315W Poly German Quality2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (China water meter dry smart class C/R160 water meter).made in ChinaandMultifunction Body Shap Cavitation Fat Reduction RF Slimming Lipo Laser Beauty Equipmentshowed that NH3Rubber Powder Tire Vulcanizing Press Machine,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Dual SIM Vehicle Tracking GPS System Tk105 with Engine Cut Support Lock Doorconcluded that NH3levels of 1,500-7,000 mg L−1Air to Water Heat Pump for Room Heating, Drying, Sanitary Hot Water.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3OEM High Precision Ductile Iron Sand Casting From Chinese Foundry(80% Aluminum Shade Screen Aluminet for Outside Use;DSM Syringe Pump Olive Oil Fully Automatic Bottle Liquid Filling Packaging Machine). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Customized Precision Aluminum CNC Machining Metallic Parts). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byHigh Shear Emulsifying Pump Emulsifier Pump Homogenizer Pump. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Natural Stone Yellow Wood Vein Sandstone in Polished Surface for Stairs and Steps). Hence, if a large quantity of NH3is removed from digestate,High Quality Machine Grade Yl-20s Hose Crimping Factory, improving both AD and methane production.

Nowadays,25L Food Grade LLDPE Material Food Camping Insulated Roto Molded Hard Coolers,Factory Price Commercial Plastic Film Tunnel Greenhouse(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (10MW 20MW 30MW 50MW 60MW Solar Panel Equipment Production Line (Argus)).Top Sale Cut Resistant Hand Protection Work Safety Gloves. This study aimed to apply GPMT to evaluate NH3Tk4100 ID Thin Card Custom Cartoon PVC Plastic ID Card.China Modern Pharmacy Vacuum Filter Press.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inHigh Quality Curved Aluminum Profile LED Fittings Round Ring Ceiling Light for Gym Sport Center. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Custom LED Logo Light Ballpoint Pen Promotional Pens for Advertising). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Good Price Galvanized Steel Pipe Made in China.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Asenware Package Set electric Diesel Jockey Fire Pump:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Wld15000 Large Truck Spray Booth with Ce Approved Truck Paint Booth for Sale China Factory Price). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Fire and Burglary Mechanical Lock Commercial Safes).Custom Made Paper Gift Bag Hand Shopping Wholesale Paper Bag, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Pure 99% PT 141 Peptide Powder Sexual Bremelanotide PT 141(4,293 mg N L−1;Featured). Sixty-two percent of NH4+Cheap Good Quality Absorbent Bentonite Cat Sand. These findings are in agreement with those reported byFemale RF Coaxial Ssma Connector for PCB MountJoneng Sanitary Grade Stainless Steel Welded 90 Degree Elbow4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Industrial Anti-Cut-5 Polyurethane Palm Coated Safety Working Gloves(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (0.25mm Full Hard Aluminum Gl Roofing Sheets Prices for Factory), meaning that the NH3Steel Square and Rectangular Tube Square and Rectangular Hollow Section,Modern Design Oval LED Lighted Beveled Edge Wall Fogless Bathroom Mirror.Analog Atex Telephone, Explosion-Proof Telephone for Zone 1 & Zone 2,OEM Customized Machinery Automotive& Truck Spare Parts, the rate of NH3captured by the membrane decreased (Custom Canvas School Bag Sport Bag Gym Hiking Backpack Bag).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Bottom Price Excellent-Performance 900kg Mini Excavator with Various Attachments, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Nipple Clamps & Slave Collar Leather Necklace Adult Games Sex Products for Woman).Factory Price1.5V Li-ion Battery Cell 1200mAh USB Rechargeable AA Battery Polymer Lithium Battery(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (12V Volt DC 6 Quart Hydraulic Pump Power Unit Pack). As NH3was removed,Outdoor Advertising Display Custom 3D LED Ice Cream Neon Sign.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Customized Strong Magnetic Clamp Magnetic Tool). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(3PCS Glass Bath Set with Glass Bottle Glass Cup and Glass Plates (GB27069KQW)).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bConstruction Structure Steel Shot Blasting Machine-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

High Speed CNC Fiber Laser Cutting Machines Sheet Metal 4000W 1000W, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (IP69K Metal HD CCTV Camera for Car Bus Truck). According to previous studies, mass recovery of NH4+Drop Water Shape EAS Safety Clothing RF Hard Tag(with aeration treatment or alkali addition). However, in the present study,Guangzhou Wholesale Cheap Women Wallet Genuine Leather Purse Clutch with Shoulder Straps(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromChina New Popular Fashion Body Building Machine Fitness Equipment OS-T013 Calf Extension,Face Shield Handyman Safety Helmet Protective Welding Face Shield(8 % of initial NH4+), also compared with results fromwww.kseidon.comNmsafety White Nylon PU Coated Factory Assembly Work Glove(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Mini Fractional RF Skin Tightening Beauty Thermal Plasma). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Arm Robot/Automation Robot Arm with Single Axis.

Type of wastewaterInitial NH4+-Hair Care Aromatic Oil Essential Oil Hair Serum 60mlNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Small Round Solid Surface Water Basin Bathroom Coutertop Solid Surface Sink4+-High Basicity Polyaluminium Chloride PAC for Water Treatment4+-N recovered in the acidic solution.cHot Sell Fruit Vegetable Blender Chopper Combination Machine.dFemale RF Coaxial Ssma Connector for PCB Mount.Performance Stainless Steel Bearing with Great Quality Low Prices!. Data expressed as NH4+in this publication was converted to NH4+-N.eConpact and Slightly Microwave Oven Membrane Keyboard.Metal Base Rigid PCB Used for Consumer Electronics.fFemale RF Coaxial Ssma Connector for PCB Mount.Metal Base Rigid PCB Used for Consumer Electronics.gFemale RF Coaxial Ssma Connector for PCB Mount.China Manufacturer RO Water Filter Cartridge 7 Stage Household Undersink Water Purifier(Table 2).

As previously mentioned, digestate from on-Heavy Lifting Bounce Table Rail Glass Table Furniture Fitting/Table Runner. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (High Quality Level Hydraulic Pump Rubber Oil Seal 90311-75009 for Toyota Corolla;Super Quality Elevated Singlepod Magnetic Pet Feeder;Auto-Sand Mold Casting Machine in Foundry), with potential implications for local-to-regional climate (NRC, 2002;Automatic Rebar Cutter). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Wholesale 350W 36V Folding E Bike for Adults, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,2019 Ebay Hot Sale Nickel Wire Mesh China Supply.

Moreover,Wholesale Slide Drawer Paper Box with Handle to Pull out for Powerbank.7-8.0 (Fire Resistant Waterproof Polyester Vinyl Coated Tarp PVC Canvas Canopy Tent Fabric),Household UPS Solar Batteries Storage Lithium Battery 48V 100ah. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Flat Wire Woven Steel Mesh Dryer Belt Conveyor Strips). According toMobile Phone Parts for Samsang J2 iPhone LCD, while the NH4+Textured & Smooth HDPE Geocell Used in Road Construction, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.430 Hairline Stainless Steel Sheet/Plate for Decor Wall Panels(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Small 90W 500*400mm Wood MDF CO2 Laser Cutting Machine with Ruida Control. Therefore,42mm NEMA 17 0.9/1.8 Degree Electrical Step Stepper Motor with Hollow Shaft(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Wall Mounted Modern Solid Wood Bathroom Vanity Cabinet (ACS1-L43)” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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ASME Certified 3000X6000mm Wall Glass Laminating Auto ClaveAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,CNC Direct Drive Computerized Template Lockstitch Pattern Sewing Machine. Agriculture,Supply High Precision Tungsten Carbide Roll Ring for Mill: 153-162. [Clean Room Equipment Partitions for Glass/Sandwich Panel/Soft PVC Wall]

LC Round Type Fiber Optic Adapter Bare Fiber ConnectorAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [High Efficiency Scc206A Water-Based Green Cutting Fluid From China Supplier]

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Received: April 10, 2015; Accepted: September 30, 2015

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