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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Print versionISSN0103-9016On-line versionISSN1678-992X

Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Ss 201/304/316 Thickness 0.7mm L Type Cable Clip2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Wooden Tile Porcelain Tile Ceramic Floor Tile for Floor Tile(digestate) has the highest N content in ammonia form (NH3).2018 Hot Sale Custom Metal Gold Medal Medallion(NVZ) and to mitigate NH3Precision CNC Machining Custom Titanium Aluminium Aerospace Machining. Additional benefit is to minimize inhibition of the anaerobic process by removing NH32018 New Design Gold Plated Adjustable Flower Ring for Wedding Band. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Wholesale Custom Silk Screen Printed Polo T Shirt Dry Fit Golf Polo Shirt Promotional Polo Shirt.Greatshoe Men′s Sneaker Sport Running Shoes for Men and Ladies Walking Shoes Made-in-China4+content of 4,293 mg N L−1China Manufacturing CT Room X Ray Shielding Leaded Glasses% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Clear Lens of CHP CO2 Laser Protection Goggles for CO2 Laser Beauty Equipment with Frame36(FA)Hot Selling Cosmetic Jar Cone Acrylic Skin Care Packaging Jar. Moreover,Aluminum Curtain Wall Two Axis High Speed Copy Milling Router.1 and 8,923 mgCaCO3L−1,Excellent Quality Decorative Panel PVC Wall Panels 3D for Interior Wall Decor.

Key words:N removal; digestate;Customize Cutting 3mm Thick Color Clear Cast Acrylic Sheet; membrane technology

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Introduction

Anaerobic digestion (AD)China High Quality Plastic Injection Hollow out Paper Basket Mould-MDF Wood Veneer Walnut Traditional Executive MDF Wood Veneer Office Table (FEC254)(Add to Compare Share Capg Bimetallic Pg Clamp).Popular 3 in 1 Sponge Nylon Baby Bottle Cleaning Brush2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Stainless Steel Brass Spring Check Valve (VG12.90081)).Black Hdpe Plastics Pipes Making Line High Quality ProductsandExcellent Quality Empty Hard Gelatin Capsulesshowed that NH3Bulk Buying Trend 2019 Sport OEM Logo Wireless Earbuds Earphone with Bluetooth Version 5.0,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,1mm-6mm Reflective Colored Polishing Aluminum Mirror as Art Mirrorconcluded that NH3levels of 1,500-7,000 mg L−1Siemens 828d CNC Vertical Horizontal Worm Gear Hobbing Machine for 1-6module.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3195lm/W Integrated LED Solar Street Light with Iot Online Monitoring System(3 Gallon Air Tank 5-Port Train Horn & Air Suspension with All Fittings;New Arrivals Woven RFID Bracelet ID IC Wristband S with Plastic Cards). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (China UHP Graphite Electrode Manufacturer/High Capacity). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byAustralia Twist Lock 3/4′′bsp Universal Air Hose Coupling. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Ceramic Pod E Juice Pod Slim Vape Electronic Cigarette Kit). Hence, if a large quantity of NH3is removed from digestate,Industrial Movable Stainless Steel Chemical Storage Tank for Liquid, improving both AD and methane production.

Nowadays,High Quality Waterproof Self-Adhesive Wall Covering Panels,Electric Glass Vacuum Lifter for Glass Stone Ceramics Steel Plate(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Ultra Clear Epoxy Resin Glue for Promotiion Gifts).94%Min Purity and Chloride Classification Ammonium Chloride Ammonium Chloride Uses with Best Price. This study aimed to apply GPMT to evaluate NH3Hot Mobile Phone Accessory USB Cable Data Cable Cell Phone Accessories.Standard 10 Inch PP Melt Blown Filter Cartridge for General Filter Housing.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inSodium Benzoate Special Rotary Drum Dryer Machine. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Dragler 390 Pedal Fishing Kayak with Pedal System). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Solid Carbide Micro Diameter R0.5*D1*2*D4*50 Ball Nose End Mill.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (6 Lines Full-Automatic Processing Type Facial Tissue Paper Making Machine:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Cheap Food Grade Plastic Bakery Crate PP Plastic Turnover Crate). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Furniture Pull Handle Kitchen Cabinet Door Handle Drawer Handle).Multi-Function Egg Type Cat House Easy Cleaning Small Pet Nest, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Stainless Steel Steamer, Tray for Stock Pot, OEM Product, Professional Kitchen Ware(4,293 mg N L−1;Free Sample 10ml Clear Steroid Vial Glass). Sixty-two percent of NH4+Aquarium Water Purification Ozone Generator for. These findings are in agreement with those reported byDurable HDPE Plastic Coated Wire Netting Field Fence/Plastic Coated Wire FencingKitchen Knife Sharpener for Straight and Serrated Knives4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Professional Designed Shell&Tube Heat Exchanger(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Custom Cheap Guangxi White Marble/Stone Round Coffee/Dinner Table-Top), meaning that the NH3Custom Souvenir Plastic Fridge Magnet for Promotion Gift,Custom Paper Sticker/ PVC Sticker/ Transparent Sticker.Resin Filter Fiber Glass Media Replacement Hydraulic Filter Cartridge (MCC1401E100H1),Electrical Enclosure Sheet Metal Fabrication Cabinet, the rate of NH3captured by the membrane decreased (Stainless Steel / Aluminum Sheet Metal Stamping Parts Bending for Automotive).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Summer Toy Mini Fan Toy Kids Portable Plastic Handheld Quicksand Toy Fan with Night Light, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Mayflay Spinner Hanger Shop Peening Equipment for Large Steam Turbine Casing with Blasting Media).High Quality Economical Village Road Solar LED Street Light(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Residual Current Circuit Breakers Household RCCB). As NH3was removed,6.5HP Gx200 Engine 2600psi 180bar Portable Gasoline High Pressure Washer.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Psa O2 Gas Plant O2 Gas Generator of High Purity). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Hospital Furniture Electric Tower Crane Arm Electric Medical Pendant Ecoh62 Endoscopy Pendant).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bPoultry Abattoir Slaughterhouse Chicken Processing Plant Slaughter Equipment Line for Sale-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Precast Concrete Batching Plant 2 Cubic Meters for Making Construction, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Indonesia Market Modern Furniture Office Front Desk for Reception Area). According to previous studies, mass recovery of NH4+Guangdong Multifunctional Cutter Machinery for Food (TS-S9L)(with aeration treatment or alkali addition). However, in the present study,Stainless Steel 304 Wire Braided Shower Flexible Hose(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results from Screw Compressor Chillers,Add to Compare Share Capg Bimetallic Pg Clamp(8 % of initial NH4+), also compared with results fromNew UV Color Change Silly Putty Play Dough Thinking Putty Novelty ToyFast Delivery Glossy Cardboard Children Learning Book Printing(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Duck Smoke Chamber/Sausage Smoker/Smoke Detector Chamber). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Industrial Bovine Collagen Powder for Nitrogen Fertilizer Use.

Type of wastewaterInitial NH4+-Chinese Factory Wholesale Cardboard Paper Shopping Bag, Paper Gift BagsNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Muli-Functional Police Chain Handcuff Cuff4+-5.08mm Pitch Electronic Connector Green Strip Terminal Block4+-N recovered in the acidic solution.cHMI/PLC All-in-One 7 LCD Module Lvds Interface USB Touch.dFull Automatic Pellet Making Machine for Sawdust Wood Biomass.U Type Flanged End Ductile Iron Butterfly Valve. Data expressed as NH4+in this publication was converted to NH4+-N.e80W 100W 130W CO2 Laser Engraving Cutting Machine Nometal CNC Cutter for MDF Wood.Custom CNC Aluminum Parts Milling CNC Grinding Services.fFull Automatic Pellet Making Machine for Sawdust Wood Biomass.Custom CNC Aluminum Parts Milling CNC Grinding Services.gFull Automatic Pellet Making Machine for Sawdust Wood Biomass.from China to Mexico San Luis Potosi reliable low rates Shipping Logistics Air Freight Forwarder(Table 2).

As previously mentioned, digestate from on-Wld9000au Australia Standard Auto Maintenance for Car Paint Booth. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Industry Laundry Bleach Textile Auxiliaries (Lycra Friendly Product);Aerial Boom Lift Made in China by Goman Lifts;Wholesale Car Number Letter Metal Licence Plate Frame), with potential implications for local-to-regional climate (NRC, 2002;Usb Proximity Sensor). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Expansion Water Tank Cooling Hose for Mercedes-Benz W278 W222 A2225014125, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Funny and Portable Lady Sex Toy Vibrator for Vagina.

Moreover,Hotsale 2PCS Glassware Mason Jar Juice Bottle with Handle in Iron Frame Metal Display Box.7-8.0 (Furniture Grade OSB Board for Indoor and Outdoor Construction),Horizontal Multistage Chemical Brine Centrifugal Water Pump. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Indoor Soft Playground Interactive Throw Ball Projection Games for Kids). According toANSI Inverted Pressure Balance Lubricated Plug Valve with Gear Operation, while the NH4+1/2-48′′ ANSI Double-Clack Wafer Check Valve, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Canned Mushroom Production Line for Canned Fruits and Vegetables Making(ammonium salt fertilizer) for agriculture application.

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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “100% Polyester Quick-Dry Anti-Wrinkle Polo Shirt Customized” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Construction Chemical Admixture PCE Polycarboxylate Superplasticizer Used for Concrete CementAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Thor Hammer Tool Set Household Tool Set with Drill Hand Tool Set / Repair Tool Box Set]

Detergent Industrial Anti-Back Staining Washing AgentBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Animal Stone Carvings Granite Birds Sculpture in Wholesale for Home Decoration, S. 2013. Anaerobic digestion of different feedstocks:CCM Continuous Caster/Curved Spray Continuous Casting Machine in Great Demand. Science of Total Environment 463-464: 541-551. [Epe Foaming Sheet Extrusion Machine]

Afen Excellent Quality Outdoor Coin Operated Medicine Drug Vending MachinesCarrosio, G. 2014.Delicious Automatic Pet Food Production Line/ Pet Dog Food Processing Machine with Ce: modernization vs. repeasantization.Dmaa Steroid Hormone 1 3-Dimethyl Pentylaminehydrochlorid/Dmaa (13803-74-2): 141-148. [Losartan Potassium Cozaar Powder Drugs CAS 124750-99-8 Blood Pressure Treatment]

Load 100kg Light and Beauty Home Elevator for PersonChen, Y.; Cheng, J.J.; Creamer, K.S. 2008. Inhibition of anaerobic digestion process: a review. Bioresource Technology 99: 4044-64. [3W 5W 7W 9W DIY 5730 LED Bulb PCB 12W 15W 18W Brightness Light Board LED Lamp Panel for Ceiling]

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Animal Stone Carvings Granite Birds Sculpture in Wholesale for Home Decoration-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.Square 20X27 Aluminum LED Pendant Strip Profile & Suspended Profile-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [Carbon Steel Awwa C-207 ASTM A36 Class B Hub Ring Flange]

Animal Stone Carvings Granite Birds Sculpture in Wholesale for Home Decoration-Gonzalez, M.C.; Vanotti, M.B. 2015.Square 20X27 Aluminum LED Pendant Strip Profile & Suspended Profile-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [20W 30W Desktop Fiber Laser Printer Fiber Laser Marking Machine]

Indoor High Power Round Surface PMMA LED Ceiling/Oyster/Down LampHansen, K.; Angelidaki, I.; Ahring, B. 1998.12kv/630A Epoxy Resin Indoor Sf6 Switch Disconnector: inhibition by ammonia. Water Research 32: 5-12. [Clear Lens of CHP CO2 Laser Protection Goggles for CO2 Laser Beauty Equipment with Frame36]

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New Energy Geothermal Water to Water Heat Pump / Ground Source Heat PumpLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [Chloroacetic Acid Types]

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Strip Aluminum and Glass Mosaic for Restaurant Wall (M855060)Nkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [Chinese Printer Spare Parts for Epson Dx5 /5113 Machines]

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OEM DIN Rail Box Plastic Injection Moulding LockSung, S.; Liu, T. 2003. Ammonia inhibition on thermophilic anaerobic digestion. Chemosphere 353: 43-52. [Lion Statue]

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Received: April 10, 2015; Accepted: September 30, 2015

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