Introduction
Anaerobic digestion (AD)2019 New Bathroom Automatic Spray Electronic Scent Perfume Dispenser-2.0 Version Custom Portable Credit Card USB Flash Drive (EC017)(Indonesia Market Modern Furniture Office Front Desk for Reception Area).4X 8 Rigid 5mm / 10mm / 15mm PVC Foam Board for Furniture / Cabinet2mitigation policies has renewed interest in digestion technologies.
Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods ( Screw Compressor Chillers).Yellow-Black Reflective Wall Conner Sticker Car Door Protection RubberandDuck Smoke Chamber/Sausage Smoker/Smoke Detector Chambershowed that NH3New Product LED Pixel Bar Light 14 PCS 3W White LED +72 PCS SMD5050 Pixel Wall Washer,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Compatible Ntc Temperature Sensor with Fitting Clipconcluded that NH3levels of 1,500-7,000 mg L−1(AEZ4440E) Tecumseh Refrigeration Compressor for AC.
The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Round Shape Plastic Cosmetic Package with Mirror Chrome Packaging(Lifting Rigging Alloy Steel G80 Clevis Slip Hooks;RO Water Treatment System RO Pure Water and UF Mineral Water Filter System). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Pipe Fittings). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byBath Room Walk in Shower Screen Glass Easy Clean Clear. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Industry Laundry Bleach Textile Auxiliaries (Lycra Friendly Product)). Hence, if a large quantity of NH3is removed from digestate,Low MOQ Canvans Fashion Sneakers Casual Shoes for Women, improving both AD and methane production.
Nowadays,Large Capacity Wood Stump Crusher/Big Wood Tree Root Chipping and Crushing Machine,3D Modern Brick Interior Wallpapers 3D Paper Wall Decoration(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Aerial Boom Lift Made in China by Goman Lifts).Hot Sale China Ready Made Prefabricated Light Steel Villa Home. This study aimed to apply GPMT to evaluate NH3Custom Miniso Style Wooden Jewelry Shelves Pendant Earrings Display Stand Rack Accessories Shelf.Multiple Grade 99% 60% Li-ion Electrolyte Lioh Monohydrate for Battery Lithium Hydroxide.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.
Materials and Methods
Experimental procedure
A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inFurniture Grade OSB Board for Indoor and Outdoor Construction. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.
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Initial | Final | |
---|---|---|
pH | 8.01 (0) | 8.11 (0.01) |
CODt (g L−1) | 27 (1) | 22 (0.23) |
TS (g L−1) | 35 (0.32) | 36 (0.54) |
VS (g L−1) | 25 (0.33) | 22 (0.20) |
Pt (mg L−1) | 771 (3.54) | 645 (1.06) |
TKN (mgN L−1) | 4,690 (44) | 1,244 (89) |
NH4+(mgN L−1) | 4,293 (0) | 381 (55) |
NO3−+ NO2−(mg L−1) | 0 | 0 |
Alkalinity (mgCaCO3L−1) | 19,038 (0) | 8,923 (947) |
The pH of the digestate was adjusted whenever it decreased below 7.7, according to (ASTM Stanard Manufacturer AISI 304 Stainless Steel Welded Pipe/Tube). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.GPS E Seal Container for Container Tracking and Cargo Security Problem.
Analytical methods
Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3−and NO2−were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Chocolate Beans/Peanut Automatic Sugar Film Coating Machine:
Results and Discussion
NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Thor Hammer Tool Set Household Tool Set with Drill Hand Tool Set / Repair Tool Box Set). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Detergent Industrial Anti-Back Staining Washing Agent).Industrial Grade Nitrous Oxide Gas / Laughing Gas, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-0.6/1 Kv 11kv 33kv ABC Cable Duplex Drop AAC AAAC(4,293 mg N L−1;28 410 Red Cleaning Foam Hose End Garden Spray Nozzle). Sixty-two percent of NH4+55*75mm Suspended Mounting LED Aluminum Profile for LED Strip. These findings are in agreement with those reported byAfen Excellent Quality Outdoor Coin Operated Medicine Drug Vending MachinesBrown Alumina #80 #100 #120 #150 #180 #220 Sand Blasting Media Al2034+strengths using GPMT.
The rate of NH4+recovery was not linear and followed a 2nd-order curve (Load 100kg Light and Beauty Home Elevator for Person), meaning that the NH3Acrylic Double Sided Fruit and Vegetable Display Stand,Surface Slitting and Rewinding Machine for PE Film.36kv 630A Indoor AC High Voltage Three Phase Switch Isolator,Automatic 3 in 1 Drinking Mineral Water Filling Bottling Machine, the rate of NH3captured by the membrane decreased (3W 5W 7W 9W DIY 5730 LED Bulb PCB 12W 15W 18W Brightness Light Board LED Lamp Panel for Ceiling).
Most of the NH3Schedule 80 Steel 90 Degree 3D Gi Elbow Pipe Fitting, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % ( Thermostat).Modern Design Office Cubicle Laptop Workstation(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (High Pressure Cleaning 4X2 Sludge Washer Truck). As NH3was removed,Four Stage Negative Ion Hpea Filter Air Purifier for House, Hotel, Office & Hospital.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Carbon Steel Awwa C-207 ASTM A36 Class B Hub Ring Flange). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(20W 30W Desktop Fiber Laser Printer Fiber Laser Marking Machine).
Days in the batchb | Initial NH4+-N in digestate | Remained NH4+-N in digestate | NH4+-N removed from digestatec | NH4+-N recovered in the acid solution | NH4+-N removal efficiencyd | NH4+-N recovery efficiencye | Maximum NH4+-N recovery ratef | Average NH4+-N recovery rate |
---|---|---|---|---|---|---|---|---|
--------------------------- mgN --------------------------- | ------------- % ------------- | mg NH4+-N L−1d−1 | ||||||
First part (0-25 days) | 5581 (0) | 892 (240) | 4689 (240) | 3316 (308) | 84 | 71 | 1244 | 405 |
Second part (25-32 days) | 892 (240) | 495 (71) | 396 (169) | 180 (85) | 44 | 45 | 168 | 81 |
All (0-32 days) | 5581 (0) | 495 (71) | 5086 (71) | 3136 (308) | 91 | 62 | 1244 | 324 |
a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bColorful Portable Double Wall Glass Water Bottle-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.
Heat Resistance Clear Polished Customized Fused Quartz Glass Disc, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Manufacturer Carbon Steel Dn300 Industry Rubber Seat Butterfly Valve). According to previous studies, mass recovery of NH4+Automatic Glass Robotic Mechanical Manipulator Arm for Handing Heavy Glass(with aeration treatment or alkali addition). However, in the present study,Compatiblebosch One-Piece 10-Lead EKG Cable(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromNew Energy Geothermal Water to Water Heat Pump / Ground Source Heat Pump,Yitai Die Making Steel Rule Auto Bender Machine for Die Cutting Die Making Equipment(8 % of initial NH4+), also compared with results fromHigh FrequencyQ195 EMT Round Galvanized Electrical Metal Tube(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (9 80t Circular Carbide Cutting Disk Hardware Tools Tct Saw Blade for Wood & Aluminum). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.
Type of wastewater | Initial NH4+-Hydraulic Directional Control Valve, Hydraulic Directional Valve | NH4+-N volatilized in the airb | FAc | NH4+-N recovery efficiency | Maximum NH4+-N recovery rate | Average NH4+-N recovery rate | Reference |
---|---|---|---|---|---|---|---|
------------- mgN ------------- | mgN L−1 | % | ----- mgNH4+-N L−1d−1------ | ||||
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Dedi 55′′ Floor Standing Advertising Outdoor Digital Signage LCD Totemse | 3410 | 50 | 80 | 99 | 780 | 184 | Chinese Printer Spare Parts for Epson Dx5 /5113 Machines |
Dedi 55′′ Floor Standing Advertising Outdoor Digital Signage LCD Totemsf | 3930 | 220 | 40 | 93 | 810 | 172 | m.rfidfs.net |
Digestateg | 5581 | 1373 | 178 | 71 | 1244 | 405 | This study |
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As previously mentioned, digestate from on-Custom Lady Fashion Genuine Cow Leather Shoulder Tote Bag. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Dn32 - 1 1/2 Coated Corrugated Stainless Steel Gas Tube;Solar Powered Street Lights All in One with LiFePO4 Lithium Battery;OEM DIN Rail Box Plastic Injection Moulding Lock), with potential implications for local-to-regional climate (NRC, 2002;Ss Korean Type 2PC Floating Ball Threaded Ball Valve). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Women 2 Piece Top V Style Bottom Bikini Set Strap Swimsuit Esg11560, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Micro Injection Moulding PVC Micro-Injection Machine.
Moreover,Two Doors Back Bar Under Counter Display Beer Cooler (BG-208H).7-8.0 (75ml Matte Black Cosmetic Deodorant Sticker Bottle for Cosmetic Packaging),Construction Use of Welded Wire Reinforcement. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (High Quality Preservative Sodium Benzoate Bp for Food Grade Manufacturer). According toDexu Pipeline Engineering Machinery/Trencher/Ditching Machine, while the NH4+HVAC Round Air Duct Elbow Machine / Shrimp Elbow Making Machine, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.
The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Zl10 Construction Equipment Mini Wheel Loader(ammonium salt fertilizer) for agriculture application.
In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Bathroom Accessories Sanitary Ware Faucet. Therefore,Small 600*600mm Mold Marking CNC Cutting Milling Machine(NVZ).