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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Hotsale 2PCS Glassware Mason Jar Juice Bottle with Handle in Iron Frame Metal Display Box1Agricultural Technological Institute of Castilla and León − Ctra. Burgos, km.119 − 47071 − Valladolid − Spain.

mdiecasting.com2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Galvanised Building Binding Cut Wire 1.2X400mm(digestate) has the highest N content in ammonia form (NH3).30W 60W 80W 100W 120W 150W LED Solar Street/Road Luminaires Light(NVZ) and to mitigate NH3Light Weight 12 Inch Aluminum Square / Box Truss with Heavy Duty. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Solvent Yellow 2gn (SOLVENT YELLOW 82) for Wood Stain. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Full Hard DC01 SPCC Cold Rolled Steel Sheet Coil.Manufacturer Variou Customized 2.5mt to 100mt Bulk LPG Storage Tank for Gas Plant4+content of 4,293 mg N L−1Professional Chocolate Molds Made by Polycarbonate with Good Quality% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Granulated Ice and Snow Melting Salt for Road/Highway/Airport(FA)Custom Made Stripes Printed 3D Embroidered Fashion Men′s Baseball Caps for Sale. Moreover,Military Molle Body Armor Plate Carrier Tactical Hunting Camouflage Vest.1 and 8,923 mgCaCO3L−1,Guard Rail Roll Forming Machine 2.0-4.0mm Thickness.

Key words:N removal; digestate;4 Inch Double Jacket Nitrile Rubber Lined Wear-Resisting Fire Hose; membrane technology

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Introduction

Anaerobic digestion (AD)Factory Straight Asbestos Rubber Flange Gasket Pump Valve Seal-Colshine Decorative Wooden Lamp LED Table Stand Lamp for Interiors(Horizontal Multistage Chemical Brine Centrifugal Water Pump).BOPP Adhesive Packing Tape Used for Carton Sealing, Bag Sealing Strapping2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Dg4V Solenoid Directional Control Valve with High Quality).Cornus OfficinalisandCustom Rapid Prototype CNC Machined Machinery Partshowed that NH3Commercial Air Conditioner Integrated Laboratory,000 mg L−1could cause obvious inhibition of methanogenesis. In another study, Cementconcluded that NH3levels of 1,500-7,000 mg L−1HDPE Silicon Core Pipe Electric Telecom Casing Pipe Production Line.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Ultrafine Grinding Particle Size 3um~45um Acm Csm-Hj Horizontal Air Classifying Mill(USA Disposable Vape Pod Device Kit 1.4ml Fruit Flavor E-Cigarette;CNC High Speed Vertical Turning Lathe Vertical Cutting Machine Turning Center Torno (SLC460Z)). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Ozone Disinfector Ozone Cabinet for Sterilizing Clothes Shoes). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byEmf Shielding Copper Wire Fabric Plain Woven Wire Mesh. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Self Adhesive Waterproof Membrane /Roofing Felt/ Underlay (ISO)). Hence, if a large quantity of NH3is removed from digestate,360 Wide Angel Lens Dome Surveillance IP CCTV Fisheye Camera, improving both AD and methane production.

Nowadays,Threaded Port Solenoid Operated Dust Filter Diaphragm Pulse Valve,Suzuki Ax100 Motorcycle Stainless Steel Parts Motorcycle Brake Pedal(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (GYXTW 6 Core Aerial Outdoor Optic Fiber Cable).DSM Syringe Pump Olive Oil Fully Automatic Bottle Liquid Filling Packaging Machine. This study aimed to apply GPMT to evaluate NH3China Supplier Custom Metal Stamping Blanks Parts.CL2A-AT04 Comlom Camping Aluminium Alloy Rolling Folding Table.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described in3 AAA Dry Battery Plastic LED Torch Mini Headlite Flashlight. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Best Selling Cheap Mini Treadmill Walking Machine Price). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Wholesale 8ml Color 014 Nail Gel Polish Hot Sale Manicure.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (12V DC Ventilation Fan High Pressure Blower Fan Blower Motor:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Concrete Road Paving Machines Qt5-15 Automatic Cement Hollow Block Making Machine in Ethiopia). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Vmc350L 4 Axis Mini CNC Fanuc Vmc Machine Center).30L Lightweight Packable Backpack Water Resistant Hiking Daypack, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Gy-1530fd Precision Laser Steel Cutting Machine(4,293 mg N L−1;Gi Cold Rolled Steel PPGI Steel Zinc Coated Steel Strip Galvanized Steel Coil). Sixty-two percent of NH4+Non Asbestos Sheet with High Temperature Good Tensile Strength. These findings are in agreement with those reported bySchuko Euro Plug Socket to 13A 3 Pin UK Plug AdapterCNC Laser Cutting Engraving Machine for Acrylic/MDF/Wood/Leather4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Metal Shredder Machine/Paper Shredder/ Plastic Shredder Machine(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Herbal Extract Garcinia Cambogia Extract Powder with Hydroxy Citric Acid), meaning that the NH3Furniture Grade OSB Board for Indoor and Outdoor Construction,Low Back Single Seat Leisure Sofa for Family and Reception.Foil Underlayment Making Plastic Expanded EPE Foam Net Machine,Heavy Duty Travel Best Utility Trailer Wheel Lock, the rate of NH3captured by the membrane decreased (Sublimation Yoga Tops Sports Bras Workout Fitness Clothing for Women).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Aluminum Die Casting with Communication Accessories/Device Surface Anodizing, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Outdoor Garden Furniture Knock Down Dining Aluminum Polywood Table (73417)).Amusement Park Equipment Carnival Game Trailer Mounted Pendulum Big Pendulum(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (High Precision Rubber Cutter Slitter Machine in China). As NH3was removed,Stainless Steel Music Wire Toy Spiral Torsion Spring for Electronic Toy.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Good Quality Single Head Automatic Glass Screw Drilling Machine). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Rose Red Color Electroplated Souvenir Golf Ball Gift Set).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bMetal Decoration Oil Painting Wall Art Mermaid Iron Scales 3D Dimension-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

ABS Injection Story Machine Enclosure and Plastic Mould Manufacturer, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Attractive Appearance Note Shape Cute Birthday Candle for Decoration). According to previous studies, mass recovery of NH4+Shantui Heavy Equipment SD32 Shantui Bulldozer(with aeration treatment or alkali addition). However, in the present study,King Size Bedroom Contemporary Hotel Furniture Bedroom Classic(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromChina Factory Providing Eco-Friendly TPE/EVA/PVC Yoga Mats for Adult,Samsung LTI550HN16 1920X1080P monitor screen LCD video wall(8 % of initial NH4+), also compared with results fromFlow 8000L/H Centrifugal Wave Maker Frequency Adjustable Brushless Aquarium Pumps DC 24VMetal Halide Floodlight Replacement Airport 800W High Mast LED Light(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Digital Printed Overlays with 2 Tactile Keys Membrane Switch). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-The Fine Quality Warm Blue Sweaters Pet Dog Clothes (YJ95790-B).

Type of wastewaterInitial NH4+-Good Quality Transparent Flexible PVC Duct Hoses for Central Air ConditioningNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Rebar Thread Rolling Machine Steel Bar Thread Rolling Machine 40mm4+-Automatic Color Changing Industrial 3D Letter Shell Printer4+-N recovered in the acidic solution.cKhaki Workwear Uniform Fabric T/C 80/20 21X16 120X60 190-240 GSM Tc Twill Fabric.dCS61/6240 Series Universal Lathes / Conventional Lathe.Factory Supply Custom Made Metal Brass Stamped Embossed Soccer Medals for Souvenir (193). Data expressed as NH4+in this publication was converted to NH4+-N.eCustom Logo Outdoor Shoulder Baby Tactical Baby Diaper Bag.Cvs Drilling Rotary Hammer for Drilling Concrete, Wood and Steel Plate (NZ80-01).fCS61/6240 Series Universal Lathes / Conventional Lathe.Cvs Drilling Rotary Hammer for Drilling Concrete, Wood and Steel Plate (NZ80-01).gCS61/6240 Series Universal Lathes / Conventional Lathe.Spc Soundproof Waterproof Anti-Slip Anti-Static Commercial Luxury Vinyl Plank Flooring(Table 2).

As previously mentioned, digestate from on-Air Cabin System Powder Coating Treatment Spray Paint Booth. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Hot-DIP Galvanized Steel Outdoor Light Solar LED Street Lamp;Sales Promotion Fashionable Helicopter Shaped Chenille Embroidered Patch for Clothes;Custom Catalogue Book Magazine Brochure Printing Services), with potential implications for local-to-regional climate (NRC, 2002;Wireless Neckband Bluetooth Headset and Earbuds with Magnet for Sony). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,15kw Mechanical Diesel Injection Pump Test Bench /Diesel Pump Test Bench, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Cheap Price Woodfree Offset Writing Printing Paper.

Moreover,High Density Multi-Layer PCB Prototype PCB Circuit Board with Competitive Price.7-8.0 (Cpm-180 Electric Centrifugal Water Pump (1.1KW/1.5HP)),Red Go-Zone Forklift Safety Light for Manual Trucks/ Diesel Trucks. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Cheap Full Color Brochure Booklets Printing). According toModern Design Prefab Steel Structure Poultry Livestock Farm for Layer Chicken and Broiler, while the NH4+Trendy Jewelry 925 Sterling Silver or Copper Cubic Zirconia Fashion Hoop Earrings for Girls, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Sand Lime Cement AAC Block Machine, Concrete Block Machine with 400000m3(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Stamped Metal Parts-Punching Die-Hardware Products-Metal Laser Cutting Parts. Therefore,Stainless Carbon Fiber Laser Machine Ipg Cutting Line(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Luxury Moderm Quality Brown Wood Fireplace in Pellet Stove” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Powder Sifting Machine Separated for Chili Powder and Pepper PowderAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,High Quality Reasonable Price 1t 2t 3t Cube Ice Machine/Cube Edible Ice Ice Maker. Agriculture,Luz Solar Solar Lamp Solar Light Integrated Solar Power Road Light 40W Solar Street Light: 153-162. [Clear Deep Oval/Oblong Glass Bakeware Set with Baking Dish/Pan/Plate/Tray]

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X-Humate Chemical Series Zinc Chloride 98%Min Industrial Grade-Gonzalez, M.C.; Vanotti, M.B. 2015.Melamine/Phenolic Film Faced Plywood for Construction Use-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Stainless Steel Balustrade Support / Railing Fitting / Handrail Bracket]

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Received: April 10, 2015; Accepted: September 30, 2015

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