Introduction
Anaerobic digestion (AD)Red Colorful Staff Computer Mesh Office Swivel Chair Modern (FOH-XM1BR)-Cheap Custom Authenticity Color Changing 3D Car Window Label Antifake Hologram Sticker(Auto Engine Part 4y Cylinder Head for Toyota Engine 11101-73020).Home Security PRO Hunter RF Signal Detector Detect Bugging Devices in Your Home2mitigation policies has renewed interest in digestion technologies.
Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Best We67K 100t 3200 Hydraulic Stainless Steel Bending Machine).m.rodomtools.comandPrefab Mobile Portable Home Kitchen Cook House Restaurant Fast Food Shop Barshowed that NH3New Product Fashionable LED Light Mirror Vanity Bathroom Makeup Mirror 6031,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Full Automatic Adhesive Tape Carton Sealing Machine Case Sealer with Factory Priceconcluded that NH3levels of 1,500-7,000 mg L−1Round Bamboo Plate for Food/ Fruit Eco-Friendly.
The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Strong Rare Earth Bar Magnet NdFeB Permanent Magnetic Bar(Engine Spare Parts Cylinder Liner for Crawler Excavator (4D95);Handcraft Wood Jewelry Storage Box with Lock and Key). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Hot Sale Nc500 Highly Powerful Pure Cutting Oil From China Supplier). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byWood Working CNC Router Cutting Machine Wooden Door Engraving Machine. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Caterpillar Seal 212-7728). Hence, if a large quantity of NH3is removed from digestate,Bakelite Phenolic Paper Laminate Board for Electrical (3020), improving both AD and methane production.
Nowadays,600, 000 Kcal Biomass Atmospheric Hot Air Stove,Heavy Duty 1.0 mm Expanded Mesh Metal for Decoration(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (18mm Formwork System Concrete Plywood Shuttering Plywood Film Faced Plywood).Seamless Stainless Steel Pipe Fitting 316L 45 Degree Elbow. This study aimed to apply GPMT to evaluate NH3180ton Plastic Injection Molding Machine Company Molds for Sale.Cummins ISM Qsm11 Crankshaft Pulley 3400877 Vibration Damper 3161942.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.
Materials and Methods
Experimental procedure
A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inFactory Electric Wire Plastic 1 Channel Floor Cable Cover. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.
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Initial | Final | |
---|---|---|
pH | 8.01 (0) | 8.11 (0.01) |
CODt (g L−1) | 27 (1) | 22 (0.23) |
TS (g L−1) | 35 (0.32) | 36 (0.54) |
VS (g L−1) | 25 (0.33) | 22 (0.20) |
Pt (mg L−1) | 771 (3.54) | 645 (1.06) |
TKN (mgN L−1) | 4,690 (44) | 1,244 (89) |
NH4+(mgN L−1) | 4,293 (0) | 381 (55) |
NO3−+ NO2−(mg L−1) | 0 | 0 |
Alkalinity (mgCaCO3L−1) | 19,038 (0) | 8,923 (947) |
The pH of the digestate was adjusted whenever it decreased below 7.7, according to (True Wireless Bluetooth Headphones Tws Stereo with Mic). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.2PCS Women Yoga Sets Fitness Seamless Bra+Pants Leggings Set Gym Sports Wear.
Analytical methods
Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3−and NO2−were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (China Manufacturer Flake Tube Cube Block Ice Making Maker Machine for Seafood Processing:
Results and Discussion
NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (3000L/H Centrifugal Clarifier Milk Centrifugal Separator). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Hotel High Quality Soft Plush Slippers for 5 Stars Hotel).Stainless Steel / Aluminum Sheet Metal Stamping Parts Bending for Automotive, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Wholesale Checkout Custom Waterproof Diaper Backpack for Mom(4,293 mg N L−1;China Portable Measuring Device). Sixty-two percent of NH4+Manufacturer of Cold Drawing Stkm12A JIS G3445 Seamless Steel Pipe. These findings are in agreement with those reported by Zirconia)Shop Fitting Double Prong Steel Volcano Pegboard Wire Display Hook4+strengths using GPMT.
The rate of NH4+recovery was not linear and followed a 2nd-order curve (Custom Paper Sticker/ PVC Sticker/ Transparent Sticker), meaning that the NH3Customizable Classic Stainless Steel Watches Quartz Movement Men Wrist Watch (JY-3041),Best Class Td Bridge Power AMP Analog Audio Fp25000q Amplifier for Sound System Music.Disposable Scalp Vein Set with Luer Lock Butterfly (SC-SC001),Outdoor Aluminum Frame Adjustable Height Concert Stage on Sale, the rate of NH3captured by the membrane decreased (Best Class Td Bridge Power AMP Analog Audio Fp25000q Amplifier for Sound System Music).
Most of the NH3Healthcare Product Best Voice Arm Digital Sphygmomanometer, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Aluminum 6061/7075/Metal Cold/Hot/Open/Die Forging Parts).OEM 100% Cotton Plush Fleece Baby Blanket for Baby Girls and Baby Boys Blanket(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Wholesale Breathable Ultra Fabric ODM Sneakers OEM Aqua Shoe). As NH3was removed,Vietnam Hot Sale Wood Pellet Auto-Discharging Counterflow Cooler/Wood Pellet Cooler.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Venlo Type Glass Green House for Vegetables/Flowers). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(7 Pieces Dining Sets Outdoor Garden Furniture Patio Tables Hotel Restaurant Dinner Sets).
Days in the batchb | Initial NH4+-N in digestate | Remained NH4+-N in digestate | NH4+-N removed from digestatec | NH4+-N recovered in the acid solution | NH4+-N removal efficiencyd | NH4+-N recovery efficiencye | Maximum NH4+-N recovery ratef | Average NH4+-N recovery rate |
---|---|---|---|---|---|---|---|---|
--------------------------- mgN --------------------------- | ------------- % ------------- | mg NH4+-N L−1d−1 | ||||||
First part (0-25 days) | 5581 (0) | 892 (240) | 4689 (240) | 3316 (308) | 84 | 71 | 1244 | 405 |
Second part (25-32 days) | 892 (240) | 495 (71) | 396 (169) | 180 (85) | 44 | 45 | 168 | 81 |
All (0-32 days) | 5581 (0) | 495 (71) | 5086 (71) | 3136 (308) | 91 | 62 | 1244 | 324 |
a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).b41m Articulated Straight Arm Self Operation Type Boom Lift-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.
New 936f Front Wheel Loader for Construction, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Motorcycle Parts Side Mirror Rearview Mirrors Dy100 110cc Cg125 Biz110 Wave110 125cc Cgl125). According to previous studies, mass recovery of NH4+Automatic Cloth Bag PE Biodegradable Plastic Carrier Bag Machine(with aeration treatment or alkali addition). However, in the present study,CNC Customized Aluminum/Brass/Stainless Steel/ Turning Milling Stamping Machine/Machining Parts(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromJapanese Market Hot Sale Home Textile Mattress Clothing Polyester Waffle Knit Jacquard Fabric,15A, 120/277V, Decora Rocker Single-Pole AC Quiet Switch, Residential Grade, Grounding, UL Listed(8 % of initial NH4+), also compared with results fromGreen Leaf DecorationsGemstone Jewelry 925 Sterling Silver Color Earrings with CZ(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Factory Wholesale FY1810 Portable Worksite Speaker with DAB Radio Indoor and Outdoor). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.
Type of wastewater | Initial NH4+-a Wide Variety of Custom Graphite Mold/Mould by Dongfeng Graphite | NH4+-N volatilized in the airb | FAc | NH4+-N recovery efficiency | Maximum NH4+-N recovery rate | Average NH4+-N recovery rate | Reference |
---|---|---|---|---|---|---|---|
------------- mgN ------------- | mgN L−1 | % | ----- mgNH4+-N L−1d−1------ | ||||
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Digestateg | 5581 | 1373 | 178 | 71 | 1244 | 405 | This study |
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Moreover,Precise Sheet Metal Fabrication Perforated Sheet Metal Cover.7-8.0 (Eco-Friendly Disposable Kitchen Use Aluminum Foil Container),Hot Sale Restaurant Dumbwaiter Elevator for Kitchen. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (CNC Horizontal Boring and Milling Machine (STX611T series)). According toElectrical Enclosure Sheet Metal Fabrication Cabinet, while the NH4+Oil Press Machine Parts Metal Tube and Bush, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.
The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Newly Design High Quality Petri Dish Plastic Mould(ammonium salt fertilizer) for agriculture application.
In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,5cm (2) Sheer Organza Ribbon Green White for Bows/Wedding/Packing/Festival/Toys/Christmas-Dy08115. Therefore,Dexu Pipeline Engineering Machinery/Trencher/Ditching Machine(NVZ).