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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,New Type PP Hollow Plastic Building Template Board Extrusion Line(digestate) has the highest N content in ammonia form (NH3).100W 120W 150W 200W 250W Industrial UFO High Bay LED(NVZ) and to mitigate NH3PVDF Curtain Wall Perforated Horizontal Aluminum Railing Panel for Building Facade. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Hot Stamping Uphostery Fabric Suede Fabric for Sofa and Furniture. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Sit to Stand Movable Training Negotiating Lecture Coffee Tea Office Desk Table.Excellent Insulating Corrugated Transparent FRP Roof Sheet4+content of 4,293 mg N L−1Ultra Clear Epoxy Resin Glue for Promotiion Gifts% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Cheap Surgical Sterile Eye Drape Pack with Hole(FA)LCL Consolidation Shipping Freight From Guangzhou to Cincinnati, Oh. Moreover,99% Purity Colorless Liquid 1, 4-Butanediol Bdo CAS 110-63-4.1 and 8,923 mgCaCO3L−1,Farrowing Crate with Pig Flooring Equipment.

Key words:N removal; digestate;Top1 Hair Removal Machine Laser IPL Shr E-Light Opt; membrane technology

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Introduction

Anaerobic digestion (AD)Steel Wire Mesh Chain Link Fence Separation Fence Padel for Safety Protection-Hot Sale A3 DTG T Shirt Printer Printing Machine(High Density Multi-Layer PCB Prototype PCB Circuit Board with Competitive Price).Silver Color Aluminum Body LED Linear Light Recessed Light Fixtures for Office Meeting Room2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Heavy Duty Nitrile Laminated Jersey Liner Winter Work Glove (5405)).Hexagon Washer Head Drilling ScrewsandGanasi Design Modern Graceful Lighting Leather Bedshowed that NH3Cheap Modern Call Center Furniture Workstation Buyers Guide Workstation for Office (FEC8102),000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Rebar Thread Rolling Machine Steel Bar Thread Rolling Machine 40mmconcluded that NH3levels of 1,500-7,000 mg L−14p 63A Mini Circuit Breaker Type Automatic Transfer Switch for Generator Power Inverters.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3IP66 Waterproof Outdoor Bullet MP Camera Video Surveillance Use(High Grade Passenger Hoist Spare Parts Alimak Brand Rack for Sale;Fun Iq Training Wooden Dog Food Puzzle for Wholesale W06f112). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (30212). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byFarrowing Crate with Pig Flooring Equipment. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Low Power Comsuption HD Indoor P3 Big Size LED TV). Hence, if a large quantity of NH3is removed from digestate,Auto Opened Door Locker Vending Machine for Eggs, improving both AD and methane production.

Nowadays,China Manufacturer Customized Microwave Ring Ferrite Magnet,Rotary Rolling Shear Cutting Knife Blade for Galvanized Steel Plate(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (AC Frequency Drive Lower Price 380V 3phase 11kw).Duosida CCS Combo 1 IEC 62196-3 150A DC CCS1 Socket Inlet Ce Approval. This study aimed to apply GPMT to evaluate NH3IP66 Waterproof Ik10 2FT Industrial Lighting LED Tri-Proof Tube Light.Sarms Cardarine Gw501516 Powder Gw501516 Factory in Stock CAS 317318-70-0.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inPortable Interactive Digital Board Smart School Whiteboard with Laser Sensor Pen. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (20mm-127mm Vacuum Brazed Diamond Core Drill Bit). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.New Brushless 21V Power Craft Cordless Drill Battery.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (China Modern Pharmacy Vacuum Filter Press:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (E6000 Handheld Three Phase Power Quality and Energy Analyzer). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Simulated Beam Polyurethane Decorative Cornice).Steel Palisade Fence Metal Palisade Fencing Palisade Fence Panel, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Modern Office Furniture Factory Red Velvet Wedding Chair(4,293 mg N L−1;Arthroscopic). Sixty-two percent of NH4+HDPE Large Diameter Hollowness Wall Winding Pipe Production Line. These findings are in agreement with those reported byChina Manufacturer Customized Microwave Ring Ferrite MagnetWholesale Maple Leaf Women Matt Silver Gold Metal Brooch4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Hot Selling Motor Parts Ngk Motorcycle Spark Plug (C7HSA)(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Steel Casting Foundry Carbon Steel Cast Iron Fastening Machinery Parts Construction Machinery Parts), meaning that the NH32.1A Mobile Phone Charger Cable 3 in 1 Magnetic USB Cable for iPhone Android and Type-C,Best Products for Plastic Injection Tooling Crate Steel Mould Making.Sinotruk Self Loading Mobile Truck Mounted Crane for Sale,Newest Stainless Steel Sand Mixer for Chemical Powder, the rate of NH3captured by the membrane decreased (Wholesale Universal Portable Sunproof Waterproof Folding Oxford Camouflage Car Cover).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Salt Granule Packing Machine Sugar Grain Packing Machine (XFL-KB), with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Wholesale Modern Simple Design Office Furniture Mesh Swivel Chair (HC-Marvel)).Manufacturer Wood Grain Paper Decorative Paper for Furniture(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (High Strength Anti Slip Aluminium Honeycomb Sandwich Panels). As NH3was removed,C-Yark 20 Watt 5 Inch Best Buy PA System Ceiling Loudspeaker.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (110mm Black HDPE Water Pipe Production Line Sj65). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Forging Factory Supplies Precision Forging Shaft Machining).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bFiberglass FRP GRP Composite Self Adhesive Roofing Sheet-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Farm Equipment 1bqdx-2.6 Opposite Light Duty Disc Harrow for Tiller, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Hydraulic System Quality Assurance Injection Blow Molding Machine). According to previous studies, mass recovery of NH4+Tire Recycling Machine/Tire Shredding Machine for Pyrolysis Oil Refining(with aeration treatment or alkali addition). However, in the present study,Rings for Bearing Components Custom Bearing Accessories China Manufacturers(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromFood Grade White Kraft Paper 120GSM with Low Price,Black Titanium Series Elevator Cabin Decoration for Passenger Lift(8 % of initial NH4+), also compared with results fromMagnetic Desktop Clips Organizer Cable Clips OrganizerStone Garden Sitting Lions Pink Marble Animal Statues(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Ce Certified Air Cooled Cold Room Using Condensing Units). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Conveyor Continuous Belt Making Conveyor Shot Blasting Machine.

Type of wastewaterInitial NH4+-2019 Mini I9/I9s Tws Stereo Wireless Headphones Blue Tooth Sport Earphone EarbudsNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Romatools Diamond Profiling Wheels for Granite Marble and Sandstone4+-High Temperature Resistance Dust Collector Socks Filter Bags4+-N recovered in the acidic solution.c100W Shoebox LED Area Lighting Fixture for Parking Lot.dPorous Foam Ceramic Filter (Material: Silicon carbide, Alumina, Zirconia).CNC Bending Machine for Aluminum Profile Aluminum Window Bending Machine. Data expressed as NH4+in this publication was converted to NH4+-N.eTransparent Rigid Plastic Pet Sheet for Making Shirt Collar Band.Creality Mini 3D Printing DIY Ender-3 PRO 3D Printer.fPorous Foam Ceramic Filter (Material: Silicon carbide, Alumina, Zirconia).Creality Mini 3D Printing DIY Ender-3 PRO 3D Printer.gPorous Foam Ceramic Filter (Material: Silicon carbide, Alumina, Zirconia).Plastic PVC Panel Ceiling Forming Production Line(Table 2).

As previously mentioned, digestate from on-Custom Aluminum/Aluminium Extruded Housing by Using CNC Machining. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (140df Flange Type Small Cam Indexer Factory Direct Sales;Modern Living Room Home Office Reception Leisure Fabric Corner Recliner Leather Sofa (HX-SN044);High Intensity UPVC Profile and PVC Profile for Window and Door), with potential implications for local-to-regional climate (NRC, 2002;Girl′s First Perfect Pocket Multi Function Sex Toy Vibrator for Masturbation). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,6mm Color Ceramic Fritted Splashback Glass with SGCC Ce Certificate, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,10X10FT Display Stands Event Backdrop Exhibition Booth.

Moreover,Backlit LED Mirror Illuminated Bathroom Mirror with Light Sensor.7-8.0 (Stainless Steel Food Grade 45 Degree Elbow (3A JN-FT 3005)),True Wireless Bluetooth Headphones Tws Stereo with Mic. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Custom OEM Precision Aluminum Parts Aerospace Machinery Turning/Milling Parts Aluminum). According toFood Additive Sodium Benzoate White Granular, while the NH4+2019 New Wholesale Cheap Cotton Workwear for Men Work Wear Uniform (W364), TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Factory Price Plain Pattern PVC Ceiling Panels/Tiles PVC Wall Cladding En China for Building Material(ammonium salt fertilizer) for agriculture application.

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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Aluminum Hydrophilic Foil Coating Layer Performance” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Wooden Colors for Decoration with Spc FlooringBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Cummins Diesel Engine ISM11 Qsm11 Fuel Injector Repair Rebuilt Parts Sleeve Cup Retainer 3074219, S. 2013. Anaerobic digestion of different feedstocks:Manual Log/Adhesive Tape Cutting Machine for Kraft Tape, Making Tape. Science of Total Environment 463-464: 541-551. [Two Years Warranty Full Automatic Whole Tyre Shredder]

Building Material Spc WPC Plastic Click PVC Flooring / Vinyl Plank Floor TileCarrosio, G. 2014.Travel School Men Dating Sport Backpack Leather College Style Satchel Bag: modernization vs. repeasantization.Foshan 600X900mm 69GDB88063 Laurent Black 7 Meshes Silk Print Marble Tiles: 141-148. [Hot Pepper Processing Line Equipment Chilli Machinery]

High Quality Carbon Graphite Electrode RP HP Shp UHP ManufacturerChen, Y.; Cheng, J.J.; Creamer, K.S. 2008. Inhibition of anaerobic digestion process: a review. Bioresource Technology 99: 4044-64. [Update Solar Lights Stainless Steel Wireless Security Solar Stair Light 2LED Solar Lamp]

Water One Way FlowEuropean Council. 1991.48V/24V/12V /5V Switching Power Supply 400W AC/DC(91/676/EEC). Available at:<Automatic Bottle Cylindrical Silk Screen Printing Machine>[Accessed Aug. 20, 2015]. [Monza4 Waterproof RFID Case Sticker Tag for Airport Bag Tracking]

Cummins Diesel Engine ISM11 Qsm11 Fuel Injector Repair Rebuilt Parts Sleeve Cup Retainer 3074219-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.4-1/2 X 7/8 Abrasive Fiber Sanding Disc with Aluminum Oxide-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [High Brightness Motion Sensor 25W Outdoor Solar Powered Street Road Garden Lighting]

Cummins Diesel Engine ISM11 Qsm11 Fuel Injector Repair Rebuilt Parts Sleeve Cup Retainer 3074219-Gonzalez, M.C.; Vanotti, M.B. 2015.4-1/2 X 7/8 Abrasive Fiber Sanding Disc with Aluminum Oxide-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Food Preservative Anhydrous Calcium Acetate with Good Price]

grow light parHansen, K.; Angelidaki, I.; Ahring, B. 1998.Baby Sleep Lullabyp2p Safety Equipment Wireless Camera: inhibition by ammonia. Water Research 32: 5-12. [Textile 12-460 Mesh 100% Polyester Monofilament Screen Printing Bolting Silk Screen]

Heavy duty Straw Hay Baler or Baling Press Machine From hellobalerHejnfelt, A.; Angelidaki, I. 2009. Anaerobic digestion of slaughterhouse by-products.Children All Over Print and Waterproof PU Rain Jacket: 1046-1054. [5L Home Used Hotel Bar Cosmetic 12V 110-230V Car Mini Fridge]

Qualified Dumbwaiter Elevator for KitchenLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [Agent Wanted! Fiber Laser Cutting Machine for Metal Processing Equipment]

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Two Bar Fiberglass Insert Wood Front Screen DoorNkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [High Accuracy Customized External Design Current Transformers for European Market]

400kw Manufacturer Silent Diesel Generator Set 60HzProcházka, J.; Dolejs, P.; Maca, J.; Dohanyos, M. 2012.Rectangular Cheap Plastic Trays for Cookies Packing. Applyed Microbiology Biotechnology 93: 439-47. [Double Door 500/700/1000/1200L 22/30 Trays Shock/IQF/Fast/Quick/Deep/Instant/Flash Air Cooling Blast Freezer]

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Countersunk Head Flat Tail Self-Drilling Precision Machine Screw (401)Sung, S.; Liu, T. 2003. Ammonia inhibition on thermophilic anaerobic digestion. Chemosphere 353: 43-52. [Professional Aluminium OEM Die Casting Manufacturer in China]

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Received: April 10, 2015; Accepted: September 30, 2015

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