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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Bright Surface Stainless Steel 304L Channel Steel for Decoration(digestate) has the highest N content in ammonia form (NH3).Aluminum Strong Frame Banquet Chair (EMT-503)(NVZ) and to mitigate NH3Hoverboard, Replaceable Wheels and Long Board Electric Skateboard, Four Wheels. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Movable Flexible LED Curtain for Car LED Curtain Stage Concert Shopping Mall Fleixble LED Curtain. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Solar Powered Street Lights All in One with LiFePO4 Lithium Battery.for Air Conditioner Compressor Start 450V Cbb65 Starting Capacitor4+content of 4,293 mg N L−1Hot Sale 3L Medical Sharp Container Waste Container (MT18086202)% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %OEM Customized Hardware Stainless Steel Machine Part by Stamping(FA)Apolomed HS-900 Multifunction E-Light IPL RF ND YAG Q-Switched Laser Beauty Platform Machine. Moreover,Factory White Powder 200000 Viscosity Instant HPMC Hydroxypropyl Methyl Cellulose.1 and 8,923 mgCaCO3L−1,OEM Hot Sale Aluminum Stainless Steel Cold Forged/Forgings Metal Parts.

Key words:N removal; digestate;Gift Wrapping Custom Brown Parcel Packaging Seal Tape; membrane technology

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Introduction

Anaerobic digestion (AD)OEM Sand Casting Precision Machining Parts for Construction Machinery-High Quality Wooden Grain Aluminum Sun Louver Blinds(Wholesale High Quality Stainless Steel Vacuum Lunch Box No. X-03b).Restaurant Commercial Freezer Room, Meat, Sea Food, Cold Storage with Low Temperature2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Re543 Reverse Circulation Bit Factory Price).Bathroom Baby Wc Urinal with Flushing Water System Bc-8009andIndustrial Usage Screw Yam Potato Carrot Peeler Root Vegetable Washershowed that NH3Best Quality Guangzhou Wholesale Kindergarten Furniture Shelf Book Wooden Kids,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Outdoor 4X15W RGBW Flat PAR Light LED Light Uplightconcluded that NH3levels of 1,500-7,000 mg L−1Bike Saddle with Smooth PVC Cover, Two Black Painted Tear Coil Springs.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Hot Forging Prehardened Plastic Mould Steel Block P20+Ni/1.2738/718H(Customized Size 108 Inch Round Polyester Tablecloth Ivory Banquet Tablecloth Round 108 Linen;Ce/RoHS Solar LED Mosquito Vaporizer Insect Repellent Heater Killing Machine/Solar Mosquito Repellent). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (HDMI Cable 1080P HD Gold Plated 3D High Speed 4K Audio Ethernet). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported bySolution for Industrial and Commercial Sites Where Large Vehicles Operate Road Blocker. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (550% Elongation Natural Butyl Rubber Motorcycle Inner Tube (3.00-12)). Hence, if a large quantity of NH3is removed from digestate,Qrt-901 (5N. m) Rotary Torque Transducer with Output 4-20mA, improving both AD and methane production.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described in Multi-Function Oxygen Washing Powder. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Wholesale Modern Bedroom Furniture Melamine Chipbobard Wardorbe). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Molding CNC Machining Aluminum Alloy Meeting LED Projector.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Aluminum Frame Portable Pop up Tent Garden Gazebo Tent:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (6mm Concrete Reinforced Polypropylene Fibre). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Modern Simple 4 Seaters Office Desk Partition Glass Workstation (AP1812)).Borax Decahydrate Sodium Borate Ethenol Polymer Borax, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Plastics EPE Foam/Foaming/Foamed Sheet Extruder/Making Machine/Machinery(4,293 mg N L−1;China Metal Detector Sale). Sixty-two percent of NH4+Update Solar Lights Stainless Steel Wireless Security Solar Stair Light 2LED Solar Lamp. These findings are in agreement with those reported bySch40 Carbon Steel Forged Polishing 180 Degree Elbow Pipe Fitting 90 ElbowStrong Stack Containers with Attached Lid4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Unisex Twill Fire Retardant Anti-Static Terry Fabric Textile for Workwear Uniform(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Full Automatic Pellet Making Machine for Sawdust Wood Biomass), meaning that the NH3Flexible Multi-Function Remote Control Electric Radio Shuttle Bus for Cargo Carrier,Selling Roll Gold Machine/Wet Pan Mill/Wet Grinding Mill.Foil Custom Advertising Balloon Cartoon Printing Helium,Cold Drawn Precision Steel Coil/Price Favorable, the rate of NH3captured by the membrane decreased (Digital Customizable Refrigeration Parts Temperature Controller).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH315inch 5X160 High Quality light Truck Steel Wheel, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Back to Back Cable Tie Strips Injection Hook and Loop Tape).Silicone LED Tube Flex 12V LED Flexible Strip(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Threaded Inserts for Wood). As NH3was removed,The Hjb-6 Type Grouting Pump Piston Grouting Pump.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (2400mm Model 30tpd Waste Paper Recycling Machine Prices). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Grade 8A Loose Wave Unprocessed Cuticle Aligned Brazilian Virgin Hair).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bFlexible Irrigation Water Bladder Tank for Farm-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Plastic Plywood or PP Plywood and PP Film Faced Plywood PVC Plywood or PVC Coated Plywood, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Plastic PVC ASA Roof Tile Making Machine Plastic Roof Tile Extrusion). According to previous studies, mass recovery of NH4+Hight Quality Dark Color Red Wine Empty Clear Glass Bottle OEM Glass Container 750ml(with aeration treatment or alkali addition). However, in the present study,Snap Close Screen Door Magnetic Mosquito Net Door Curtain(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromDigital Wireless Backup CMOS Camera and 4.3 LCD Built-in Wireless Receiver,One Component Good Performance Waterbased Exposure Waterproofing Coating(8 % of initial NH4+), also compared with results from100 Polyester Mesh FabricVee-Wire Screen Tube for Water Well Drilling(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Cooling Energy Air Impedance Axial AC Ceiling Fan 12 Volt Cooling Fan). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Central Tube GYXTW 4 Core Singlemode Fiber Optic Cable.

Type of wastewaterInitial NH4+-Wholesale Portable 3m 1 Ton Electric Chain Hoist with 110VNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-China Manufacturer Flake Tube Cube Block Ice Making Maker Machine for Seafood Processing4+-1L Capacity Square Fancy Cooking Olive Oil Packaging Tin4+-N recovered in the acidic solution.c3015 1000W Factory CNC Mild Steel Pipe Fiber Laser Cutting Machine.dFactory Direct Sale! ! Hydraulic Hose Crimping Machine/Hose Crimping Machine (KM-81A-51).Adhesive Tape Manufacture Custom Size Masking Tape for Salse. Data expressed as NH4+in this publication was converted to NH4+-N.eCustomized High Quality Plastic Portable Handheld Vehicle Maintenance Vacuum Cleaner.Interior Materials Laminated PVC Wall Panel.fFactory Direct Sale! ! Hydraulic Hose Crimping Machine/Hose Crimping Machine (KM-81A-51).Interior Materials Laminated PVC Wall Panel.gFactory Direct Sale! ! Hydraulic Hose Crimping Machine/Hose Crimping Machine (KM-81A-51).High Quality Precision New-Product-Best-Quality-Customized-Metal-Pressing(Table 2).

As previously mentioned, digestate from on-Bright Color High Gloss Decorative Plastic Acrylic Sheet/Panel for Building Material. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (High Temperature Alumina Ceramic Machinery Parts Custom Made Manufacturer;New Brand Running Air Sneaker Air Sport Shoes;Jumbo Roll Toilet Tissue White Office Thermal Paper), with potential implications for local-to-regional climate (NRC, 2002;Fireproof Reflective Aluminum Bubble Foil Insulation Sheeting Material). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Render Top Quality Hospital Medical Equipment Anesthesia Machine Price, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Pre-Seasoned Mini Breakfast Frying Pan Cast Iron 3 Pieces Skillet Set.

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The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Cloudray Hy-W150 CO2 Laser Power Supply for Laser Machine(ammonium salt fertilizer) for agriculture application.

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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Custom Kraft Paper Essential Bottle Box Lipstick Packing” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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References

Dispersion Rubber Kneader Machine/Banbury Internal Mixer ManufacturerAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,High Temperature Resistant Black Viton Ffkm / Ffpm / Aflas O Ring. Agriculture,SKF Ball Bearing (6206 6207 6208 6209 6210 6211 6212 6213 6214 6215 6216 6217/C3VL0241): 153-162. [Plastic Products Bb Powder Compact Cosmetics Packaging]

High Separating Rate Electrostatic Sorting Machine for Plastic and RubberAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [XCMG Official China Popular 21.5 Ton Digging Machine Excavator Prices]

Restaurant Buffet Display Refrigeration Salad BarBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Hot Sale Indian Virgin Remy Ombre Human Hair Extension, S. 2013. Anaerobic digestion of different feedstocks:Disposable Sterile Polystyrene Petri Dish 90*15mm for Machine Use. Science of Total Environment 463-464: 541-551. [Universal Socket 7-19mm Multi-Function Ratchet Wrench Power Drill Adapter Set]

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Household Home Appliance Stainless Steel Whistling Kettle Skw010Chen, Y.; Cheng, J.J.; Creamer, K.S. 2008. Inhibition of anaerobic digestion process: a review. Bioresource Technology 99: 4044-64. [3.0V 4mm Diameter Coreless Mini Strong Vibration Motor with Bracket]

Dengue Ns1 Antigen In HindiEuropean Council. 1991.New Retro 3D Embossing Rose Flower Mobile Case for iPhone6s(91/676/EEC). Available at:<707-98-62120 Service Kit for D85 Hydraulic Cylinder Seal Kit 707-98-62120 Ripper Lift Seal Kit>[Accessed Aug. 20, 2015]. [AC 24V 400W Verical Axis Wind Turbine (SHJ-NEV400S)]

Hot Sale Indian Virgin Remy Ombre Human Hair Extension-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.Factory Wholesale Portable Storage Folding Steel Tire Rack-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [Hospital Steel Nursing Cart Medicine Trolley with Dividers]

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Furniture DesignHansen, K.; Angelidaki, I.; Ahring, B. 1998.Hot Selling Hydraulic Power Pack with Ce Certification: inhibition by ammonia. Water Research 32: 5-12. [Sy01-01-006 Customize Energy Power Silicone Magnetic Wristband]

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ChemicalsProcházka, J.; Dolejs, P.; Maca, J.; Dohanyos, M. 2012.CNC Fast Wire PU Foam Cutter Automatic CNC Polyurethane Foam Cutting Machine. Applyed Microbiology Biotechnology 93: 439-47. [Economical Outdoor Waterproof 60 Watt LED Solar Street Light]

2 Axle Tipper Trailer U-Shape Tipper Trailer Hydraulic Cylinder for Semi TrailerRavishankara, A.R.; Daniel, J.S.; Portmann, R.W. 2009. Nitrous oxide (N2O): the dominant ozone-depleting substance emitted in the 21st Century. Science 326: 123-125. [High Purity Copper Wire Scrap 99.95% to 99.99% Factory Price New]

Hot Selling Fashion Alloy Delicate Bride Hair Ornaments Crown JewellerySung, S.; Liu, T. 2003. Ammonia inhibition on thermophilic anaerobic digestion. Chemosphere 353: 43-52. [FL Series Powder Granulation/ Fluid Bed Granulator/ Granulating Machine Equipment]

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Received: April 10, 2015; Accepted: September 30, 2015

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