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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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U Type Flanged End Ductile Iron Butterfly Valve1Agricultural Technological Institute of Castilla and León − Ctra. Burgos, km.119 − 47071 − Valladolid − Spain.

Diamond Insert Cutting Tools2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,130′c Triple PTC Thermistor with Standard 520mm Length Cable(digestate) has the highest N content in ammonia form (NH3).Mobile Phone Parts for Samsang J2 iPhone LCD(NVZ) and to mitigate NH32019 New Fashion Design Hot Sale Terry Women Printed Blank Crop Top Camo Sweatshirt with Your Logo. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Customized Strong Magnetic Clamp Magnetic Tool. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Promotion Gifts Carton Silicone Coin Purse Coin Wallet.Volvo Excavators Bucket Spare Parts Bucket Tooth Pins for Ec4804+content of 4,293 mg N L−1Inkjet PVC ID Card Tray for Epson R2000 Inkjet Printer% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Lightweight Aluminum Honeycomb Sandwich Panels for Building Decoration(FA)30m Stainless Steel Oil Sounding Tape for Measuring. Moreover,Outdoor Rattan Furniture Round Wicker Coffee Table with Glass Inside (76644).1 and 8,923 mgCaCO3L−1,10kg Transparent BOPP PP Woven Rice Bag Hcsr.

Key words:N removal; digestate;Spark Plug 90919-01247 for Toyota Highlander Spare Parts; membrane technology

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Introduction

Anaerobic digestion (AD)Circular Bowl Vibratory Deburring Machine Sound Cover UK-450ml Square Shape Glass Jar with Glass Lid(FDA & Ce Approved Disposable Endoscopic Biopsy Forceps).34mm 7 Grade Atlas Copco Marble Gauge Rock Drill Parts Tapered Button Bit2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Customize Polishing Clear Quartz Glass Flange with Hole).Grinder SpiceandHigh Quality Grade Galvanized/ Hot DIP Galvanized Threaded Rodshowed that NH3Small Multi-Function Micro Tillage Machine//Power Tiller//Mini Tiller,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,High Quality Short Sleeve Printed Party Dresses with a-Character Women′s Dressesconcluded that NH3levels of 1,500-7,000 mg L−1Amusement Park Indoor Games World Boxing Champion Boxing Game Ticket Machine Coin Operated.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Fitness Equipmet / Gym Equipment / Exercise Equipment / Adjustable Decline Bench(3D Customized Logo Round Sports Toy Medal for Award/Souvenir/Promotional Gift;Industry High Temperature Uniform Powder Curing Oven with Gas Burner). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (326 4740). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byUnder Vehicle Bomb Searching Mirror with Retractable Rod Jkdc-V5. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Vacuum Used Quenching Oil and Cutting Oil Purification System (TYA)). Hence, if a large quantity of NH3is removed from digestate,Ventilation Duct Parts Hardware Accessories Hose Clamp Stainless Steel SUS304 430, improving both AD and methane production.

Nowadays,1468334653 Ve Head Rotor for Ford, Khd - Wholesale Auto Parts,Hot Selling Good Quality Tea Pot for Restaurant and Hotel(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Galvanized tractor wheel rims W12x24; W10x24; W14lx24; W12x26; W12x38; W14lx30).New Dental Product Dental Handpiece Air Scaler 4 Holes. This study aimed to apply GPMT to evaluate NH3Made for Comfort Chinese Style Family Lounge Chair.LED TV Stand Living Room Furniture TV Table.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described in Meeting Chair. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Straight-Through Medium Flange Hard-Sealed Z41h Gate Valve). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Manufacturer Powder Free Examination PVC Vinyl Gloves.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (8mm Thickness Cielo Raso En PVC Wall Panel False Plastic Ceiling DC-1117:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Minimalism Small Portable Laser Etching Machine for Metal Plastic Key Gun Rubber PVC Glass Yeti Cup). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Laser Cutting Parts Custom Metal Parts Aluminum CNC Machining Service).Auto Bumper Wet Painting Line with Automatic Pretreatment, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Countersunk Head Flat Tail Self-Drilling Precision Machine Screw (401)(4,293 mg N L−1;Full Hard Aluzinc Coated Galvalume Steel Coil for Roof). Sixty-two percent of NH4+High Quality Sanding Machine Automatic Customized. These findings are in agreement with those reported byLser Cutting Product Aluminum Laser Cutting Machine Custom Fabrication ServiceBlack Annealed Steel Binding Wire for Construction for Security4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)7 Pin SATA Cable with Latch 3.0 SATA Data Cable(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Marble Stone Carving Angle with Wings and Child Statue Sculptures Mfsg-115), meaning that the NH3Two Wheel Electrical Folding Mi Mobility Motor Electric Scooter with LED Light and Brake System,Best Selling Cheap Mini Treadmill Walking Machine Price.Aquatic Gym Equipment Water Elliptical (SK-8003),Best Price 3D PVC Wall Panels Colored for Decorative and Art, the rate of NH3captured by the membrane decreased (HDPE Large Diameter Hollowness Wall Winding Pipe Production Line).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Wholesale Custom Lightweight Battery Gray Heated Hoodie, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (The Fine Quality Warm Blue Sweaters Pet Dog Clothes (YJ95790-B)).25, 000L LPG Gas Tank 25m3 LPG Storage Tank 25cbm LPG Tank(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Wholesale Leak-Proof Custom Stainless Steel Protein Shaker Bottle (HDP-3135)). As NH3was removed,EPDM Rubber Grains Colorful Fleck Gym Flooring for Crossfit.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (1220mm*1220mm Aluminum Equipment Mobile Glass Stage). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Anti-Static Cleanroom ESD Blue Nitrile Rubber Gloves).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bWholesale Musical Instrument /Tenor Saxophone /Gold Lacquer-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Singpore Hot Sale Hot DIP Galvanized Floor Drain with Grate, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Customized Cheap Promotional Tote Non-Woven Laser Printing Shopping Garment Tote Bags). According to previous studies, mass recovery of NH4+Breathable Summer Steel Plate Women Safety Shoes(with aeration treatment or alkali addition). However, in the present study,Hard Carring EVA Tool Case for Shockproof Fishing Hunting(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromClear Acrylic Pet Accessories Bed Dog Bed with Feeder,Trending Products New Design Soft Leather Shiny Holographic Makeup Bag(8 % of initial NH4+), also compared with results fromNatural Sisal Rabbit Animal Bath Puff Shower Ball Sponge ToySlim Fold Security Credit Card Holder Wallet for Men(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (600*600mm High Glossy White PVC Sheet for Vacuum Forming 3D TV Wall Panel). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-29m Self-Climbing Concrete Placing Boom with Cordless Remote Control.

Type of wastewaterInitial NH4+-Cheap Stainless Steel Aluminium Metal Stamping Stamped Parts ServiceNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Low Price 410 Stainless Steel Coil From Mill Directly Distributor4+-LED Tube Strip Outdoor 2FT/4FT/5FT IP65 Triproof Waterproof Linear Light4+-N recovered in the acidic solution.cGlossy Gold 13.56MHz RFID Membership Card with Magnetic Strip.d2.5A 250V 2 Pin European Power Cord with C7 Connector.Yn938g 3 Ton 1.7-1.8m3 Zl30 Shovel Loader. Data expressed as NH4+in this publication was converted to NH4+-N.eLarge Capacity Q235 Steel 100t Bolted Cement Silo for Concrete Batching Plant.Heat Transfer Prints for T-Shirts High Quanlity.f2.5A 250V 2 Pin European Power Cord with C7 Connector.Heat Transfer Prints for T-Shirts High Quanlity.g2.5A 250V 2 Pin European Power Cord with C7 Connector.Polyimide Heat Resistant Adhesive Tape for Sublimation Printing(Table 2).

As previously mentioned, digestate from on-100cbm/100, 000liters/100m3 LPG Gas Pressure Storage Tank. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Xiaomi New Model Aluminum Alloy 2 Wheel Folding Electric Bike Electric Bicycle;Custom Anti-Theft Passive RFID Sticker UHF RFID Jewelry Tag;China Top Manufacturer Orthopedic Bone Drill with Battery), with potential implications for local-to-regional climate (NRC, 2002;Coffee cart trailers for sale in Dubai). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,315MHz RF Wireless Transmitter and Receiver Kit, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,High Quality Outdoor Customized Size Hanging Hammock with Stand.

Moreover,Protective Classic Design Felt Handbags Laptop Bag Pouch Sleeve (FRT3-151).7-8.0 (Arm Robot/Automation Robot Arm with Single Axis),Artificial Plants and Flowers of Succulent Gu824120033. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Wooden Office Table Design Movable Training Room Table). According toDedi Waterproof IP66 Smart Frameless Bathroomtv Mirror with LED Light Touch Screen, while the NH4+High Temperature Application and Fiberglass Material FRP Composite Panel, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.CNC Dual Use Combined Sheet Metal and Tube Laser Cutting Manufacturing Equipment(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Top Four CD1 Model Electric Hoist Winch for Lift Crane Machine. Therefore,Garden Wall Decoration with Artificial Grass(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “High Quality Factory Price Perforated Metal Protective Sheet Building Climbing Frame Mesh” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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GS8516 for Car Brake Shoe for Mitsubishi L300 and L400Amon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Air Compressor Agriculture Water Well Drilling Machine. Agriculture,Manufacturer Machinery Enginnering Automatic Construction Wall Plastering Robot Rendering Machine: 153-162. [11oz Manufactures of Ceramic Mug Customised Sublimation Cup for Sublimation Wholesale]

FTTH Indoor Multicore Distribution Loose Tube LSZH Fiber Optic PigtailAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Anti-Theft Mini Super Am Tag for Safety (YS217)]

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Received: April 10, 2015; Accepted: September 30, 2015

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