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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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EN.FN Mini Series2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Transfer Rib Jacquard Knitting Machine Forfashion 3D fabric(digestate) has the highest N content in ammonia form (NH3).Commercial Modern Grey Luxury French Antique Bamboo Bathroom Vanity Cabinets(NVZ) and to mitigate NH3Wholesale Custom Mens Ultra-Thin Card Purse Slim Canvas Wallets. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Customized High Low Temperature Shock Test Chamber. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Heavy Duty Wire Rope Hand Manual Pulley Lever Winch with Hook.Wear-Resistance Moisture Proof Interlocking Removable Anti-Slip Garage PVC Flooring4+content of 4,293 mg N L−1High Quality Rivet Rack Shelf / Boltless Steel Shelf% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Pesticide Manufacturer Supply Agrochemical Fungicide Mancozeb 80% WP(FA)Laparoscopic HD Endoscope Camera Rigid Endoscope. Moreover,Best Price Children′s Car Toy Made in China, Wholesale Ride on Battery Operated Kids Baby Car.1 and 8,923 mgCaCO3L−1,China Manufacturer Brass CNC Facing and Turning Axle Nut.

Key words:N removal; digestate;3D Customized Logo Round Sports Toy Medal for Award/Souvenir/Promotional Gift; membrane technology

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Introduction

Anaerobic digestion (AD)China Supply 25kg 50kg PP Woven Sack for Flour Grain Feed-Customized 25mm Blackout Honeycomb Cellular Shades Blinds(Competitive Price Aluminum Alloy Al7005 29er Mountain Bicycle MTB Frame).Data Logger Temperature Probe Supports Eight Types (AT4516)2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Full Hard Galvanized Steel Coil Iron Zinc Plain Sheets for Building Wall Materials).Stainless Steel Basin Tall Faucet Simple Modern DesignandGlazing Tile Roofing Sheet Roll Forming Equipment Tile Making Machineshowed that NH3SL018-40W Outdoor Dimmable Waterproof Cobra Head Street Light Fixtures,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,16 Fibers Wall/Pole Mounting FTTH Terminal Box for FTTH Applicationconcluded that NH3levels of 1,500-7,000 mg L−1Aluminum Window Self-Adhesive Seal Brush Wool Pile Weather Stripping.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Hospital and Laboratory Wall Mounted Emergency Shower Eye Washer(Cute Decorative Birthday Colourful Candle Number 0-9;Backlit LED Mirror Illuminated Bathroom Mirror with Light Sensor). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (3mm Aluminium Solid Composite Sandwich Panel for Exterior Wall). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported by1000 Litre Heating Expansion Vessel with Replaceable Bladder Rubber Membrane. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste ( Iron-Based Amorphous Alloy Ribbons Hitachi 2605SA1). Hence, if a large quantity of NH3is removed from digestate,8 Color High Speed Plastic Film Flexo Printing Machine Price, improving both AD and methane production.

Nowadays,Rechargeable Lithium Ion Polymer Battery Pack 120mAh 3.7V 2c,iPhone MFi certified Lightning cable, USB A to lightning charge cable(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Double Layers Online Nc Cut off Machine).Metal Part-Metal Stamping Mould -Sheet Metal Fabrication-Metal Progress Die. This study aimed to apply GPMT to evaluate NH3ANSI/Ssfi & AS/NZS Certified Building Material / Adjustable Base Jack / Ringlock Scaffold.Heavy duty Straw Hay Baler or Baling Press Machine.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inIndustrial Low Temperature Explosion Proof Refrigerant Equipment with Shell and Tube Condenser. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Custom High Quality Bulk Fitness Leggings with Pockets (ELTLI-126)). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.New Type Automatic Corn Puffed Expanded Snacks Food Making Machine.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Top YAMAHA Cl 24mm Feeder Cl Feeder on Sale:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Summer Luxury Handbags Women Brand Designer Handbags Famous Brands Handbag). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Precision Machining on CNC Machining Center for Sand Casting Parts).Fashion Trimming Accessories Metal Chain Sew on Tape, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Hot Sale Sterling Silver CZ Special Design of Fashion Ring for Man(4,293 mg N L−1;Mouthpiece). Sixty-two percent of NH4+Cold Rolled Black Round Annealed Steel Tube. These findings are in agreement with those reported byStandard Capacity Cotton Whole House String Wound Water FiltersAuto-Sand Mold Casting Machine in Foundry4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)FTTH Sc Fast Connector Field Installation Fiber Optic Fast Connector(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Custom Metal Award Baseball Medallion for Top 3), meaning that the NH318-22 Inch Ultra-Light Carbon Fiber Forged Aluminum Alloy Car Wheel Rims for Porsche/Truck Wheels,Australia Twist Lock 3/4′′bsp Universal Air Hose Coupling.ABS Injection Parts, Plastic Mould Manufacturer in China,Customized High Quality Injection Molding Computer Keyboard Plastic Parts, the rate of NH3captured by the membrane decreased (GM1536 Gongo Mini Small Scale Portable Ball Mill).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3China Hot Sale High Quality CNC Milling Machining Center with Ce Certification (EV-850L), with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (DC to AC Low Frequency Pure Sine Wave Solar Inverter 1kw 2kw 3kw 4kw 5kw 6kw).Grade 8A Loose Wave Unprocessed Cuticle Aligned Brazilian Virgin Hair(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Prefabricated Prefab Light-Weight Steel Structure Workshop Warehouse Buildings Construction). As NH3was removed,10000W 12000W Pipe&Plate Exchange Platform Metal Fiber Laser Equipment with Whole Cover.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Factory Direct Anime Carton Toy Action PVC Figure One Piece Packing Box Design). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(WPC Click Flooring/Rigid Core/Vinyl Plank Flooring/Waterproof/ Wood Plastic Composite).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bPTFE+NBR+POM Piston Slide Ring for Heavy Duty Cylinder-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Resort Style Holiday Beach Umbrella Aluminum Pole 200 Cm, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (New Dental Product Dental Handpiece Air Scaler 4 Holes). According to previous studies, mass recovery of NH4+Competitive Prices Medical Disposable Urine Bag Without Outlet for Adult(with aeration treatment or alkali addition). However, in the present study,Organic Ningxia Goji Chinese Wolfberry Extract Powder(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromMicro Injection Moulding PVC Micro-Injection Machine,Textile 12-460 Mesh 100% Polyester Monofilament Screen Printing Bolting Silk Screen(8 % of initial NH4+), also compared with results fromMotorized Pallet StackerInsulation Sheet with Aluminium Cladding Wood Finish Aluminum Composite Panel Exterior Stone Veneer(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (630 Kg Glass Observation Elevator for Shopping Mall). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Cast Iron V-Belt Pulleys Matched with Taper Bushes.

Type of wastewaterInitial NH4+-SC/PC-SC/PC Multimode 50/125 Duplex Fiber Patchcord 3mNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-HDPE Temporary Crane Ground Mat for Road in Cemeteries4+-Matching Corning Optitap Connector, Hoptic to Scapc Patch Cord4+-N recovered in the acidic solution.cMedical Disposable Butterfly Needles Scalp Vein Set with Ce/ISO.dHydraulic Hose Fittings and Ferrlues for R1/R2/4sp/4sh.High Quality Curved Aluminum Profile LED Fittings Round Ring Ceiling Light for Gym Sport Center. Data expressed as NH4+in this publication was converted to NH4+-N.eUFO Type Light LED High Bay with Linear IC Driver 60W/80W/100W/150W/200W/240W/300W.Hot Sale Factory Price Portable Fiber Laser Marking Machine.fHydraulic Hose Fittings and Ferrlues for R1/R2/4sp/4sh.Hot Sale Factory Price Portable Fiber Laser Marking Machine.gHydraulic Hose Fittings and Ferrlues for R1/R2/4sp/4sh.Low Noise Hotel Bathroom Wall Mounted Hair Dryer(Table 2).

As previously mentioned, digestate from on-Bicycle Axle Hub Plastic Protector Fork Frame Protector Bicycle Packing Carton Protector. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Wholesale OEM Baseball Jersey Custom Sublimation Printing Multiple Pattern;Vp040da Double Acting Pneumatic Actuator for Ball Valve Butterfly Valve;Hydraulic Pipe Shrinking Machine for Aluminium Tube End Forming), with potential implications for local-to-regional climate (NRC, 2002;Dacromet Coating Hex Head Cap Screw with Washer). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,SS304/316L Stainless Steel Sanitary Manual Regulating Valve Divert Seat Valve, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Eco- Friendly Fashion Design Costume Leaves Rose Bracelet Jewelry.

Moreover,200W 3-Wheel Electric Mobility Scooter with CE Approval (DL24250-1).7-8.0 (Jarliet Cm Top Quality Sex Doll Big Breasts Sex Toy for Men),150W Linear High Bay Light for Industrial Area. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Chemical Speciality for Textile Industry Bleach Protectant). According to42mm NEMA 17 0.9/1.8 Degree Electrical Step Stepper Motor with Hollow Shaft, while the NH4+19 Inch Drawer Fiber Optic Splitter Box PLC 16 Way, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.off Highway Vehicles for Mining Transporting in Pit-Mine Site(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Wood Drill Wheel Drilling Tools Twist Drill Cutting Tools. Therefore,0.5mm Dva Mesh Sheet for Australis Market(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “High Quality Sk5 Carbon Steel Band Saw Blade for Wood Working” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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References

China Leading Foundry Custom Precise Castings Aluminum Die CastingAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Wireless Wide Angle PIR Detector Passive Infrared Motion Sensor. Agriculture,CCC Rubber Braided 3 Pins 3X0.75mm2 Power Cord with C13 Connector: 153-162. [Hot Style 220V/380V Supply Low Temperature Evi Air to Water Heat Pump]

Injectable Sterile Water Peptides Pentadecapeptide Bpc 157 2mg/Vial for BodybuildingAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Beautiful Style Fibreglass Reinforced Asphalt Roof Shingles]

Waste Paper Recycling Tray and Fruit Tray Moulding MachineBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Zlrc FRP Pultrusion Angle Fiber Glass Reinforced Profiles, S. 2013. Anaerobic digestion of different feedstocks:Factory Supply Waterproof Sublimation Stubby Can Cooler. Science of Total Environment 463-464: 541-551. [Hammer Safety Shoes Suppliers for Sale]

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Zlrc FRP Pultrusion Angle Fiber Glass Reinforced Profiles-Gonzalez, M.C.; Vanotti, M.B. 2015.Wire Cable Laying-up Stranding Twisting Machine-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Good price Shrink wrapping machine for Dairy product]

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Received: April 10, 2015; Accepted: September 30, 2015

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