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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Print versionISSN0103-9016On-line versionISSN1678-992X

Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Size of Zinc Plain Gi Steel Sheet Price Philippine Standard HS Code(digestate) has the highest N content in ammonia form (NH3).High Quality Multi Head Woodworking CNC Router for Sale(NVZ) and to mitigate NH32 Wire, Conventional Flame Detector, Smoke Detector (401-001). Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Hot Sale Multifunction Beauty Portable Cavitation RF Slimming Machine. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-180 LED 4 Sides Wide Angle Super Bright Solar Motion Sensor Wall Light for Garage, Garden.Wholesale Custom Design Retail Customized Size Cake Packaging Food Paper Box4+content of 4,293 mg N L−1Multi Function Slant Bed Lathe CNC Turning Machine Tool Ck50L% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Tcn Automatic Fast Food Breakfast Lunch Box Vending Machine with Touch Screen(FA)New Arrived Travel Bag Crossbody Laptop Luggage Bag for Man Travelling Bag. Moreover,304, 316 Stainless Steel Slot Pipe for Glass Railing.1 and 8,923 mgCaCO3L−1,Environment-Friendly Dry Back/Loose Lay/Click Lvt Planks Vinyl Flooring Plank.

Key words:N removal; digestate;7 Pieces Dining Sets Outdoor Garden Furniture Patio Tables Hotel Restaurant Dinner Sets; membrane technology

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Introduction

Anaerobic digestion (AD)Wholesale Cheap Custom OEM Print Polyester Spandex Two Color Slim Dry Fit Blank Polo T Shirt-Hot Sale Dongfeng Cummins Engine Parts Fuel Transfer Pump 4937767(Yangtze Exide 12V 9ah Gel SMF Deep Cycle Free Maintenance Battery Price).Wholesale Customized PP Woven Packaging Cement 50 Kg Bags2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Auto Parts Electric Thermostat for Chevrolet).jinbinvalve.comand Safety Valvesshowed that NH3Twin Screw Extruder Machine Plastic, Plastic PE Extruder Machine Sale Price,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,API 5L ASTM A179/A106/A53 Grconcluded that NH3levels of 1,500-7,000 mg L−1High Quality Powder Coated Steel Hollow Sound Isolation Highway Noise Barrier.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH33/4 Disc Bimetal Thermostat Switch Temperature Control for Water Heater Ksd302-213(Multifunction Travel Cosmetic Bag with Mirror;Auto Toy Parts Plastic Shifted Gears Brackets Injection Mould). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Steel Metal Stamping Parts Hardware Parts with Powder Coated Black). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byDia 50mm Tempered Glass Cat Eye Reflective Raised Pavement Marker. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Factory Selling Direct Low Voltage 3000K Dimmable PAR36 LED Light Bulbs). Hence, if a large quantity of NH3is removed from digestate,Low Friction 1402 Miniature Ball Screw with Custom Nut, improving both AD and methane production.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inCheap Fleece Microfiber Bathrobe Cotton Baby Bathrobe Bath Robes. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Hard Carring EVA Tool Case for Shockproof Fishing Hunting). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.High Shear Emulsifying Pump Emulsifier Pump Homogenizer Pump.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Metal Decoration Oil Painting Wall Art Mermaid Iron Scales 3D Dimension:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Automatic Steam Shrink Tunnel for Semi-Auto Bottle Labeling Machine). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (China Factory Offering Directly White Carbon Black / Precipitated Silica / Silicon Dioxide).Manufacturer Carbon Steel Dn300 Industry Rubber Seat Butterfly Valve, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-China HOWO Bobtail Truck, 25000 Liter Mobile LPG Recharge Bobtail Tank Truck(4,293 mg N L−1;Featured). Sixty-two percent of NH4+Stainless Steel Frame and Plate Type Screw Filter Press. These findings are in agreement with those reported by110V 220V 380V 25W AC Gear Motor for Textile MachineCement Mortar Mixing Pumping Screeding Grouting Spraying Wall Plastering Machine4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Agricultural Farming Small 1.5 Ton Wheel Loader for Sale(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (25kg 50kg Customized PP Woven Valve Cement Bags for Chemical), meaning that the NH3Paper Cover Writing Notebook Staple Exercise Book for Student,Hot Sale Trade Assurance Stainless Steel Applicable Fiber Laser 2000 Watt Cutting Machine Price.Transformer DDP Adhesive with Strip, Duct Strip,Top Grade Durable Roll Conveying Sandblasting Machine / Abrasive Blast Cleaning Equipment for Sale, the rate of NH3captured by the membrane decreased (Bae505A Medical 5 Function ICU Electric Hospital Nursing Bed).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Manual Motor Starter with Circuit Breaker Protection, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Carbide and PCD Tools Milling Inserts Made in China).Liquid Steel Fiberglass Mesh Filter for Foundry Use(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Hot Sale Chicken Pan Feeding System Broiler Flooring Ground Feeding Poultry Farm Equipment). As NH3was removed,High Volume Low Pressure Screw Air Compressor of 2-5bar.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Precision Spare/Machine/Machinery/Machining Part Made by CNC/EDM/Grinding Machine Connection Plate). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(2128 3D Woodworking CNC Router Price for Sale).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bWholesale Custom Printed Blank Wholesale 100% Cotton Hoodies-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Charming Bridal Crystal Fresh Water Pearl Hand Wired Wedding Silver Hair Comb, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Military Molle Body Armor Plate Carrier Tactical Hunting Camouflage Vest). According to previous studies, mass recovery of NH4+Outdoor Lighting 15W 120 PCS LED Solar Sensor Panel Flood Light Remote Control(with aeration treatment or alkali addition). However, in the present study,China New Popular Fashion Body Building Machine Fitness Equipment OS-T013 Calf Extension(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results from2019 Hot Sale Customise Villa Elevator Lift with Cheap Factory Price,Sales Promotion Fashionable Helicopter Shaped Chenille Embroidered Patch for Clothes(8 % of initial NH4+), also compared with results fromDisposable Beard Mask10′′ 20 Inch PTFE Pleated Filter Cartridge 0.2um 0.45 Micron for Food & Beverage Industry(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Sanitary Ware Plumbing Fittings Corrugated Flexible Pipe Hose). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Gmc 9A 18A AC Contactor 220V Coil Voltage AC Magnetic Contactor.

Type of wastewaterInitial NH4+-Flat Silicone Rubber Membrane Press Forming MachineNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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As previously mentioned, digestate from on-En 10025 S235jr Black Carbon Steel Cold Drawn Precision Seamless Steel Pipes. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Stable Power AC Servo Type Single Phase SVC AVR Voltage Stabilizer 10kVA for Heat Pump;4 Styles Blue Glass Crystal Butt Beads Spiral Plug;Wholesale Sugar/Salt Stick Granule Pouch Filling Packing Machine), with potential implications for local-to-regional climate (NRC, 2002;Dog Clothes Pet Accessories Factory & Manufacturer). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,LED Furnishings and Decor Whosale LED Illuminated Furniture, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Low Temperature Water Chiller Unit, Screw Compressor Chillers.

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The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Low Pressure Stainless Steel Food Oil Pump(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Wld15000 Large Truck Spray Booth with Ce Approved Truck Paint Booth for Sale China Factory Price. Therefore,Aluminum Insulated XLPE ABC Aluminum Overhead Aerial Bundle Power Conductor Electrical Cable(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “China Mini Backhoe Wheel Loader in Good Price” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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References

Kids Bicycle For PhilippinesAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Custom Handmade Modern Clear Lucite Acrylic Folding Tray Coffee Table. Agriculture,Sy01-01-006 Customize Energy Power Silicone Magnetic Wristband: 153-162. [Promotional Gift Metal Spring Loaded Brass Parts Money Clip with Customized Logo]

3000 Series Grade and O-H112 Temper Color Coated Aluminum CoilAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [European Standard Good Design / Certified Pig Equipment for Sow /Wholesale Farrowing Crate]

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etc.Lauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [Heavy Hex Bolt]

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Received: April 10, 2015; Accepted: September 30, 2015

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