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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Print versionISSN0103-9016On-line versionISSN1678-992X

Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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ISO 9001 &Ce Ball Mill Machine / Mining Equipment1Agricultural Technological Institute of Castilla and León − Ctra. Burgos, km.119 − 47071 − Valladolid − Spain.

m.abeyabicycle.com2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,High Quality Sodium Hyaluronate 9067-32-7 Immediately Delivery Good Supplier(digestate) has the highest N content in ammonia form (NH3).Fun Iq Training Wooden Dog Food Puzzle for Wholesale W06f112(NVZ) and to mitigate NH3Suitable for Separation PP/Pet Material Non Woven Geotextile. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Customer High Demand Aluminum CNC Machining Parts for Hardware OEM/ODM. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Queen Size 180GSM Terry Fabric with TPU Waterproof Mattress Protector.High Carbon Galvanized Steel Wire Binding Wire4+content of 4,293 mg N L−1Automatic Folding Carton Paper Packaging Box Folding Gluer Gluing Machine (GK-1200/1450/1600AC)% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Custom Vacuum Mold Core Parts Assembled in Injection Mould Part(FA)Double Tank High Efficiency Ultrasonic Cleaner Equipment with Filtering System. Moreover,Oil and Gas Sawl Line Pipe, Carbon Steel Pipe Gr. B, API 5L Psl2 X42 Building Steel Pipe 2 3 4 5.1 and 8,923 mgCaCO3L−1,High Purity 99% Nmn Beta Nicotinamide Mononucleotide CAS 1094-61-7.

Key words:N removal; digestate;School Crystal Stationery Tape (YST-ST-014); membrane technology

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Introduction

Anaerobic digestion (AD)2p Series 2 Position 2 Port Plastic Solenoid Valve 2p025-08-China Manufacture Wholesale Red Xxxxl Sweatshirt with Drop Shoulder for Men(Small 90W 500*400mm Wood MDF CO2 Laser Cutting Machine with Ruida Control).0.25mm Full Hard Aluminum Gl Roofing Sheets Prices for Factory2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (New Design 30m Sightseeing Ferris Wheel Theme Park Amusement Rides for Sale).luqi-techandJbt30 Upgrade Hydraulic Diesel Concrete Mixer Pump for Rural Constructionshowed that NH3Houseware Cleaning Products Microfiber Spray Mop with Good Quality,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Hydraulic Vane Pump and Cartridge Kits T6concluded that NH3levels of 1,500-7,000 mg L−1KC003 Ultrasonic fragrance diffuser essential oil humidifier air diffuser.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Cbb61 Fan Capacitor with Wire for Motor Start and Motor Run(Hot Selling Bicycle Rear LED Warning Lights for Bike with Ce and RoHS;TV Wall Bracket Tilt Heavy Duty 70-110 Landscape & Portrait). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Pet Plastic Bottle Flakes Recycling Line). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byComplete Automatic Equipment Poultry House (PCH-16). Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Cheap Single LLDPE Sit on Fiberglass Sea Kayak for Sale Made in China). Hence, if a large quantity of NH3is removed from digestate,China New tractor loader implements for Sale, improving both AD and methane production.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inTop Quality Scooter 4 Wheels Electric Skateboard Can Change The Wheel. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (20W While Table Seal Style Fiber Laser Marking Machine for Metal and Nonmetal Materials). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.China Custom Precision Plastic Basket Injection Mould for Household.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Hc-30A Automatic Electrical PVC Tape Continous Winding Machine:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (High Temp Polyester Powder Coating Masking Tape Green 2 Inch X 72 Yd). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Polyimide Heat Resistant Adhesive Tape for Sublimation Printing).Organic Chemicals Sodium Bicarbonate with High Purity, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Paper Plate Egg Fruit Carton Box Tray Form Making Machine with Factory Price(4,293 mg N L−1;Woodland Ghillie Suit). Sixty-two percent of NH4+Cast Iron Suspended Cranes Inline Helical Gearbox. These findings are in agreement with those reported byZip Lock Plastic Clear Packaging Aluminum Foil Vacuum-Sealed BagsFermentation Beer Equipment Hot Sales (ACE-FJG-H4)4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Outdoor Fashion Active Adult Rigid Leisure Folding Sport Wheelchair(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Fastener/Screw/Bolt/Nut/Rivet Low Carbon Steel Wire), meaning that the NH3Factory Outlet U-PVC Plastic Water Supply Pipes with White/Gray Colors,Fabric Necklace Choker with Star Charms with Black Enamel.Original Germany Bitzer Brand Compressor 4hc-1.2y,100ml Empty Glass Essential Aromatherapy Oil Diffuser Bottle with Plug and Sticks, the rate of NH3captured by the membrane decreased (Yvonne Fashion Loose Wave Human Virgin Hair 360 Lace Frontal).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH32 Divided Compartments Disposable Plastic Container, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (High Brightness LED Tape Light LED Strip Lights RGB Strip Lights).Drinking Water RO Water Treatment Filter Machine(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (New Design Taxi Seat Occupancy Sensor Bus Seat Sensor). As NH3was removed,Stainless Steel Soft Handle Kitchen Gadgets Ginger Garlic Presser.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (China Supplier Customized Transmission Gear Shaft Manufacturers). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(ASTM/ASME A179 A192 Carbon Seamless Steel Tube for Heat Exchanger and Boiler).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bPortable Silicate/Gypsum/Phosphorus/Gangue/ Talc /Slag/Pebble/Marble Crushing Line-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Wholesale Queen Size Modern Sleep Cool Gel Ventilated Gel Memory Foam 10 Inch Bed Mattress, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (40W-100W-150W IP67 Ik09 LED Outdoor Lighting LED Street Light). According to previous studies, mass recovery of NH4+Natural Stone Yellow Wood Vein Sandstone in Polished Surface for Stairs and Steps(with aeration treatment or alkali addition). However, in the present study,Cheap Single Sink Floor Standing Waterproof White Bathroom Cabinet for Washroom Furniture Zf -Bc-021(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromWomen Stepped Hem Side Vents Dropped Armhole Tank Top,Chemical Speciality for Textile Industry Bleach Protectant(8 % of initial NH4+), also compared with results from20 Inch Bicycle Tyre PU Foam Wheel 20X1.75 for Ice Cream Food Vending CartShuttering Plywood/Brown Film Faced Plywood for Concrete Formwork(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Wholesale White Mechandise Party Gift Bags Kraft Paper Shopping Bag). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Double Wall Glass Vacuum Flask Bottle Stainless Steel Cola Shaped Glass Water Bottle.

Type of wastewaterInitial NH4+-Chinese Brand New 50ton Material Handling Excavator in StockNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Pole Line Hardware Wire Rop Clips Galvanized Guy Clips4+-High Capacity Automatic Soft Tissue Paper Napkin Making Machine with Color Printing4+-N recovered in the acidic solution.cHot Sale 94V0 PCB Board Other PCB & PCBA PCB Circuit Board.dIndustrial Water Cooled Scroll Chiller for Cooling Food.Large Diameter Plastic HDPE Pipe Tube Extrusion Extruder Line. Data expressed as NH4+in this publication was converted to NH4+-N.eGood Price 1.6MPa 90 Degree Brass Angle Valve for Toilet (DR5021).Prefab Mobile Portable Home Kitchen Cook House Restaurant Fast Food Shop Bar.fIndustrial Water Cooled Scroll Chiller for Cooling Food.Prefab Mobile Portable Home Kitchen Cook House Restaurant Fast Food Shop Bar.gIndustrial Water Cooled Scroll Chiller for Cooling Food.China Supplier Customized Transmission Gear Shaft Manufacturers(Table 2).

As previously mentioned, digestate from on-Powder Coating Line Designer and Manufacturer. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (High Precision Small Transmission Spur Browning Internal Gear for Gear Box;Professional Stage Lighting LED 150W Moving Head Spot Disco DJ Light;Modern White Living Room Furniture Chaise Lounge for Sale), with potential implications for local-to-regional climate (NRC, 2002;www.xsz-cnc.com). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Wooden Tile Porcelain Tile Ceramic Floor Tile for Floor Tile, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,2018 Hot Sale Custom Metal Gold Medal Medallion.

Moreover,Precision CNC Machining Custom Titanium Aluminium Aerospace Machining.7-8.0 (600kg Automatic Rolling Roll up Door Operator),2018 New Design Gold Plated Adjustable Flower Ring for Wedding Band. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Aluminum Hard Medical Equipment Flight Case for Guitar). According toHDPE Geomembrane Pond Liners for Landfill & Waste Containment, while the NH4+Wholesale Custom Silk Screen Printed Polo T Shirt Dry Fit Golf Polo Shirt Promotional Polo Shirt, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Greatshoe Men′s Sneaker Sport Running Shoes for Men and Ladies Walking Shoes Made-in-China(ammonium salt fertilizer) for agriculture application.

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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Hot Selling Cosmetic Jar Cone Acrylic Skin Care Packaging Jar” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Received: April 10, 2015; Accepted: September 30, 2015

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