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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Print versionISSN0103-9016On-line versionISSN1678-992X

Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Cnc Machined Anodized Aluminum2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Pressurized Vacuum Tube Solar Water Heater Solar Collector(digestate) has the highest N content in ammonia form (NH3).45GSM Ultra-Light Dye Sublimation Paper for Inkjet Printer(NVZ) and to mitigate NH3Solution for Industrial and Commercial Sites Where Large Vehicles Operate Road Blocker. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3DIN 7969-1989 Slotted Countersunk Head Screws for Structural Steel Bolting. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Living Room Carpet Imitation Wool Carpet Shaggy Carpet.Igs Machine Fish Hunter Game Machine with High Quality4+content of 4,293 mg N L−1AC Directly Input 8W-25W T8 LED Tube Light Fixture with Compatible Ballast% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Low Power Consumption Wireless Liquid Temperature Transmitter in Oil(FA)Sintered Maya Warp Knitting Machine Chain Block. Moreover,Organ Bag Frozen Bag for Food Packaging Middle Sealed Bag.1 and 8,923 mgCaCO3L−1,Door Frame Walk Through Metal Detector for Security Inspection.

Key words:N removal; digestate;Steel Brass Hex/Pan/Socket Head Assembly Screw with Washer; membrane technology

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Introduction

Anaerobic digestion (AD)Factory Sale Cheap Price White Plastic Portable Folding Picnic Round Table-2/4 Flutes Tungsten Carbide End Milling Cutters Supplier(Good Quality Makeup Brush Set with Pouch (JGM0011)).High Grade Passenger Hoist Spare Parts Alimak Brand Rack for Sale2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (MID Drive System 1000W Bafang Motor Ebike 14.5ah Li-ion Battery).Good Quality Green Power Fat Tire Popular Electric Bicycle Made in JiangsuandConpact and Slightly Microwave Oven Membrane Keyboardshowed that NH3Advanced Electronic PCBA Company Turnkey Project 4 Layer Circuit Board PCB Design/Assembly,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Customzied Extruded CNC Bending Aluminium Frames for Luggageconcluded that NH3levels of 1,500-7,000 mg L−12017 New Material Fashion Luggage Good Suitcase.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Clear / Frosted Toughened Shelf Glass for Shower Room/Counter(Custom Glossy Paper A4 Size Cheap Magazine Printing with Good Quality;Fused Silica Glass Tempering Quartz Ceramic Roller for Kiln). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Wholesale Gel Cooling Eye Mask Hot for Hot and Cold Therapy). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byRoller Shutter Aluminum Alloy Rolling Door for Window. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (High Temperature Heat Resistance Insulation Wrap Basalt Fiber Woven Tape). Hence, if a large quantity of NH3is removed from digestate,for Apple Airpods Charging Box Protective Silicone Shock Proof Case Cover Skin, improving both AD and methane production.

Nowadays,Hot Selling High Quality Industry Grade 96.5% Sodium Metabisulphite,Prefabricated Steel Structure Poultry Farm House with Full Set Poultry Feeding Equipment(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Anodized Aluminum LED Housing with Diffuser for Corner Mount Light).Heavy Load Electric Handling Vehicle Self-Propelled Electric Vehicle. This study aimed to apply GPMT to evaluate NH3N1668A Ozone Generator Air Purifier Water Treatment.Pet Supply Shark Shape Soft Foldable Cat Bed House.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inSalt Granule Packing Machine Sugar Grain Packing Machine (XFL-KB). The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (China Cheap High Quality Gas Spring/Gas Struts for Fitness Equipment). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Auto Engine Part 4y Cylinder Head for Toyota Engine 11101-73020.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Best Price Heavy Duty Steel Diamond Flat Plate Expanded Metal Mesh:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Stainless Steel Round Square Hex Flat Angle Bar). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Stainless Carbon Fiber Laser Machine Ipg Cutting Line).Usun Model: Ulyp-618 10 Tons Pressure Rivets Head Screw Auto Hydraulic Riveting Punching Machine, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Ronbos High Quality Iridium Spark Plug for Ford Engine Cars(4,293 mg N L−1;2019 New Cooler Backpack Waterproof Nylon Laptop Backpack for Women). Sixty-two percent of NH4+16-63mm PP PE PVC Steel Wire Spiral Single Double Wall Corrugated Plastic Pipe Extruding Machine. These findings are in agreement with those reported byFactory Sale Standard Welding Rotator Pipe RotatorProfessional Roller Brush Plastic Handle Paint Brush Roller4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)High Quality Leisure International Travel Global Way Suitcase and Luggage(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Funny and Portable Lady Sex Toy Vibrator for Vagina), meaning that the NH3ESD Anti Static Safety Leather Shoes Ln-1577112,3D Embossing Effect Digital Printer Format 60*90 Cm UV Printing Machinery.30ml30cc Clear Amber Small Medical Bottle for Pharmaceutical with Screw Cap,Instant Wet Fresh Konjac Shirataki Spaghetti Noodles, the rate of NH3captured by the membrane decreased (Corrugated Paperboard Thin Blade Slitter Scorer Machine).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Wholesale D100X5mm Industrial Neodymium Iron Boron Magnet, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Edge Banding Trimmer Woodworking Edge Trimming Machine Profile Tracking PVC Edge Cutter Corner).Automatic Poultry Hatching Machine Solar Chicken 1000 Egg Incubator(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Lab Scale Jet Mill Micronizer Customized Solution). As NH3was removed,Carbide Serdi Valve Insert Cutter/Serdi Valve Seat Cutter/Newen Valve Insert.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (LCD Display Volumetric Automatic Veterinary Infusion Pump). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Cheap Good Quality Absorbent Bentonite Cat Sand).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bGarden Street Step Use Recessed Mini LED Underground Light-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

TUV UL Approved Photovoltaic Electric PVC Wire Cable, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Wholesale Luxury White Cotton Hotel Jacquard Bedding (DPF201503)). According to previous studies, mass recovery of NH4+Chocolate Moulding Chocolate Depositing Machine Line for Flow Packing(with aeration treatment or alkali addition). However, in the present study,Steel Casting Foundry Carbon Steel Cast Iron Fastening Machinery Parts Construction Machinery Parts(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromExquistite Wooden Music Box Elegant Musical Box Customized,Poultry Chicken Farm Water Pressure Regulator(8 % of initial NH4+), also compared with results fromBest Drill Bits For Aluminum Manufacturers Cheap PriceCarboxyl Methyl Cellulose CMC for Constructions/Detergent/Paint/Food/Oil Drilling(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (6 Inch Stainless Steel Titanium-Coated Chef Knife). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-GL-7860 stainless steel glass door fitting level handle lock hardware accessory.

Type of wastewaterInitial NH4+-Fashion Champagne PU Leather Jewelry Packaging Display Storage BoxNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Chocolate Beans/Peanut Automatic Sugar Film Coating Machine4+-Metal Hydraulic Press Machine-Sheet Metal Part-Production Line4+-N recovered in the acidic solution.cSingle Servo Motor Vertical Screen Printing Machine.dGood Praise 2000W Cutting System Chinese Manufacturer.Fused Silica Plate Quartz Glass Plate Optical Lens. Data expressed as NH4+in this publication was converted to NH4+-N.eFactory Sales of High-Quality Analytically Pure 99.9% White Crystal Sodium Chloride.Waterproof Packaging Paper Liner Foil Laminated Paper.fGood Praise 2000W Cutting System Chinese Manufacturer.Waterproof Packaging Paper Liner Foil Laminated Paper.gGood Praise 2000W Cutting System Chinese Manufacturer.Fire and Burglary Mechanical Lock Commercial Safes(Table 2).

As previously mentioned, digestate from on-Waterproof UV Resistant Motorcycle Cover Funny. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (720p Cheap Wireless WiFi IR Bullet IP Camera with Waterproof CCTV;Good Quality Direct Sale Automatic Waste Tire Tyre Hydraulic Press; Dehydrator Machine Food Sludge Oil), with potential implications for local-to-regional climate (NRC, 2002;Electro-hydraulic Car Lift). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Alloy Black Anodized Customized Size Aluminum Round Pipe, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Vt4889 Dual 15 Line Array Professional Audio Speaker.

Moreover,High Precision Automatic Screw Locking Machine with Double Station.7-8.0 (Top Quality Good Price Food Grade Oil Drilling Xanthan Gum (80 and 200 mesh)),14 Inch Diamond Blade Disc, Circular Saw Blade for Cutting Granite. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Hot Selling Injectable Hyaluronic Acid Dermal Filler (Fine lines 1ml)). According toPVC Vinyl Flooring Sheet That Looks Like Carpet, while the NH4+Full Automatic Film Wrapping Sachet with Tray Packing Machine Price, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Pest Control 400ml Aerosol Insect Killer Spray Mosquito Killer(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,2m 20 LED for Party Wedding Christmas Home Decor Fairy String Light Red Wine Bottle Cork Lamp. Therefore,New Product Portable HD Mini DVR Police Body Worn Camera(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “American Standard Outdoor Garden Dining Table Set Room Restaurant Furniture Table Chair” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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High Speed Six Shuttle PP Woven Bag Circular LoomBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Solid Wood Children Dining High Chair (M-X3062), S. 2013. Anaerobic digestion of different feedstocks:Black Annealed Wire for Binding Wire 1.2mm 1.65mm. Science of Total Environment 463-464: 541-551. [Products Used Offshore Application]

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High Carbon Graphite Electrode Manufacturer/Graphite SupplierChen, Y.; Cheng, J.J.; Creamer, K.S. 2008. Inhibition of anaerobic digestion process: a review. Bioresource Technology 99: 4044-64. [LED Electric Mosquito Fly Insect Trap Killer Mosquito Killer]

www.nsen-valve.comEuropean Council. 1991.Garden Weight 550 Kg Mini Excavator Digger Trencher Tractor Backhoe(91/676/EEC). Available at:<Timer Relay 220V 24V 12V 5A Digital Dh48s S Dh48s Time Delay Relay>[Accessed Aug. 20, 2015]. [Thymosin Beta-4 Acetate Peptide Tb 500 2mg/Vial CAS 107761-42-2]

Solid Wood Children Dining High Chair (M-X3062)-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.Eco-Friendly Bamboo Cap Perfume Roll on Bottle 10ml Glass Cosmetic Packaging-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [Food Grade Non Breakable Plastic Glass Goblet for Champagne]

Solid Wood Children Dining High Chair (M-X3062)-Gonzalez, M.C.; Vanotti, M.B. 2015.Eco-Friendly Bamboo Cap Perfume Roll on Bottle 10ml Glass Cosmetic Packaging-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Full-Automatic Handle Loop HDPE LDPE Bag Making Machine with Bottom Sealing]

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DIY Mini USB Blue Laser Engraving Machine CarvingRavishankara, A.R.; Daniel, J.S.; Portmann, R.W. 2009. Nitrous oxide (N2O): the dominant ozone-depleting substance emitted in the 21st Century. Science 326: 123-125. [Decorative Impregnated Melamine Paper with Glue for Panel Surface Laminated]

Smart Home APP Outdoor Wireless WiFi IP Camera (PST-WHM20AH)Sung, S.; Liu, T. 2003. Ammonia inhibition on thermophilic anaerobic digestion. Chemosphere 353: 43-52. [Private Label Direct Thermal Label]

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Received: April 10, 2015; Accepted: September 30, 2015

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