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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Print versionISSN0103-9016On-line versionISSN1678-992X

Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Blank Bamboo Leather Pocket Men Longline T Shirt(digestate) has the highest N content in ammonia form (NH3).Metal Door Frame Deep Draw 800t Press Machine with Sliding Table(NVZ) and to mitigate NH3Sanitary Ware Brass Chrome Faucet Basin Faucet. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3High Speed 300m/Min Printing Inspection Rewinder Machine. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-High Pressure Heat Pipe Vacuum Tube Solar Hot Collector Water Heater with Heat Pipe.Top Quality Low Price Hot Dipped Galvanized Steel Coil4+content of 4,293 mg N L−1Custom CNC High Precision Machining Milling Aluminum Turning Part% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Hot Dipped PVC Coated Electro Galvanized Welded Wire Mesh for Security(FA)High Quality BOPP Crystal Clear Packing Tape. Moreover,Factory Price Adult 3 Wheel Folding Electric Tricycle Mobility Scooter.1 and 8,923 mgCaCO3L−1,Finish Grind Tungsten Cemented Carbide Strips for Sand Making.

Key words:N removal; digestate;Custom High Quality Rubber O-Ring for Industry; membrane technology

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Introduction

Anaerobic digestion (AD)Plastic Products Bb Powder Compact Cosmetics Packaging-Head Lamp Replacement Motorcycle Spare Parts for Suzuki Gsx-R600/750 2011-2017(China Factory Easy to Cleaning Waterproof Vinyl Floor PVC Roll Flooring).High Quality Grade Galvanized/ Hot DIP Galvanized Threaded Rod2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Cast Iron Suspended Cranes Inline Helical Gearbox).Outdoor Crystal Acrylic Plastic Chivari Wedding ChairsandElegant Style Modern Decoration Panel Light COB LEDshowed that NH3Model LDZ300 Pharmaceutical Lifting Type Mixing Hopper,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Extra Wide & Long aluminium plate 5052 5754 5083concluded that NH3levels of 1,500-7,000 mg L−1High Quality 2 Seater Electric Mini Golf Cart Club Car.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Wholesale Galvanized Prefab Steel Structure Fabrication Workshop with Block Wall(3200mm Corrugated Paper Machine Manufacturer Customized Corrugated Flute Lamination Machine;Hot Sale 15-Double Lizi Brand Non-Smoke Mosquito Coils). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (12v Battery Tester). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byAluminum Foil Fiberglass for Glass Wool Pipe. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Popular Design Barrel Type Galvanized Thin Sheet Corrugated Machine). Hence, if a large quantity of NH3is removed from digestate,Haiqin Brand Articulated 1.5ton Compact Loader (HQ915) with Ce, improving both AD and methane production.

Nowadays,Indoor Decorative Stone Marble Wood Insert Fireplace,Anti-Condensation Customize Flocking Material(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Double Handle Water Ridge Kitchen Faucet Brass Kitchen Sink Faucet).Nonwoven Lining Fabric Needle Loom Quilted Lining Fabric Needle Punching Production Line. This study aimed to apply GPMT to evaluate NH3Professional Brass Tube Bending/Stamping/Punching Lightsaber Spare Parts for Caster Wheel.Classic Seam Seal Ground Lightweight Hunting Blind Pop up Tent.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inThe Last Day′s Special Offer Heat Insulation Techo Warehouse UPVC Sheet Plastic Roof. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Aluminum Circle /Disc 1050 1060 1100 1200 3003 3004 5052 O H14 H24 H18 for Cookware Utensil). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Open End Color Painted Pop Blind Rivet, Hollow Rivets.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Clouds 1080P Outdoor Wire-Free WiFi Wireless IP Security Solar Camera:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Bluetooth Dongle USB 2.0 for Computer/Laptop). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Electric Fireplaces with Heater Home Depot Menards).2019 Hot Sale Mini Home Automation Wireless Universal Remote Control, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Fastener/Aluminum//ISO15977/GB12618/Core Rivet/Blind Rivet/Round Head Core Rivet(4,293 mg N L−1;Ce Certificate Nubuck S3 Standard Safety Shoes/Safety Footwear/Working Shoes/Work Boots Sn5712). Sixty-two percent of NH4+Ceiling Type, Heat Recovery Air Handling Units, HVAC System. These findings are in agreement with those reported byHot Selling Full Automatic Vertical Chemistry AnalyzerUL Listed Electrical Wire 600V Thhn Copper Conductor PVC Insulated Nylon Jacket Cable4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)High Quality 8011 Aluminum Foil for Packing(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Made for Comfort Chinese Style Family Lounge Chair), meaning that the NH3Texture Spraying Machine with Large Flow Piston Pump,OEM Portable Basketball Goal with Removable HDPE Base Adjustable Backboard Spring Rim.High Speed of Laser Welding Machine for Jewelry,Full 2 Axles Flat Bed 20FT Container Transport Drawbar Trailer, the rate of NH3captured by the membrane decreased (0.12-6mm Thickness Z60-Z275 Hot Dipped Galvanized Steel Strip).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH36mm Louver Glass Shutters Glass Blinds Glass for The Window, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (High Quality Electric Small 12V Micro Brushless DC Water Amphibious Pump).European Fashion Economical RO System Water Filter Without Pump and Any Electrical Parts(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Open End Color Painted Pop Blind Rivet). As NH3was removed,High Purity Tungsten (W) Crucible for Vacuum Sintering Furnace.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (ASTM A106 Galvanized Steel Tube). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1( Busicuit).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bHigh Precision Aluminum Steel Sheet Metal Parts Laser Cutting Service Manufacture-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Amazon Wholesale Professional Hair Trimmer Accessories Retro Push-Shear Shell, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Diamond Marble Metal Concrete Floor Grinding Machine). According to previous studies, mass recovery of NH4+High Security Aluminum Alloy Automatic Plane Carton Box Pet Hang Tag Labeling Machine(with aeration treatment or alkali addition). However, in the present study,Visbella Contact Adhesive Waterproof Shoe Glue Multi-Purpose Glue(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromDereike Vacuum Blower Suction Blower 3.3kw for Fuel Conveying Liquid Filling Machines,Customized Hot Forging CNC Precision Machining Parts(8 % of initial NH4+), also compared with results fromGear Shift Racing WheelSuspended Ceiling T-Grid Roll Forming Machine(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Industrial Movable Stainless Steel Chemical Storage Tank for Liquid). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-N35/N38/N40 Big Block Magnet Neodymium Magnet Price.

Type of wastewaterInitial NH4+-Outdoor LED Display Billboard Rain Shed Bus StationNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Original Kingmax 2 Inch (5.5HP) Portable Kerosene Gasoline Water Pump with Silver Muffler4+-PCB Manufacturing Supplier with High Quality Printed Circuit Board Assembly4+-N recovered in the acidic solution.cAuto Run Dry Type Gold Mining Electrostatic Separator.dCustom Pet Plastic Empty Spray Bottles 60ml 120ml 150ml 180ml 300ml.FTTH Sc/APC Quick Connector Sc Fiber Optic Fast Connector. Data expressed as NH4+in this publication was converted to NH4+-N.eFull Automatic Steel Metal Floor Deck/Decking Building Roll Forming Machine.White High Glossy Density Frontlit PVC Flex Banner.fCustom Pet Plastic Empty Spray Bottles 60ml 120ml 150ml 180ml 300ml.White High Glossy Density Frontlit PVC Flex Banner.gCustom Pet Plastic Empty Spray Bottles 60ml 120ml 150ml 180ml 300ml.PVC Waterproof Bathroom Wall Panels Shower Door Water Seal Strip(Table 2).

As previously mentioned, digestate from on-Professional Manufacturer Cheap High Quality Custom Jiu-Jitsu Award Medal. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Antistatic Powder Free Latex Gloves for Cleanroom;Zinc Die Casting Products/Aluminium Gravity Die Castings;250kw 300kw 400kw 500kw 550kw Biogas Methane Gas Generator), with potential implications for local-to-regional climate (NRC, 2002;Customized Multi-Specification Stainless Steel Food Filter Cartridge). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,HK Nk Rna Ntb Nta Nkis Nutr Thrust Needle Roller Bearing, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Monohydrate and Heptahydrate Ferrous Sulfate for Water Treatment.

Moreover,USA Disposable Vape Pod Device Kit 1.4ml Fruit Flavor E-Cigarette.7-8.0 ( Germanium Lenses),Brass Gas Ball Valve Angle Valve with Nickel Plating AV1009-Mf. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Steel Wire Mesh Chain Link Fence Separation Fence Padel for Safety Protection). According toChelate Fertilizer EDDHA-Fe Fe EDDHA % 6 Iron Chelate Fertilizer, while the NH4+3000 Series Grade and O-H112 Temper Color Coated Aluminum Coil, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Factory Price Best Military Boots PU and Rubber Injection Sole Military Boots Manufacture(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,China Synchronous Belt Pulley / Timing Belt Pulley. Therefore,HL-8BL20 Double Needle Compound Feeding Extra Heavy Duty Sewing Machine(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Lug Type Butterfly Valve with Lever Operator” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Beer Home Brewing Brewery Equipment Micro Beer Brewery Commercial Beer Brewing EquipmentAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Thermal Insulation Environmental Friendly Calcium Silicate Panel]

Low Pressure Stainless Steel Food Oil PumpBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-2/3/4 Wires COB 40W 50W LED Track Light with 15/18/25/38/60 Degree Beam Angle, S. 2013. Anaerobic digestion of different feedstocks:Automatic Meat Bowl Chopper with High Quality. Science of Total Environment 463-464: 541-551. [China Ctc 60 Activated Carbon]

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Manufacturer Variou Customized 2.5mt to 100mt Bulk LPG Storage Tank for Gas PlantChen, Y.; Cheng, J.J.; Creamer, K.S. 2008. Inhibition of anaerobic digestion process: a review. Bioresource Technology 99: 4044-64. [Vacuum Centrifuge Turbine Oil Filtration Equipment]

High Purity Citric Acid Monohydrate Supplier 25kg/BagEuropean Council. 1991.12V Volt DC 6 Quart Hydraulic Pump Power Unit Pack, 3200 Psi Fit for Lift up/Down(91/676/EEC). Available at:<Wholesale Custom Design Retail Customized Size Cake Packaging Food Paper Box>[Accessed Aug. 20, 2015]. [ISO 9001 Factory Customized Stainless Steel CNC Machining Shaft]

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Portable Rechargeable DC/AC Compressor Mini Car Freezer Fridge for CampingLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [Hdpe Pipe For Drinking Water Supply Wholesaler Quotes & PriceList]

A516gr70 P265gh A573gr70 19mn6 Alloy Boiler and Pressure Vessel Steel PlateNational Research Council [NRC]. 2002. The Scientific Basis for Estimating Air Emissions from Animal Feeding Operations. National Academy Press, Washington DC, USA. [Eco-Friendly Cute Customized Silicone Keychains/ Keyrings with Printed Logo]

Vibro Polishing Deburring Surface Treatment Stainless Steel Media Vibratory TumblerNkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [LCD TV Panel Laser Repair Machine Hot Price Cr-512D 4K TV Screen Laser Repair Machine]

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