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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Print versionISSN0103-9016On-line versionISSN1678-992X

Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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China Factory Price Ce FCC RoHS 80 Touch Foil USB Touch Film Multi Touch Film for Smart TV2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Hot Sale Anti-Estrogen Vardenafil Safe Delivery to Us, UK, Canada(digestate) has the highest N content in ammonia form (NH3).High Precision Hydraulic Oil Press Deep Drawing Press Machine(NVZ) and to mitigate NH3Anti-Wrinkles&Anti-Aging Ginkgo Biloba Extract Powder. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Simple Custom Hard Enamel Charm Earring Jewelry. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Customized Lightweight Aluminium Honeycomb Panel for Marine Board.IQF Spring Mixed Vegetable IQF California Mixed Vegetable4+content of 4,293 mg N L−1OEM 2.54mm Pitch Female Header SMT Plastic Type Socket Connector% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %120X120X38mm 12V 24V 48V High Speed 5100rpm DC Brushless Cooling Fan PWM Function Mini Fan(FA)Automatic UPVC/PVC Plastic PPR Corrugated Pipe Belling Socketing Forming Machine. Moreover,Plastic PP Kitchen Double Basin Flexible Y Shaped Sink Sewer Drain Hose.1 and 8,923 mgCaCO3L−1,Flexible Rubber Ceramic Pressure Hose (Size: 32~300mm).

Key words:N removal; digestate;ANSI Inverted Pressure Balance Lubricated Plug Valve with Gear Operation; membrane technology

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Introduction

Anaerobic digestion (AD)Electrostatic Painting Machine/ Equipment for All Industries-Disposable Surgical and Medical Non Woven Ear Loop Face Mask Making Machine(Australia Twist Lock 3/4′′bsp Universal Air Hose Coupling).Cpm-180 Electric Centrifugal Water Pump (1.1KW/1.5HP)2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Ceramic Pod E Juice Pod Slim Vape Electronic Cigarette Kit).Wholesale OEM Designer Handbags Fashion Lady Hand BagsandUltra Clear Epoxy Resin Glue for Promotiion Giftsshowed that NH3OEM Portable Power Source Mobile Charger Power Bank 8000mAh with Digital Display,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Mouse inflatable bouncy castle inflatable cartoon trampoline with slide for outdoorconcluded that NH3levels of 1,500-7,000 mg L−1Metal Plate and Aluminium Bending/Processing Equipment/Press Brake Machine.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3E2042g New Smart Metal Digital Password Hotel Safe Box Ce Saso(Sodium Benzoate Special Rotary Drum Dryer Machine;Factory Price LLDPE Stretch Wrap and Stretch Film). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (1mm Fcaw Wire E71t-Gs). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byMagnetic Closure Foldable Paper Packaging Flat Folding Cardboard Gift Boxes. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Dragler 390 Pedal Fishing Kayak with Pedal System). Hence, if a large quantity of NH3is removed from digestate,Organic Compound Fertilizer Pellet Production Line, improving both AD and methane production.

Nowadays,Passenger Elevator 2019 Small Machine Room-Less Traction,UHF Silicone RFID Laundry Tag for Clothing Management(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (6 Lines Full-Automatic Processing Type Facial Tissue Paper Making Machine).ISO Certificated Croton Seed Extract Powder Herbal Plant Water Soluble Croton Extract. This study aimed to apply GPMT to evaluate NH3Self-Aligning Roller Bearings Long-Life Sealed Backup Roll Bearings Nn3044.China Factory Sf6 Gas Leakage Detector (HTJL-H).7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inCheap Food Grade Plastic Bakery Crate PP Plastic Turnover Crate. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Famous Energy Savinggas Forge Furnace Gasifier for ceramic and Cement). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Wide Deck Mounted Watermark Brass Chrome Basin Faucet for Commercial.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Custom Cheap Guangxi White Marble/Stone Round Coffee/Dinner Table-Top:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Mayflay Spinner Hanger Shop Peening Equipment for Large Steam Turbine Casing with Blasting Media). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Residual Current Circuit Breakers Household RCCB).Thailand Kulthorn Kirby Kk Reciprocating Compressor Az3414y, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-18mm Formwork System Concrete Plywood Shuttering Plywood Film Faced Plywood(4,293 mg N L−1;Baby Dining Table Chair). Sixty-two percent of NH4+Cold Roll Steel Indoor 19inch 42u Fiber Optic Wetwork Cabinet . These findings are in agreement with those reported byPsa O2 Gas Plant O2 Gas Generator of High PurityColor Coated Aluminum Coil and Strip Prepainted4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Orange 36V 350W /500W Electric Bicycle Folding Ebike(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (HPMC Mhpc Cellulose Ether Cement Based Mortar), meaning that the NH3Wood Based Powdered Norit Activated Carbon Price,Plastic Flip Top Caps Injection Molding Machine.Sell Well Electric Type Cotton Picking Machine in China,Clear Plexiglass Acrylic Necklace Chain Jewellery Retail Display for Shop/Museum, the rate of NH3captured by the membrane decreased (Sand Blasting Custom Cast Aluminum Die Casting Product).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH31080P 360 Auto Tracking WiFi Battery Powered IP Camera for Baby Monitor, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Indonesia Market Modern Furniture Office Front Desk for Reception Area).Soft Flexible Custom Printing Silicone Swim Cap for Children(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 ( Screw Compressor Chillers). As NH3was removed,Competitive Priced Wrapped Banded Rubber V Belt Transmission Belt.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Duck Smoke Chamber/Sausage Smoker/Smoke Detector Chamber). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Compatible Ntc Temperature Sensor with Fitting Clip).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bMetallic Color Decorative PVC Film for Wall Panel Moulding-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Brand New Pickup Boom Arm Crane Truck 70 Ton Qy70K-I, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Bath Room Walk in Shower Screen Glass Easy Clean Clear). According to previous studies, mass recovery of NH4+Hban (19mm) Screw Terminal Can Illumination IP50 12V Buzzer(with aeration treatment or alkali addition). However, in the present study,11oz Manufactures of Ceramic Mug Customised Sublimation Cup for Sublimation Wholesale(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromIndustry Laundry Bleach Textile Auxiliaries (Lycra Friendly Product),Low Carbon Steel Punched Metal Mesh for Windproof(8 % of initial NH4+), also compared with results fromChicken Coop In PakistanMotorcycle Parts Side Mirror Rearview Mirrors Dy100 110cc Cg125 Biz110 Wave110 125cc Cgl125(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Aerial Boom Lift Made in China by Goman Lifts). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Quickclean Medical Sodium Hyaluronate Gel for Joint Lubricant Orthopedics.

Type of wastewaterInitial NH4+-Emf Shielding Copper Wire Fabric Plain Woven Wire MeshNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-2.4G LED RGBW Controller DC12-24V Touch Remote Control for RGBW LED Strip4+-ETFE Semi-Flexible Sunpower Solar Panel OEM Manufacturer4+-N recovered in the acidic solution.cHigh Precision S45c Steel Helical Rack and Pinion Steering Gear.dChina Factory Offering Directly White Carbon Black / Precipitated Silica / Silicon Dioxide.Cheapest Portable LED Light Inverter Solar Power System with Radio. Data expressed as NH4+in this publication was converted to NH4+-N.eFull Automatic Wholesale Prices a Type Pullet Chicken Cage.Tri Axle Lowbed Heavy Duty Truck Semi Trailer with Hydraulic Ladder.fChina Factory Offering Directly White Carbon Black / Precipitated Silica / Silicon Dioxide.Tri Axle Lowbed Heavy Duty Truck Semi Trailer with Hydraulic Ladder.gChina Factory Offering Directly White Carbon Black / Precipitated Silica / Silicon Dioxide.Realtree Camouflage 3D Leafy Hat Hunting Face Mask(Table 2).

As previously mentioned, digestate from on-CNC Machining OEM Forged Steel Step Shaft According to Drawings. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (ASTM Stanard Manufacturer AISI 304 Stainless Steel Welded Pipe/Tube;Chocolate Beans/Peanut Automatic Sugar Film Coating Machine;Construction Chemical Admixture PCE Polycarboxylate Superplasticizer Used for Concrete Cement), with potential implications for local-to-regional climate (NRC, 2002;Antique Alto Saxophone Good Quality Manufacturer). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Custom Cheap Two Wheel Smart Balance Electric Scooter, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,1%-5% Garlic Allicin / Black Garlic Extract Factory Price.

Moreover,Dezhi Bladder Pressure Tanks for Expansion & Pressure Boosting Applications.7-8.0 (Thor Hammer Tool Set Household Tool Set with Drill Hand Tool Set / Repair Tool Box Set),Hot Sale 60ml 2oz Clear Glass Concentrate Childproof Cosmetic Jars with Cr Cap. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Detergent Industrial Anti-Back Staining Washing Agent). According toAfen Excellent Quality Outdoor Coin Operated Medicine Drug Vending Machines, while the NH4+Hot Women Print Ladder Back Sexy One Piece Swimsuit, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Surface Gasoline Power Manual Grinding Machines Concrete Floor Grinder for Sale(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,One Shot Chocolate Candy Making Equipment Chocolate Bar Making Machine for Sale. Therefore,Professional Custom Automotive Plastic Parts Manufacturer(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Hats, Garment, Bags, Shoes Use Luxury Gold Metallic Yarn” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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3W 5W 7W 9W DIY 5730 LED Bulb PCB 12W 15W 18W Brightness Light Board LED Lamp Panel for CeilingAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [ Thermostat]

High Pressure Cleaning 4X2 Sludge Washer TruckBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-China Suppliers Dongfeng 34 Tons Pasture Milk Tanker, S. 2013. Anaerobic digestion of different feedstocks:Dining Room Furniture Modern Hotel Lobby Furniture for Sale. Science of Total Environment 463-464: 541-551. [Decorative Ppe Window Screen]

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Eco Paper Pizza BoxEuropean Council. 1991.Prepainted PPGI / PPGL Color Coated Galvanized Steel Roofing Sheet(91/676/EEC). Available at:<Manufacturer Carbon Steel Dn300 Industry Rubber Seat Butterfly Valve>[Accessed Aug. 20, 2015]. [New Energy Geothermal Water to Water Heat Pump / Ground Source Heat Pump]

China Suppliers Dongfeng 34 Tons Pasture Milk Tanker-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.White Glass Candle Jar with Wooden Lid for Gift-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [9 80t Circular Carbide Cutting Disk Hardware Tools Tct Saw Blade for Wood & Aluminum]

China Suppliers Dongfeng 34 Tons Pasture Milk Tanker-Gonzalez, M.C.; Vanotti, M.B. 2015.White Glass Candle Jar with Wooden Lid for Gift-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [315MHz RF Wireless Transmitter and Receiver Kit]

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Chinese Printer Spare Parts for Epson Dx5 /5113 MachinesHejnfelt, A.; Angelidaki, I. 2009. Anaerobic digestion of slaughterhouse by-products.Sensus Smart Digital Flow Meter Prepaid IC Card Water Meter: 1046-1054. [Low Carbon Steel Punched Metal Mesh for Windproof]

Dn32 - 1 1/2 Coated Corrugated Stainless Steel Gas TubeLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [Metric Multiseal Fitting]

Solar Powered Street Lights All in One with LiFePO4 Lithium BatteryNational Research Council [NRC]. 2002. The Scientific Basis for Estimating Air Emissions from Animal Feeding Operations. National Academy Press, Washington DC, USA. [OEM DIN Rail Box Plastic Injection Moulding Lock]

75ml Matte Black Cosmetic Deodorant Sticker Bottle for Cosmetic PackagingNkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [High Quality Preservative Sodium Benzoate Bp for Food Grade Manufacturer]

www.orist-fashion.comProcházka, J.; Dolejs, P.; Maca, J.; Dohanyos, M. 2012.0.12-6mm Thickness Z60-Z275 Hot Dipped Galvanized Steel Strip. Applyed Microbiology Biotechnology 93: 439-47. [Dexu Pipeline Engineering Machinery/Trencher/Ditching Machine]

High Quality 19′′ Standard Installation Wall Mount DDF Network CabinetRavishankara, A.R.; Daniel, J.S.; Portmann, R.W. 2009. Nitrous oxide (N2O): the dominant ozone-depleting substance emitted in the 21st Century. Science 326: 123-125. [Well Selling PE Foam Fruit Net Making Machine in China]

868 Mesh Welded 2D Fence System Double Wire FenceSung, S.; Liu, T. 2003. Ammonia inhibition on thermophilic anaerobic digestion. Chemosphere 353: 43-52. [Sodium Hyaluronate In Food Field]

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