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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

Salvador Pneumatic Design Butterfly Valve in Different Materials

AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,0.5mm Welding Machine Price List Stainless Steel Pipe Price List(digestate) has the highest N content in ammonia form (NH3).Customizable Logo Luxury Watch Mechanic Movement Hollow Steel Mens Watch (JY-G037)(NVZ) and to mitigate NH3Custom Articulating Tilt Swivel TV Wall Swing out Mounting Bracket with ISO. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Electro Galvanized Cyclone Wire Chain Link Fence for Building Materials with SGS and White Color. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Automatic 12 Heads Pear Juice Filling Machine in Pet Bottles.Bottom Lift Tubular Big Ton Bag FIBC Bulk Container Bag4+content of 4,293 mg N L−1304 Stainless Steel Frame Inclined Conveyor with Modular Plastic Belt% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %20W While Table Seal Style Fiber Laser Marking Machine for Metal and Nonmetal Materials(FA)Magnetic Stripe Card Cmyk Offset Printing Card. Moreover,Steel Galvanized Kwikstage Scaffolding in Hot Sales.1 and 8,923 mgCaCO3L−1,Halogen Free Flame Retardant Ammonium Polyphosphate / Crystal Phase II (n>1000).

Key words:N removal; digestate;A5 Custom Printed Hardcover Diary Notebook with Back Pocket; membrane technology

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Introduction

Anaerobic digestion (AD)Hydroxypropyl Methyl Cellulose HPMC for Tile Adhesive, Gypsum, Detergent, Wall Putty Mortar-Multi Color Personal Alarm 120dB with Keychain for Woman Kids The Aged Hw-3212(Xinyujie High Speed 4028 40mm 5V 12V DC Axial Car Cooling Fan 40X40X28mm 1.6 Inch).Micro End Mills Small End Mills Tool Carbide Cutter 0.1-0.9mm2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (HL-8BL20 Double Needle Compound Feeding Extra Heavy Duty Sewing Machine).Acrylic Office Chair With Wheels High Quality SupplierandGood Quality Car Used Small Solar Rechargeable DC 12 Volt Car Fanshowed that NH3China Wholesale Luxury Folding Matte Cardboard Gift Box with Ribbon Closure,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Fireproof Colorful High Pressure Laminate HPL Boardconcluded that NH3levels of 1,500-7,000 mg L−145-400W IP65 High Power LED Explosion Proof High Bay Lighting for Indoor Industrial Use.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Amazon Beer Bottles Vagina Sex Masturbation Cup(Nmsafety White Nylon PU Coated Factory Assembly Work Glove;Little Kid Infant Flyknit Children Baby Boys Girls Shoes). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Refrigerant R134A Gas Refrigerator R134 Refilling for Sale). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byStamped Metal Parts-Punching Die-Hardware Products-Metal Laser Cutting Parts. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Heavy Duty Steel Foldable Stair Climbing Hand Truck Hand Pallet Truck Rubber Wheel (YH-HK013C)). Hence, if a large quantity of NH3is removed from digestate,Fast wall charger wirh PD 60W and QC 3.0 18W for mobile phone, improving both AD and methane production.

Nowadays,2019 Professional Cosmetic Product 11 Packs Set White Makeup Brush,Prefab Cheap Container House for Labor Camp with Toilet(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Double-Sided HASL LED PCB Circuit Board for Lighting Industry).2-5mm Marble/Granite Arc Aluminum Honeycomb Composite Panel/ Tile for Column. This study aimed to apply GPMT to evaluate NH3Lightweight M370-27speed Aluminum Alloy Mantis Mountain Bike 29er.Pump Seal Plate for Air Compressor Oil Pump Shaft Seal Valve Plate in Dongguan.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described in220mm Length 90 Watt LED Corn Bulb with Cool White. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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60%

Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (High Output Tree Stump Crusher with Good Quality). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Cheap Best Quality Absorbent 1-3.5mm Ball Shape Bentonite Cat Litter.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Greatshoe Men′s Sneaker Sport Running Shoes for Men and Ladies Walking Shoes Made-in-China:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Usun Model: Ulyp-618 10 Tons Pressure Rivets Head Screw Auto Hydraulic Riveting Punching Machine). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Anti Glare LCD /LED/TV Display Touch Screen Glass Panel).Fashion Cactus Shaped Plain Silver Cubic Zirconia Earrings for Party, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-High Qulaity Perforated Template Formwork/Rib Mesh for Building Construction(4,293 mg N L−1;www.gsbracefactory.com). Sixty-two percent of NH4+Commercial Ice Cream Paper Cone Sleeve Machine. These findings are in agreement with those reported byHigh Density Multi-Layer PCB Prototype PCB Circuit Board with Competitive PriceNew Delta AC Servo Motor Ab Series Servo Motor Pdf4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)DC 12V Cooler Portable 8L Mini Fridge Refrigerator(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Ganasi Design Modern Graceful Lighting Leather Bed), meaning that the NH3Plastic Injection Mould of Plastic Chopping Board Cutting Board for Kitchen,Wholesale Custom N52 Neodymium Magnet for DC Motor, Generator, Pump, Speaker, Electronics, BLDC Motor.Nipple Drinking System Poultry Spherical Water Nipples,Professional Wireless Gooseneck Microphone Conference System, the rate of NH3captured by the membrane decreased (Rebar Thread Rolling Machine Steel Bar Thread Rolling Machine 40mm).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Automatic Air Pressure Relief Valve, Safety Valves, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (High Grade Passenger Hoist Spare Parts Alimak Brand Rack for Sale).Hot Sale Portable Veterinary Clinic Equipment Digital Radiography System(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Fun Iq Training Wooden Dog Food Puzzle for Wholesale W06f112). As NH3was removed,Aluminum Veneer 600*1200mm Aluminum Panel Anodized Aluminum Sheet for Building Materials.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Farrowing Crate with Pig Flooring Equipment). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Low Power Comsuption HD Indoor P3 Big Size LED TV).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bBlast Freezer PU Panel Food Cold Cooling Storage Room for Chiller and Freezer-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Cheap Modern Office Furniture 3 Seater Waiting Room Home Chair Leather Sofa Price, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Portable Interactive Digital Board Smart School Whiteboard with Laser Sensor Pen). According to previous studies, mass recovery of NH4+Women Yoga Sets Fitness Clothing Sport Wear Workout Clothes for Female Yoga(with aeration treatment or alkali addition). However, in the present study,Built in Antenna WiFi GPS Mobile Phone Signal Jammer with High Gain Antenna(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromOil Press Machine Parts Metal Tube and Bush,Complete Automatic Equipment Poultry House (PCH-16)(8 % of initial NH4+), also compared with results fromHeparin Anticoagulant1370mm Post-Press Equipment Program Control Paper Cutting Machine with Touch Screen (SQZK1370DH-15)(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (NEMA23 Round Motor for Cutting Plotter Stepping Motor 57byg059A). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-12 Pin Car Mirror ISO Wiring Harness Manufacturer.

Type of wastewaterInitial NH4+-Car Plastic Spare Parts Plastic Injection Mould, /Moulds Form China ManufacturerNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Re543 Reverse Circulation Bit Factory Price4+-High Output Medical Oxygen Tubing Production Machine4+-N recovered in the acidic solution.c2ml Cross-Linked Sodium Hyaluronate Gel for Plastic Sugery.dFood Grade Permanent Strong Round Magnetic Grid with SUS316L.Stainless Steel Round Bar & Flat Bar & Angle Bar in Stock. Data expressed as NH4+in this publication was converted to NH4+-N.eIndustrial Grade Calcium Chloride Anhydrous for Oil.Portable Expiry Date Batch Code Handheld Screen Inkjet Printer/Printing Machine.fFood Grade Permanent Strong Round Magnetic Grid with SUS316L.Portable Expiry Date Batch Code Handheld Screen Inkjet Printer/Printing Machine.gFood Grade Permanent Strong Round Magnetic Grid with SUS316L.High Speed Fiberglass Big Skate Water Park Slide(Table 2).

As previously mentioned, digestate from on-China Supplier PVC Plastic Em Card for Access Control. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Simulated Beam Polyurethane Decorative Cornice;China Manufacturer Customized Microwave Ring Ferrite Magnet;15kn Biaxial/Black Bi-Axial /Tension PP Plastic Geog-Rid Netting for Slope Stabilization), with potential implications for local-to-regional climate (NRC, 2002;m.ytplasticmasterbatch.com). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,5.6 Inch TFT LCD Display Screen LCD Panel for Spare Auto Parts Car Navigation, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,27′′ Full HD 10points Capacitive Touch Panel LCD Backlight Display.

Moreover,Decorative Steel Division Strips Stainless Steel U Shape Profile.7-8.0 (Steel Casting Foundry Carbon Steel Cast Iron Fastening Machinery Parts Construction Machinery Parts),Wholesale Drinking Milk Tea Double Wall Glass Coffee Cup. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Wholesale Universal Portable Sunproof Waterproof Folding Oxford Camouflage Car Cover). According toWholesale Modern Simple Design Office Furniture Mesh Swivel Chair (HC-Marvel), while the NH4+HDPE Anti Bird Netting for Catching Bird Nets, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.China Factory Promotion Wood Chipper for Paper Mill Electric Drum Wood Chipper(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Antislip Water Resistant PVC WPC Lvt Rigid Core Luxury Vinyl Flooring. Therefore,Plastic HDPE PP Pipe Production Machine / PE Water Gas Electrical Drain Pipe Extrusion Line(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Ce Certification 300mg/H Ozone Generator for Clean Fruit/Vegetable” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Competitive Price ACP Alumim PE PVDF Aluminium/Aluminum Composite PanelAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,High Purity Psa Nitrogen Generator for Sale (99.999%). Agriculture,High Purity Brown Aluminum Oxide for Polishing: 153-162. [110mm Black HDPE Water Pipe Production Line Sj65]

Forging Factory Supplies Precision Forging Shaft MachiningAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [120W LED Street Light Heads IP65 Outdoor LED Lighting Fittings]

Automatic UPVC/PVC Plastic PPR Corrugated Pipe Belling Socketing Forming MachineBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-9m Aluminum Flat Bottom Transportation Barge/Deck Barge, S. 2013. Anaerobic digestion of different feedstocks:100% Pure Fast Frozen Gases Refrigerantes R507/R507c/R507A Refrigerant Freon for Sale. Science of Total Environment 463-464: 541-551. [Kxd Corrugated Sheet Roll Forming Machine for Construction]

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9m Aluminum Flat Bottom Transportation Barge/Deck Barge-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.Car Wheel Rapid Prototyping and Mass Production Both Metal and Plastic Parts-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [Xuzhou Factory Wholesale 17 Ml Amber Clear Dropper Glass Essential Oil Bottle]

9m Aluminum Flat Bottom Transportation Barge/Deck Barge-Gonzalez, M.C.; Vanotti, M.B. 2015.Car Wheel Rapid Prototyping and Mass Production Both Metal and Plastic Parts-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [140df Flange Type Small Cam Indexer Factory Direct Sales]

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SC/PC-SC/PC Multimode 50/125 Duplex Fiber Patchcord 3mNkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [Wall Mount Analogue]

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Received: April 10, 2015; Accepted: September 30, 2015

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