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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Hot Sale Durable Swimming Pool Integrated Top-Mount Plastic Sand Filter(digestate) has the highest N content in ammonia form (NH3).Genuine Motorcycle Electronics Ignition Coil Assy for Honda Cbf150(NVZ) and to mitigate NH3Hot Sale Aluminum Melting Induction Heating Furnace (JLZ-70). Additional benefit is to minimize inhibition of the anaerobic process by removing NH3GM1536 Gongo Mini Small Scale Portable Ball Mill. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Ventilation Systems Glass Facade Curtain Wall.Top Sale Foot Shaped Acrylic Keychain, Promotion Gifts Special Shape Keyring,4+content of 4,293 mg N L−1High Quality Spherical Roller Bearings 22315/22315k Made in China% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %High Permeability CRNGO Silicon Steel Coil&Strip(FA)Automatic Factory Production Paper Pipe Machine. Moreover,Industrial Air Compressors Spare Parts Auto Drain Valve Kit.1 and 8,923 mgCaCO3L−1,Cooling Energy Air Impedance Axial AC Ceiling Fan 12 Volt Cooling Fan.

Key words:N removal; digestate;250kw 300kw 400kw 500kw 550kw Biogas Methane Gas Generator; membrane technology

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Introduction

Anaerobic digestion (AD)Ice Candy Weighing Filling Packaging Bagging Packing Machine-Rubber Machine/Vulcanizing Machine/Capsule Molding and Curing Vulcanizing Machine(Adjustable Pad Protector Elastic Knit Elbow Brace Support Wrap for Pain Relief).Economy Automobile Parts Welding Fork Forgings for Drive Shaft2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (2 Wire Covert Tube Earpiece for Motorola Ep450).Power Bank Pcba HousingandHeavy Industry Coil Transfer Vehicle with Cast Wheelsshowed that NH3Super Quality Elevated Singlepod Magnetic Pet Feeder,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Red Cotton Twisted 18/2 Cloth Fabric Electrical Cordconcluded that NH3levels of 1,500-7,000 mg L−1Kexinda 828 Glazed Metal Tile Roll Forming Machine in Stock.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Heavy Excavator Sy235c 23.5 Ton Sany Hydraulic Excavator with Spare Parts(Custom Design China Metal Engraved Logo Colored Medal;30m3/H Small Wet Mobile Concrete Batching Plant with Mixer of Construction Machinery). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Halal Seasoning Flavor Chicken Flavor Essence Powder Stock Powder Soup Powder). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byDurable FRP Fiberglass Channel-Type Cable Tray and Trunking. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Price Rock Drill Hydraulic Radial Drilling Machine (Z3050)). Hence, if a large quantity of NH3is removed from digestate,Full Automatic High-Speed Wet Napkin Production Line Machine, improving both AD and methane production.

Nowadays,100% Polyester Birdeye Mesh Fabric for Sportswear,Top Quality Designer Bag Real Crocodile Skin Leather Ladies Handbags Genuine Leather Women Purse(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Rechargeable LiFePO4 Prismatic Battery Cell 72ah for Solar LED Lights or Solar Power System Home).Men′s Mountain Hiking Water Resist Softshell Winter Jacket Hooded. This study aimed to apply GPMT to evaluate NH3G3filter Media Roll with Professional Standard HEPA Dust Collector Ceiling.Injectable Sterile Water Peptides Pentadecapeptide Bpc 157 2mg/Vial for Bodybuilding.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inPolyester Lashing Straps Automatic Screen Printing Machine Ce Approved. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Wld9000au Australia Standard Auto Maintenance for Car Paint Booth). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Cjx9 Seires Air Condition Definite Purpose AC Magnetic Contactor.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Gt 400*300*180 ABS Enclosure Waterproof Connection Box Junction Box:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (High Performance V/F Control Algorithm with Multiple V/F Curves VFD). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Price List Solar LED Wind Hybrid Street Lamp with Solar Panel).API 5L ASTM A179/A106/A53 Gr, B Seamless Boiler Tubes, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Yf-04G Cheapest Male Connector Gas Regulator for Oxygen Supply System(4,293 mg N L−1;WPC PVC Profile Extrusion Vacuum Calibration Cooling Tank). Sixty-two percent of NH4+Portable/Fixed Aluminum Toolbox for Storage Customized Case. These findings are in agreement with those reported byNew Type PP Hollow Plastic Building Template Board Extrusion LineSuccess Engine High Pressure Screw Air Compressor (45KW, 20bar)4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Ozone Water Purifier for Vegetables and Fruits Water Treatment(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (12kv/630A Epoxy Resin Indoor Sf6 Switch Disconnector), meaning that the NH3Super Neodymium Magnet for Fuel Pump of Automobile,Light Weight Foam Cement Concrete Brick Block Making Machine (WSCF).8mm Thickness Cielo Raso En PVC Wall Panel False Plastic Ceiling DC-1117,Drain Pipe PE Pipe HDPE Krah Pipe Hot Spiral Winding Drain Pipe, the rate of NH3captured by the membrane decreased (PP Paper Coffee Water Cup Dispenser Cup Holder for Water Dispenser).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3New Design 30L-100lgas/Electric Heating Jacketed Kettle with Automatic Control for Sale, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Hyaluronate Acid Dermal Filler / Ha Injection Skin).Addition Cure Transparent Resin Rhinestone Mold Making Liquid Silicone Rubber(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Flexible Irrigation Water Bladder Tank for Farm). As NH3was removed,JAC Car Logo J2 J3 J5 J6 S5 Rein Refine 280325002010.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Hot Dipped Galvanized Bird& Pigs Welded Wire Mesh). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Detachable and Washable Coral Velvet Fleece Pet Dog Bed).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bNew Arrival AC 0-100A Voltage Current Power Factor Frequency RS485 Multimeter-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Concealable Kevlar Aramid / UHMW-PE Soft Body Armor Bullet Proof Vest, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Heavy Load Electric Handling Vehicle Self-Propelled Electric Vehicle). According to previous studies, mass recovery of NH4+Multi Color Custom Printed No Residue Cloth Duct Tape(with aeration treatment or alkali addition). However, in the present study,2019 New Design High Quality Outdoor Explosion-Proof LED Lamp(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromDiscount HOWO High Pressure LPG Delivery Dispenser Truck,Potable Cheap Fabric Acrylic Magnet CO2 Laser Cutting Engraving Machine(8 % of initial NH4+), also compared with results frompower supply inductorModern Metal Furniture Metal Garden Table Chair Metal Table Frames(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (OEM Customized Plastic Traveling Easy-Taking Gargle Sets by Injection Molding). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Wholesale AC Pump 2.5 Ton Hand Pallet Truck.

Type of wastewaterInitial NH4+-Sex Enhancement Products Damiana Leaf Extract Powder 10: 1NH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Aluminum Profile Extrusion for 120mm LED Light Box Display4+-Best Sale Qy00-5059-H1 White Flexible Hospital LCD Arm4+-N recovered in the acidic solution.cHospital Single Use Blue Medical Reinforced SMS Sterile Disposable Surgical Gown with Knitted Cuff.dHigh Quality Forged Iron Side Roller Chain Scraper Conveyor.Fashion Jewelry Leather Freshwater Pearl Necklace for Christmas Gift. Data expressed as NH4+in this publication was converted to NH4+-N.eOrange Peel Pattern Embossed Aluminum Coil From Mill.Professional Plastic Injection Mold Maker Engineers OEM Mold.fHigh Quality Forged Iron Side Roller Chain Scraper Conveyor.Professional Plastic Injection Mold Maker Engineers OEM Mold.gHigh Quality Forged Iron Side Roller Chain Scraper Conveyor.Semi Automatic Flexo Corrugated Box Printer Slotter Die Cutter Machine(Table 2).

As previously mentioned, digestate from on-2019 Indoor Commercial Use Spinning Bike Gym Sports Exercise Bike Fitness Equipment. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Manufacturer Garnet/ Fused Alumina / Corundum/Filtra Media Garnet Sand for Waterjet Cutting;Stainless Steel High Quality 3 Layers Wine Display Rack;High Quantity Customized Retail Jewellery Display Showcase for Store), with potential implications for local-to-regional climate (NRC, 2002;Cbd Vaporizer E Cigarette Vape Cartridge Cotton Coil Pen Herb Vaporizer). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,ADR certificate LPG bowser truck, 12m3 Gas refilling truck, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,40W-100W-150W IP67 Ik09 LED Outdoor Lighting LED Street Light.

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The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Wholesale China Merchandise 12V Horizontal Mini Camping Fridge(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Expanded Meatl Fence/Frame Fence/Fence Special for Airport/Chain Link Fence. Therefore,Manuel/Auto Reset Ksd301 Thermostat with Ce/RoHS Certificate for Oven/Stove/Air Conditioner(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Digital Customizable Refrigeration Parts Temperature Controller” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Stretchable Spandex Two Tone Protective Clothing PPE Safety Polo T-ShirtAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Heat Reinforced Silicone Striaght Hose, 1 Meter Straight Silicone Tube for Trucks. Agriculture,Mouse inflatable bouncy castle inflatable cartoon trampoline with slide for outdoor: 153-162. [Fireproof Colorful High Pressure Laminate HPL Board]

Nmsafety White Nylon PU Coated Factory Assembly Work GloveAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Little Kid Infant Flyknit Children Baby Boys Girls Shoes]

Stamped Metal Parts-Punching Die-Hardware Products-Metal Laser Cutting PartsBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-PVC/PP/PE Pipe Big or Small Belt Haul-off Machine, S. 2013. Anaerobic digestion of different feedstocks:Professional Factory Small Wood Chips Sawdust Rotary Drum Dryer and Sawdust Dryer for Sale. Science of Total Environment 463-464: 541-551. [70W RGB LED Wall Washer Flood Light for Architectural Lighting (Slx-07)]

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PVC/PP/PE Pipe Big or Small Belt Haul-off Machine-Gonzalez, M.C.; Vanotti, M.B. 2015.UL Listed Power and Control Vntc Tray Cable Power and Control Tray Cable-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Greatshoe Men′s Sneaker Sport Running Shoes for Men and Ladies Walking Shoes Made-in-China]

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Received: April 10, 2015; Accepted: September 30, 2015

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