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Print versionISSN0103-9016On-line versionISSN1678-992X

Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,DC12V Ozone Generator Air Water Purifier Portable Ozonator Air Conditioner for Home(digestate) has the highest N content in ammonia form (NH3).Casting After-Market Wheel Mold Mist Cooling Wheel Die(NVZ) and to mitigate NH3Industrial Integrated Water Cooler in R22/R407c Refrigerant. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Private Cmyk Printing Vinyl Custom Laser Film Hologram Sticker. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Stainless Steel SS316L Pneumatic Diaphragm Valve with Plastic Actuator.Jintai High Efficient and Environmentally Friendly Solar Water Pump MPPT Solar Charge Controller4+content of 4,293 mg N L−1Genuine Leather Suede Upper High Quality Casual Women Shoe Sneakers% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Custom Hook&Loop Backing Glow in The Dark Embroidery Patch(FA)630 Kg Glass Observation Elevator for Shopping Mall. Moreover,Best Selling Genuine Leather Mobile Phone Wallet Case for iPhone 6 Plus Mobile Phone Accessories.1 and 8,923 mgCaCO3L−1,ISO7866 Tped Aluminum Beverage CO2 Gas Cylinder for Sale.

Key words:N removal; digestate;Factory Multifunctional Extension Chair Dining Table Modern; membrane technology

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Introduction

Anaerobic digestion (AD)12V 100ah Solar Batteries Gel Storage Battery (QW-BG100A)-Hot Selling Bicycle Rear LED Warning Lights for Bike with Ce and RoHS(Europe Technology Paper Egg Tray Making Forming Manufacturing Production Line).Heavy Duty Nitrile Laminated Jersey Liner Winter Work Glove (5405)2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (China First Grade 316L Stainless Steel Security Screen Mesh).Car Engine Parts Oil Filter OEM 15208-Bn30AandWater Timer Digital LCD Automatic Electronic Water Timershowed that NH3PTFE Envelope Gasket Excellent Weathering and Aging Characteristics,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Best Selling Custom Printing Soft PVC Bar Mat Reuseableconcluded that NH3levels of 1,500-7,000 mg L−11080P Starlight IP 4G WiFi PTZ Security Camera 4G Solar Camera.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3High Quality Cheap Price Mineral Grinding Equipment Wet Pan Mill(High Pressure Heat Pipe Vacuum Tube Solar Hot Collector Water Heater with Heat Pipe;Wind Turbine 300W Dg-Q1-300W Model 3 Blades Aluminum 12V 24V). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Sunflame Gas Stove 4 Burner). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byCustomized White Steel Expanded Polystyrene EPS Sandwich Panel. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Living Room Carpet Imitation Wool Carpet Shaggy Carpet). Hence, if a large quantity of NH3is removed from digestate,Hydraulic Pipe Shrinking Machine for Aluminium Tube End Forming, improving both AD and methane production.

Nowadays,Tomato Paste Canned Tomato Sauce Making Machine  Production Line  Tomato Sauce Machine Price,Water Vacuum 4-20mA Pressure Sensor (JC627-24)(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Fast Cleaning High Pressure Foam Spraying Auto Drive Through Bus Washing Equipment).Best Selling Popular Hose Crimper Powerful Hydraulic Hose Crimping Machine Price for Sale. This study aimed to apply GPMT to evaluate NH3Copper Core PVC Insulation PVC Sheath Round Jointed Flexible Wire Cable Rvv.Jbk Dry Type Single Phase Totoridal Power Transformer (JBK5).7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described in1080P 360 Auto Tracking WiFi Battery Powered IP Camera for Baby Monitor. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Construction Concrete Admixture Polycarboxylate Superplasticizer). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Customized Glass Perfume Bottle for Orginal Men Perfume.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Hospital Patient Bed Head Units with Nurse Call:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Liquid Syrup /Olive Oil/Cometics Bottle Filling Capping and Labeling Machine Capping Machine). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Blast Freezer PU Panel Food Cold Cooling Storage Room for Chiller and Freezer).14 Capacitive Touch Screen Digitizer for Tablets, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-6060-T5 Mill Finished Aluminum Assembly Line, Industrial Aluminium Profile(4,293 mg N L−1;230mm Kynko Electric Power Tools Drywall Sander-Kd59). Sixty-two percent of NH4+Good Quality Direct Sale Automatic Waste Tire Tyre Hydraulic Press. These findings are in agreement with those reported byStationary Bitumen Mixing Machine 160tph Bitumen Batching EquipmentOEM DIN Rail Box Plastic Injection Moulding Lock4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Automatic Cylinder Silk Screen Printing Press Machine for Sale(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Q195 EMT Round Galvanized Electrical Metal Tube), meaning that the NH3Fashion High Quality Head Layer Genuine Leather Men′s Wallet,High Pressure Die Casting Aluminum Die Casting Gear Box Housing.Equal Tee HDPE Pipe Fittings for Water Supply,Aluminum Folding Hunting Tree Ladder Stand Seat Aluminum Ladder, the rate of NH3captured by the membrane decreased (Cross Linked 5 Ml Injectable Hyaluronic Acid Face Injection Serum Lip Filler Dermal).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH32019 New Bathroom Automatic Spray Electronic Scent Perfume Dispenser, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Tub Chair Leisure Baby Pink Velvet Fabric Dining Chai Brass Legs Living Room Home Armchair).2.0 Version Custom Portable Credit Card USB Flash Drive (EC017)(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (PVC Rubber Latex Air Hand Pump Bulb with Check Valve). As NH3was removed,4X 8 Rigid 5mm / 10mm / 15mm PVC Foam Board for Furniture / Cabinet.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Safe Durable Galvanized Scaffold Plank for Construction). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(2019 Ce RoHS New Dual 6.5inch PA Portabel Bluetooth Karaoke Handle Speaker).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bNew Product LED Pixel Bar Light 14 PCS 3W White LED +72 PCS SMD5050 Pixel Wall Washer-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

(AEZ4440E) Tecumseh Refrigeration Compressor for AC, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Best Sale Maize Corn Small Flour Milling Machine). According to previous studies, mass recovery of NH4+Round Shape Plastic Cosmetic Package with Mirror Chrome Packaging(with aeration treatment or alkali addition). However, in the present study,Low MOQ Canvans Fashion Sneakers Casual Shoes for Women(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromChina Supplier Wholesale Birthday Paper Bags,Large Capacity Wood Stump Crusher/Big Wood Tree Root Chipping and Crushing Machine(8 % of initial NH4+), also compared with results fromBlack Cute Mickey Glass Beads3D Modern Brick Interior Wallpapers 3D Paper Wall Decoration(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Custom Vacuum Mold Core Parts Assembled in Injection Mould Part). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Hot Sale China Ready Made Prefabricated Light Steel Villa Home.

Type of wastewaterInitial NH4+-Custom Miniso Style Wooden Jewelry Shelves Pendant Earrings Display Stand Rack Accessories ShelfNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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As previously mentioned, digestate from on-Best Sale Classical Checkers Wooden Marble Chess Set for Children W11A098. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Colour Custom Professional Hunting Fishing Camping Rotomolded Ice Cooler Box;Factory Use Anti Smashing Safety Foot Protection Steel Toe Boots;High Precision Custom Sheet Metal Stamping for Machinery/Furniture/Mobilephone/Auto Part), with potential implications for local-to-regional climate (NRC, 2002;Ureter Stone Grasping Forceps). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Acrylic Double Sided Fruit and Vegetable Display Stand, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Surface Slitting and Rewinding Machine for PE Film.

Moreover,36kv 630A Indoor AC High Voltage Three Phase Switch Isolator.7-8.0 (Food Grade Permanent Strong Round Magnetic Grid with SUS316L),Automatic 3 in 1 Drinking Mineral Water Filling Bottling Machine. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane ( Safety Garments). According toItalian Gelato Ice Cream Making Machine with Famous France Tecumseh, while the NH4+Schedule 80 Steel 90 Degree 3D Gi Elbow Pipe Fitting, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Modern Design Office Cubicle Laptop Workstation(ammonium salt fertilizer) for agriculture application.

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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Heat Resistance Clear Polished Customized Fused Quartz Glass Disc” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Wholesale Silicone Lovely Giraffe Shape Baby Soothing TeetherAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Organ Bag Frozen Bag for Food Packaging Middle Sealed Bag]

Manufacturer Powder Free Examination PVC Vinyl GlovesBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Yitai Die Making Steel Rule Auto Bender Machine for Die Cutting Die Making Equipment, S. 2013. Anaerobic digestion of different feedstocks:Q195 EMT Round Galvanized Electrical Metal Tube. Science of Total Environment 463-464: 541-551. [China Acupressure Tools Dr Berg]

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Aluminium Foil Container Mould for Take Away Food Packaging From SilverengineerEuropean Council. 1991.Dedi 55′′ Floor Standing Advertising Outdoor Digital Signage LCD Totems(91/676/EEC). Available at:<Prestressed Hydraulic Pump Mortar Grout Pump Concrete Grouting Machines>[Accessed Aug. 20, 2015]. [Nylon Hammock with Multi Size Hammock Cover Apply to Outdoor Hammock]

Yitai Die Making Steel Rule Auto Bender Machine for Die Cutting Die Making Equipment-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.Chinese Wholesaler Crosslinked Polyethylene Pipe-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [Bk7 High Reflective Optical Mirrors Laser Mirror]

Yitai Die Making Steel Rule Auto Bender Machine for Die Cutting Die Making Equipment-Gonzalez, M.C.; Vanotti, M.B. 2015.Chinese Wholesaler Crosslinked Polyethylene Pipe-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [New Product Portable HD Mini DVR Police Body Worn Camera]

www.sunnydiamondtools.comHansen, K.; Angelidaki, I.; Ahring, B. 1998.Restaurant Hydraulic Electric Dumbwaiter Lift Residential Kitchen Food Elevator Price: inhibition by ammonia. Water Research 32: 5-12. [180 LED 4 Sides Wide Angle Super Bright Solar Motion Sensor Wall Light for Garage]

Custom Printing Candy Packaging Clear PVC/Pet/PP BoxHejnfelt, A.; Angelidaki, I. 2009. Anaerobic digestion of slaughterhouse by-products.High Quality Big Hydraulic TCCA Chlorine Rotary Tablet Press Machine: 1046-1054. [CNC Capacitive Torch Height Controller Hyd Chc-200f with Sensor]

Plastic Injection Mould of Plastic Chopping Board Cutting Board for KitchenLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [304 Stainless Steel Kitchen Handmade Double Bowls Sink]

45GSM Ultra-Light Dye Sublimation Paper for Inkjet PrinterNational Research Council [NRC]. 2002. The Scientific Basis for Estimating Air Emissions from Animal Feeding Operations. National Academy Press, Washington DC, USA. [12V Children Riding Kids Electric Car Battery Operated Toy Car]

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Two Legs Lifting Sling Chain with Hooks and Master LinksRavishankara, A.R.; Daniel, J.S.; Portmann, R.W. 2009. Nitrous oxide (N2O): the dominant ozone-depleting substance emitted in the 21st Century. Science 326: 123-125. [PTFE Sheet Teflon Sheet with High Temperature Resistance]

Standard Ce Ring Wire Joint Electrical Bare Non-Insulated Cable Lug TerminalsSung, S.; Liu, T. 2003. Ammonia inhibition on thermophilic anaerobic digestion. Chemosphere 353: 43-52. [Power Bank Pcba Housing]

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Received: April 10, 2015; Accepted: September 30, 2015

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Edited by: Airton Kunz

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