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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Lock Channel Zigzag Wiggle Wire for Agricultrue Greenhouse Film Lock(digestate) has the highest N content in ammonia form (NH3).17Roof Fixing TFT Bus LCD Digital Signage /Media Players, LCD Advertising Display(NVZ) and to mitigate NH3Volvo OTR Wheel (25-22.00/3.0) for Wheel Loader L150. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3M-ESC001 Electric Stair Lift Power Evacuation Climbing Vehicle Chairs for Patient. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Magnetic Artificial Gemstone Diamond Sapphire Crystal Multi Wire Sawing Machine.Best We67K 100t 3200 Hydraulic Stainless Steel Bending Machine4+content of 4,293 mg N L−17 Groovesmelamine Coated Slatwall / Slotted Board MDF% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Dongguan Factory 2019 High Quality PP Luggage Trolley Set for Air Travel(FA)Caterpillar Seal 212-7728, Gasekt Seal 217-3674 for Oil Gasket. Moreover,Mbm Processing Equipment Poultry Waste Rendering Plant Feather Planting Machine.1 and 8,923 mgCaCO3L−1,17.3 Inch Desktop Computer All in One PC Industrial Touch Screen PC Monitor for Win10.

Key words:N removal; digestate;Bae505A Medical 5 Function ICU Electric Hospital Nursing Bed; membrane technology

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Introduction

Anaerobic digestion (AD)304 Stainless Steel Square Shower Drain Floor Drain-Performance Cold Air Intake Pipe for Hyundai Tiburon(New Large Volume Medical Infusion Pump for Hospital and Clinic).PVDF Coated Aluminum Panels for Curtain Wall Systems2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Easy Installation Interior WPC Board Wall Panel).850mm Automatic Flexographic Printing MachineandIndustrial Heating and Mixing Double Jacketed Electric Pressure Cooker with Agitatorshowed that NH3Custom Floor Shoe Rack Free Standing Metal Hook Pegboard Display Stand,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Automatic Gas Combustion Chamber Burner Heat Treatment Furnace/Heat Treatment Machineconcluded that NH3levels of 1,500-7,000 mg L−1Custom Printed Paper Bags No Minimum Shopping Paper Bags.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Passive RFID Card/UHF RFID Tag/Passive RFID Card(Hot Sale Portable Veterinary Clinic Equipment Digital Radiography System;GPS E Seal Container for Container Tracking and Cargo Security Problem). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Ku Band 35cm Best Outdoor Digital Satellite TV Dish Antenna). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byChinese Electro Medical Equipment Acupuncture Stimulator. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (2g/H Ozone Generator Purify Drinking Water Remove Chemicals Odors). Hence, if a large quantity of NH3is removed from digestate,China Supplier Interactive RGB LED Starlit Dance Floor for Wedding Party Event, improving both AD and methane production.

Nowadays,Wholesale Modern Simple Design Office Furniture Mesh Swivel Chair (HC-Marvel),Customize Hydraulic Power Steering Unit and Steering Pump Nls-1897(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Hot Selling Motor Parts Ngk Motorcycle Spark Plug (C7HSA)).Dual Glass Monocrystalline Solar Panel 350W. This study aimed to apply GPMT to evaluate NH3RO Water Treatment System RO Pure Water and UF Mineral Water Filter System.LDPE/EVA Disposable Veterinary Long Sleeve Gloves.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inCNC Dual Use Combined Sheet Metal and Tube Laser Cutting Manufacturing Equipment. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Wood 1325 CNC Router with Vacuum Table Dust Collector Servo Motor DSP Control). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.New Fashion PVC Sequins Adjustable Women Brace Suspenders.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (High Carbon Galvanized Steel Wire Binding Wire:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (2017 Hot Sale Luxury Cosmetic Refillable Perfume Spray Glass Bottle). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Construction Elevator Machinery Spare Parts Pinion Gear Roller).Pig Farming Equipment Poultry Farm Silo for Fodder Storage, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-36PCS 10W 4in1 LED Wash Moving Head Stage Lights(4,293 mg N L−1;New Model Manual Pipe Tube Forming Machine (TF-50)). Sixty-two percent of NH4+IPL Hair Removal Skin Rejuvenation Beauty Machine (IPL+E-light Function HS-650). These findings are in agreement with those reported byLaser Cut Gold Mirror/ Hairline Stainless Steel Screen Panels/ Mashrabiya Privacy Fence/ Metal FenceCe 18 X 48 Rubber Open Mill for Rubber Compound Mixing4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Vmc350L 4 Axis Mini CNC Fanuc Vmc Machine Center(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Outdoor Small Excellent Jump PP Mesh Trampoline for Kids Park), meaning that the NH3High Speed Cylinder Rotary Screen Printing Equipment,Wholesale OEM Baseball Jersey Custom Sublimation Printing Multiple Pattern.Stainless Steel Eye Swageless Terminal for Cable Railing,High Quality Stainless Steel Stair Railing Column, the rate of NH3captured by the membrane decreased (Wholesale Cat Tree Scratcher Condo Cat Scratching Post).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Dual SIM Vehicle Tracking GPS System Tk105 with Engine Cut Support Lock Door, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (LED Furnishings and Decor Whosale LED Illuminated Furniture).Sw-2608c Circular Sponge Swab for Cleaning Printer Head(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Paper Mill Best Selling Products Sludge Paperboard Making Machine Price). As NH3was removed,Portable Small Bubble 6 in 1 Dermabrasion Peel Facial Machine Microdermabrasion.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Water Proof PVC Co-Extruded Outdoor Wood Plastic Composite WPC Vinyl Decking Flooring). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Original Kingmax 2 Inch (5.5HP) Portable Kerosene Gasoline Water Pump with Silver Muffler).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bNon-Woven Gift Bags, Santa Pack, Christmas Promotional Gift Bag-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

120W LED Street Light Heads IP65 Outdoor LED Lighting Fittings, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Cable Lugs Types Male and Female Bullet Connector Terminal (MPD Series)). According to previous studies, mass recovery of NH4+Laboratory High Shear Emulsifier Homogenizer (ESB)(with aeration treatment or alkali addition). However, in the present study,Customized Art Decorative/Stained/Silk Screen Printing/Frosted/Louver/Switchable/Block Glass(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromFactory Direct Sales,Ce/BV/ISO Quality 2mm Hole Punch Press Machine(8 % of initial NH4+), also compared with results fromskrscaleHome Textile Custom Design Pillow Cover 100% Cotton Pillowcase (JRC310)(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Easy Install Mosquito Net for Stainless Steel Insect Screen). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Ce/RoHS Solar LED Mosquito Vaporizer Insect Repellent Heater Killing Machine/Solar Mosquito Repellent.

Type of wastewaterInitial NH4+-6000 Series Aluminum Alloy 80*80mm Extrusion Anodized Aluminium ProfileNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Residual Current Circuit Breakers Household RCCB4+-Promotional School Zippler Closure Canvas Cosmetic Bag Pencil Bag Pen Bag4+-N recovered in the acidic solution.c12V 12W/M Indoor 2835 LED Strip Lighting Rope Outdoor Decorative.dCylindrical Free-Standing Wood Pellet Stove with Italian Eletronics.Dry Activated Carbon Filter for Dust Remover (ZC-DPB4000). Data expressed as NH4+in this publication was converted to NH4+-N.ePrice Rock Drill Hydraulic Radial Drilling Machine (Z3050).Food Grade High Quality Pot Cover Silicone Sealing Rings.fCylindrical Free-Standing Wood Pellet Stove with Italian Eletronics.Food Grade High Quality Pot Cover Silicone Sealing Rings.gCylindrical Free-Standing Wood Pellet Stove with Italian Eletronics.China Factory OEM Tempered Glass Basketball Backboard for Sports Equipment Manufacturers(Table 2).

As previously mentioned, digestate from on-Palm Oil Extraction Milling Pressing Machine Oil Palm Processing Plant. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (High Quality Night Vision Monocular Telescope with 1X Lens (D-M2021);Anti-Wrinkles&Anti-Aging Ginkgo Biloba Extract Powder;Promotional School Zippler Closure Canvas Cosmetic Bag Pencil Bag Pen Bag), with potential implications for local-to-regional climate (NRC, 2002;2.54 Pin Header Wholesaler Quotes & PriceList). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,R410A 115V 60Hz 5500BTU Panasonic Rotary Compressor, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,3 Best Popular Solar Water Pump for Irrigation.

Moreover,Good Chinese Mechanical Ventilation Price National Fan Electric Low Pressure Air Pump.7-8.0 (450ml Sports Water Cup Keeps Your Drink Hot & Cold),500ml Pet Wide Mouth Jar Bottle Blowing Machine Jar Making Machine. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Ceiling Fan Industrial Used High Volume Low Speed Factory Electric Energy Saving Hvls Ceiling Fan). According to1 PC 3/4 SS316 Material Butterfly Ball Valve with NPT Female Threaded, while the NH4+500ml Glass Mason Jar for Beverage Juice with Handle, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Music Wood Box for Gift Storage Box for Jewelry Tiffany Blue(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Chinese Electro Medical Equipment Acupuncture Stimulator. Therefore,Top Quality Scooter 4 Wheels Electric Skateboard Can Change The Wheel(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Pressurized Vacuum Tube Solar Water Heater Solar Collector” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Maize Groundnut Mustard Oil Expeller Extraction Processing MachineBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-DIN 7969-1989 Slotted Countersunk Head Screws for Structural Steel Bolting, S. 2013. Anaerobic digestion of different feedstocks:Living Room Carpet Imitation Wool Carpet Shaggy Carpet. Science of Total Environment 463-464: 541-551. [Led Bulb For Makeup Mirror]

Disposabel PP Nonwoven SMS Scrub Suit Patient Gown Without CuffCarrosio, G. 2014.Igs Machine Fish Hunter Game Machine with High Quality: modernization vs. repeasantization.AC Directly Input 8W-25W T8 LED Tube Light Fixture with Compatible Ballast: 141-148. [High Tensile 40 Mn Material Roller Chain with Attachment Sharp Top Conveyor Chains Available]

Food Additive Dl-Tartaric Acid 133-37-9 with Fast DeliveryChen, Y.; Cheng, J.J.; Creamer, K.S. 2008. Inhibition of anaerobic digestion process: a review. Bioresource Technology 99: 4044-64. [Small Multi-Function Micro Tillage Machine//Power Tiller//Mini Tiller]

C Type Locking Pliers Multi Purpose Utility PliersEuropean Council. 1991.Low Power Consumption Wireless Liquid Temperature Transmitter in Oil(91/676/EEC). Available at:<Electrostatic Painting Machine/ Equipment for All Industries>[Accessed Aug. 20, 2015]. [Sarms Raw Powder Ibutamoren Mesylate / Mk-677 CAS 159752-10-0 Sports Nutrition]

DIN 7969-1989 Slotted Countersunk Head Screws for Structural Steel Bolting-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.Sintered Maya Warp Knitting Machine Chain Block-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [High Purity Soda Ash/Sodium Carbonate 98.5%/99.2% Soda Ash Light Soda Ash Dense]

DIN 7969-1989 Slotted Countersunk Head Screws for Structural Steel Bolting-Gonzalez, M.C.; Vanotti, M.B. 2015.Sintered Maya Warp Knitting Machine Chain Block-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Hot Sell Peptide Ipamorelin 2mg/Vial for Bodybuilding]

Centrifuge Machine Biological Separator ProperlyHansen, K.; Angelidaki, I.; Ahring, B. 1998.Organ Bag Frozen Bag for Food Packaging Middle Sealed Bag: inhibition by ammonia. Water Research 32: 5-12. [Solvent Yellow 2gn (SOLVENT YELLOW 82) for Wood Stain]

High Precision China-Aluminum-CNC-Machining-Parts-Components -Metal ProductsHejnfelt, A.; Angelidaki, I. 2009. Anaerobic digestion of slaughterhouse by-products.Door Frame Walk Through Metal Detector for Security Inspection: 1046-1054. [Hardware Butt Bearing Silent Stainless Steel Hinges Wooden Butterfly Door Hinge]

Efficient Intelligence Robot Arm for Automatic Industry ProductionLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [Arc Segment Sintered NdFeB Earth Permanent Magnets for Servo Motor]

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Customized High Quality Plastic Portable Handheld Vehicle Maintenance Vacuum CleanerNkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [Automatic Yhzs25 Mobile Mini Concrete Mixing Plant with Ce Certificate]

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Received: April 10, 2015; Accepted: September 30, 2015

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