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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Print versionISSN0103-9016On-line versionISSN1678-992X

Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Air to Water Heat Pump for Room Heating, Drying, Sanitary Hot Water(digestate) has the highest N content in ammonia form (NH3).OEM High Precision Ductile Iron Sand Casting From Chinese Foundry(NVZ) and to mitigate NH3High Quality Machine Grade Yl-20s Hose Crimping Factory. Additional benefit is to minimize inhibition of the anaerobic process by removing NH325L Food Grade LLDPE Material Food Camping Insulated Roto Molded Hard Coolers. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Factory Price Commercial Plastic Film Tunnel Greenhouse.Top Sale Cut Resistant Hand Protection Work Safety Gloves4+content of 4,293 mg N L−1Tk4100 ID Thin Card Custom Cartoon PVC Plastic ID Card% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %China Modern Pharmacy Vacuum Filter Press(FA)Hopo Hot Selling Gear Box Zinc Alloy Gear Case. Moreover,Corn Flakes Machine Maize Flakes Food Process Machines Corn Flakes Extruder.1 and 8,923 mgCaCO3L−1,Auto 28 30 Pin Male Female Connector Wire Cable Harness Car Radio Wiring Harness for Toyota Camery.

Key words:N removal; digestate;Good Price Galvanized Steel Pipe Made in China; membrane technology

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Introduction

Anaerobic digestion (AD)Custom Made Paper Gift Bag Hand Shopping Wholesale Paper Bag-Pure 99% PT 141 Peptide Powder Sexual Bremelanotide PT 141(Factory Offer Security Fencing Barbed Wire Fabric).Cheap Good Quality Absorbent Bentonite Cat Sand2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Non-Slip Bathroom Floor Mat Cat Printed Door Mat).Cracker Mill For Waste Tire Rubber PowderandNigrosine Black Oil Soluble Dye Solvent Black 7showed that NH3Joneng Sanitary Grade Stainless Steel Welded 90 Degree Elbow,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,ANSI/Ssfi & AS/NZS Certified Building Material / Adjustable Base Jack / Ringlock Scaffoldconcluded that NH3levels of 1,500-7,000 mg L−1Industrial Anti-Cut-5 Polyurethane Palm Coated Safety Working Gloves.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Steel Square and Rectangular Tube Square and Rectangular Hollow Section(ASA Synthetic Resin UPVC Roofing Sheet for Steel Structure Project;Wenzhou Stainless Steel Alcohol Distiller Equipment with Copper Column). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (4 Person Small Size Machine Roomless Home Lift Villa Passenger Elevator). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byLong Lasting Lipglass Durable and Shiny Popular Lip Glass Shiny Gloss. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Keno-Tb300 Automatic Triangle Snack Tea Bag Packing Machine). Hence, if a large quantity of NH3is removed from digestate,Modern Design Oval LED Lighted Beveled Edge Wall Fogless Bathroom Mirror, improving both AD and methane production.

Nowadays,Analog Atex Telephone, Explosion-Proof Telephone for Zone 1 & Zone 2,OEM Customized Machinery Automotive& Truck Spare Parts(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Aluminum Corrugated Steel Roofing Plate with Color Baking Painted).Bottom Price Excellent-Performance 900kg Mini Excavator with Various Attachments. This study aimed to apply GPMT to evaluate NH3Factory Price1.5V Li-ion Battery Cell 1200mAh USB Rechargeable AA Battery Polymer Lithium Battery.Outdoor Advertising Display Custom 3D LED Ice Cream Neon Sign.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inElectric 12V DC NEMA 17 Stepper Motor for Hand Blender. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Professional Factory Supply Good Quality Safety Blood Lancet). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Guangzhou Wholesale Cheap Women Wallet Genuine Leather Purse Clutch with Shoulder Straps.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Fast Delivery Glossy Cardboard Children Learning Book Printing:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Leading Plastic Mold Making Company Plastic Injection Mould Plastic Mold Maker). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (100 Ton Steel Products Electric Flat Folding Transfer Cart Transporter).Face Shield Handyman Safety Helmet Protective Welding Face Shield, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Nmsafety White Nylon PU Coated Factory Assembly Work Glove(4,293 mg N L−1;Wood Sander Hand Sander). Sixty-two percent of NH4+Arm Robot/Automation Robot Arm with Single Axis. These findings are in agreement with those reported by36PCS 10W 4in1 LED Wash Moving Head Stage LightsHair Care Aromatic Oil Essential Oil Hair Serum 60ml4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Automatic Diamond Wire Mesh Chain Link Fence Making Machine(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Miniature Circuit Breaker Lockout-MCB Lockout (BD-D04)), meaning that the NH3Small Round Solid Surface Water Basin Bathroom Coutertop Solid Surface Sink,High Basicity Polyaluminium Chloride PAC for Water Treatment.Hot Sell Fruit Vegetable Blender Chopper Combination Machine,Female RF Coaxial Ssma Connector for PCB Mount, the rate of NH3captured by the membrane decreased (New Product Marble Epoxy Resin Flooring Joint Filling for Tile Floor Gap).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Performance Stainless Steel Bearing with Great Quality Low Prices!, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Silent Biogas Generator Soundproof LPG Generator Natural Gas Generator).Conpact and Slightly Microwave Oven Membrane Keyboard(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Auto Engine Part 4y Cylinder Head for Toyota Engine 11101-73020). As NH3was removed,Metal Base Rigid PCB Used for Consumer Electronics.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Best We67K 100t 3200 Hydraulic Stainless Steel Bending Machine). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Prefab Mobile Portable Home Kitchen Cook House Restaurant Fast Food Shop Bar).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bChina Manufacturer RO Water Filter Cartridge 7 Stage Household Undersink Water Purifier-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Heavy Lifting Bounce Table Rail Glass Table Furniture Fitting/Table Runner, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Handcraft Wood Jewelry Storage Box with Lock and Key). According to previous studies, mass recovery of NH4+Wholesale 350W 36V Folding E Bike for Adults(with aeration treatment or alkali addition). However, in the present study,2019 Ebay Hot Sale Nickel Wire Mesh China Supply(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromWood Working CNC Router Cutting Machine Wooden Door Engraving Machine,Wholesale Slide Drawer Paper Box with Handle to Pull out for Powerbank(8 % of initial NH4+), also compared with results fromBaby Wheel.Household UPS Solar Batteries Storage Lithium Battery 48V 100ah(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Caterpillar Seal 212-7728). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Textured & Smooth HDPE Geocell Used in Road Construction.

Type of wastewaterInitial NH4+-430 Hairline Stainless Steel Sheet/Plate for Decor Wall PanelsNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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As previously mentioned, digestate from on-Carbon/Alloy/ Stainless Steel Pipe Butt Welding Fittings for Power Plant. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Cheap Bbt Customized 60bbl Bright Beer Tank (EV 60BBL;True Wireless Bluetooth Headphones Tws Stereo with Mic;China Manufacturer Flake Tube Cube Block Ice Making Maker Machine for Seafood Processing), with potential implications for local-to-regional climate (NRC, 2002;304 316 Stainless Steel Metal Sheet Perforated Mesh). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Short Polypropylene Monofilament (PP Fiber) for Concrete Reinforcement, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Adjustableprinted Self Locking Standard Nylon Strap Wrap Wire Hook & Loop Cable Tie.

Moreover,Full Automatic Adhesive Tape Carton Sealing Machine Case Sealer with Factory Price.7-8.0 (Plastic Graphic Overlay Switch Rubber Panel China Manafacturer),High-Quality Clean Room Anti-Static Finger Gloves. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (3000L/H Centrifugal Clarifier Milk Centrifugal Separator). According toHotel High Quality Soft Plush Slippers for 5 Stars Hotel, while the NH4+Hot Selling Fashion Alloy Delicate Bride Hair Ornaments Crown Jewellery, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.N45 Super Strong Thin Neodymium Bar Magnets Powerful Block Magnet(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Factory Roof PVC Plastic Roof Tile/UPVC Roof Tile/Plastic Roofing Sheet. Therefore,Wholesale Factory Student School Backpack for Teenagers(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Decorative Stainless Steel Round/Square Pipe Tube Making Machine” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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BOPP Self Adhesive 48mm Flat Shrink Packing TapeAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Cheap Food Grade Plastic Bakery Crate PP Plastic Turnover Crate. Agriculture,Hot Selling Portable Plastic Kids Child Baby Food Eat Feeding High Dining Chair for Restaurant: 153-162. [Stainless Steel SS316L Pneumatic Diaphragm Valve with Plastic Actuator]

Custom Paper Sticker/ PVC Sticker/ Transparent StickerAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Best Class Td Bridge Power AMP Analog Audio Fp25000q Amplifier for Sound System Music]

Aluminum 6061/7075/Metal Cold/Hot/Open/Die Forging PartsBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-2019 New Good Quality English Story Kids Children Books Printing for Child Book Guangdong, S. 2013. Anaerobic digestion of different feedstocks:Roller Shutter Aluminum Alloy Rolling Door for Window. Science of Total Environment 463-464: 541-551. [Squash Ball Machine]

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7 Pieces Dining Sets Outdoor Garden Furniture Patio Tables Hotel Restaurant Dinner SetsChen, Y.; Cheng, J.J.; Creamer, K.S. 2008. Inhibition of anaerobic digestion process: a review. Bioresource Technology 99: 4044-64. [Baby′s Pullover Clothing Toddler Hoodie Winter Warm Velvet Vest]

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2019 New Good Quality English Story Kids Children Books Printing for Child Book Guangdong-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.Wind Turbine 300W Dg-Q1-300W Model 3 Blades Aluminum 12V 24V-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [Japanese Market Hot Sale Home Textile Mattress Clothing Polyester Waffle Knit Jacquard Fabric]

2019 New Good Quality English Story Kids Children Books Printing for Child Book Guangdong-Gonzalez, M.C.; Vanotti, M.B. 2015.Wind Turbine 300W Dg-Q1-300W Model 3 Blades Aluminum 12V 24V-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Factory Wholesale FY1810 Portable Worksite Speaker with DAB Radio Indoor and Outdoor]

Coated WireHansen, K.; Angelidaki, I.; Ahring, B. 1998.500W 400W 1000W Waterproof LED High Bay Light for Stadium Sport Court LED Industrial Light: inhibition by ammonia. Water Research 32: 5-12. [Custom Logo Backwall Display Advertising Formulate Horizontal]

2017 New Material Fashion Luggage Good SuitcaseHejnfelt, A.; Angelidaki, I. 2009. Anaerobic digestion of slaughterhouse by-products.LED Shining Ice Bucket Beer Wine Champagne Cooler: 1046-1054. [Sunup Aio-Sw10-M500-P-50e 500t Reverse Osmosis Seawater Desalination Plant]

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Structural Steel Frames for Steel Working Platform Manufactured by China FabricatorNkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [Eco-Friendly Disposable Kitchen Use Aluminum Foil Container]

www.kseidon.comProcházka, J.; Dolejs, P.; Maca, J.; Dohanyos, M. 2012.Clear Deep Oval/Oblong Glass Bakeware Set with Baking Dish/Pan/Plate/Tray. Applyed Microbiology Biotechnology 93: 439-47. [CNC Horizontal Boring and Milling Machine (STX611T series)]

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Copper Coated Flat Arc Air Gouging Carbon Graphite ElectrodeSung, S.; Liu, T. 2003. Ammonia inhibition on thermophilic anaerobic digestion. Chemosphere 353: 43-52. [CL2A-AT04 Comlom Camping Aluminium Alloy Rolling Folding Table]

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Received: April 10, 2015; Accepted: September 30, 2015

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