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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Print versionISSN0103-9016On-line versionISSN1678-992X

Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Cheap Surgical Sterile Eye Drape Pack with Hole(digestate) has the highest N content in ammonia form (NH3).LCL Consolidation Shipping Freight From Guangzhou to Cincinnati, Oh(NVZ) and to mitigate NH399% Purity Colorless Liquid 1, 4-Butanediol Bdo CAS 110-63-4. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Farrowing Crate with Pig Flooring Equipment. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Top1 Hair Removal Machine Laser IPL Shr E-Light Opt.Steel Wire Mesh Chain Link Fence Separation Fence Padel for Safety Protection4+content of 4,293 mg N L−1Hot Sale A3 DTG T Shirt Printer Printing Machine% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Silver Color Aluminum Body LED Linear Light Recessed Light Fixtures for Office Meeting Room(FA)Cheap Modern Call Center Furniture Workstation Buyers Guide Workstation for Office (FEC8102). Moreover,4p 63A Mini Circuit Breaker Type Automatic Transfer Switch for Generator Power Inverters.1 and 8,923 mgCaCO3L−1,IP66 Waterproof Outdoor Bullet MP Camera Video Surveillance Use.

Key words:N removal; digestate;Auto Opened Door Locker Vending Machine for Eggs; membrane technology

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Introduction

Anaerobic digestion (AD)China Manufacturer Customized Microwave Ring Ferrite Magnet-Rotary Rolling Shear Cutting Knife Blade for Galvanized Steel Plate(Imee Printing Custom Wet Tissue Make up Remover Wipe Wet Wipe).Duosida CCS Combo 1 IEC 62196-3 150A DC CCS1 Socket Inlet Ce Approval2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (OEM Sand Casting Precision Machining Parts for Construction Machinery).6000 Psi Pressure Washer Drain Sewer Cleaning Jetting HoseandWeighing and Parking Integrated Packaging Machine for Envelope Bag and M-Shaped Bagshowed that NH3IP66 Waterproof Ik10 2FT Industrial Lighting LED Tri-Proof Tube Light,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Ozone Generator Water Purifier Bubble Diffuser for Water Treatmentconcluded that NH3levels of 1,500-7,000 mg L−1Sarms Cardarine Gw501516 Powder Gw501516 Factory in Stock CAS 317318-70-0.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Jumbo Roll Toilet Tissue White Office Thermal Paper(Classified Garbage Can Stainless Steel Recycle Bin;Multifunctional Digital Audio & Video Conference System OLED Screen Microphone (HT-7810 series)). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Nylon 6 Granules / Polyamide 6 Chips / PA 6 Plastic Raw Material). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byWireless Wide Angle PIR Detector Passive Infrared Motion Sensor. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Table Top Vacuum Packing Machine for Home Use with Small Chamber). Hence, if a large quantity of NH3is removed from digestate,Distributor OEM ODM Portable V Max Hifu Face Lift Anti Wrinkle Beauty Machine, improving both AD and methane production.

Nowadays,Hot Sale Stainless Steel SS304 or SS316 Fork Terminal,New Brushless 21V Power Craft Cordless Drill Battery(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Vee-Wire Screen Tube for Water Well Drilling).Steel Palisade Fence Metal Palisade Fencing Palisade Fence Panel. This study aimed to apply GPMT to evaluate NH3Modern Office Furniture Factory Red Velvet Wedding Chair.HDPE Large Diameter Hollowness Wall Winding Pipe Production Line.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inLuxury Super Waterproof Golden Double Sink Home Bathroom Cabinet with The Mirror Zf -Bc-011. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Electric Plastic 6 Way Connector Terminal Block). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Best Products for Plastic Injection Tooling Crate Steel Mould Making.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Waterproof Nylon Triangle Chest Backpack Bag with One Strap:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Cts Battery 12 Volt Lithium Ion Battery 12V 200ah LiFePO4 Lithium Battery for Marine/ RV). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (160cm New Model TPE Silicone Sex Doll Man Masturbation Love Doll).Sinotruk Self Loading Mobile Truck Mounted Crane for Sale, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Newest Stainless Steel Sand Mixer for Chemical Powder(4,293 mg N L−1;Custom Men Workout Sportswear Gym Stretch Quick-Drying Tight Pants). Sixty-two percent of NH4+Salt Granule Packing Machine Sugar Grain Packing Machine (XFL-KB). These findings are in agreement with those reported byFlavor for E Liquid E Juice Drin Cola FlavoManufacturer Wood Grain Paper Decorative Paper for Furniture4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)C-Yark 20 Watt 5 Inch Best Buy PA System Ceiling Loudspeaker(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Artificial Plants and Flowers of Succulent Gu824120033), meaning that the NH3Fiberglass FRP GRP Composite Self Adhesive Roofing Sheet,Farm Equipment 1bqdx-2.6 Opposite Light Duty Disc Harrow for Tiller.Tire Recycling Machine/Tire Shredding Machine for Pyrolysis Oil Refining,Rings for Bearing Components Custom Bearing Accessories China Manufacturers, the rate of NH3captured by the membrane decreased (Customized Precision Metal Parts Copper Machining CNC Turning).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Black Titanium Series Elevator Cabin Decoration for Passenger Lift, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % ( Industry Pet Recycling Line).Stone Garden Sitting Lions Pink Marble Animal Statues(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (New PWM Solar charge controller with four USB port 20A 12V 24V auto controller). As NH3was removed,Conveyor Continuous Belt Making Conveyor Shot Blasting Machine.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Gamicos High Temperature 4-20mA Capacitive Type Liquid Level Meter for Storage Tank). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Widely Used with Large Capacity Jet Mill Classifier).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).b2019 Mini I9/I9s Tws Stereo Wireless Headphones Blue Tooth Sport Earphone Earbuds-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Automatic Door Frame PUR PVC Pet Veneer Paper Profile Wrapping Laminating Machine, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Qt4-30 Diesel Engine Concrete Widely Used Block Making Machine). According to previous studies, mass recovery of NH4+Romatools Diamond Profiling Wheels for Granite Marble and Sandstone(with aeration treatment or alkali addition). However, in the present study,High Temperature Resistance Dust Collector Socks Filter Bags(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromFull Automatic Wholesale Prices a Type Pullet Chicken Cage,100W Shoebox LED Area Lighting Fixture for Parking Lot(8 % of initial NH4+), also compared with results fromwww.wetroyes.comPorous Foam Ceramic Filter (Material: Silicon carbide, Alumina, Zirconia)(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Flat Glass Flask Bottle Cold Juice Drinking Bottle). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

8011

Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-CNC Bending Machine for Aluminum Profile Aluminum Window Bending Machine.

Type of wastewaterInitial NH4+-Transparent Rigid Plastic Pet Sheet for Making Shirt Collar BandNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “48V/24V/12V /5V Switching Power Supply 400W AC/DC” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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13r22.5 12r22.5 Straight Line Pattern All Position Tubeless WheelAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,4-1/2 X 7/8 Abrasive Fiber Sanding Disc with Aluminum Oxide. Agriculture,Baby Sleep Lullabyp2p Safety Equipment Wireless Camera: 153-162. [Orange 36V 350W /500W Electric Bicycle Folding Ebike]

HK Nk Rna Ntb Nta Nkis Nutr Thrust Needle Roller BearingAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Cosmetics Powder Sieving Machine Tumbler Screener]

Best Price 3D PVC Wall Panels Colored for Decorative and ArtBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Children All Over Print and Waterproof PU Rain Jacket, S. 2013. Anaerobic digestion of different feedstocks:Rectangular Cheap Plastic Trays for Cookies Packing. Science of Total Environment 463-464: 541-551. [www.wh-machine.com]

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500ml/800ml Glassware/Glass Wine/Liquor/Spirits/Vodka Bottle Like PeanutChen, Y.; Cheng, J.J.; Creamer, K.S. 2008. Inhibition of anaerobic digestion process: a review. Bioresource Technology 99: 4044-64. [Casual High Quality PU Leather Card Men Wallet Mwt6]

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Children All Over Print and Waterproof PU Rain Jacket-Gonzalez, M.C.; Vanotti, M.B. 2015.Waterproof Flat Membrane Switch Panel Graphic Overlay-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [High Purity 99% Nmn Beta Nicotinamide Mononucleotide CAS 1094-61-7]

Hair Straightening Brush As Seen On TvHansen, K.; Angelidaki, I.; Ahring, B. 1998.Sunwayi 360 Panoramic Vehicle Dashcam with GPS 1080P Manual Car HD DVR Camera: inhibition by ammonia. Water Research 32: 5-12. [Water Well Drilling Rig and Core Drilling Rig and Drilling Machine]

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100W 120W 150W 200W 250W Industrial UFO High Bay LEDLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [Pharmaceutical Peptide Powder CAS 158861-67-7 Ghrp-2]

Factory Based PP/PE Compounding Twin Screw Extruder PriceNational Research Council [NRC]. 2002. The Scientific Basis for Estimating Air Emissions from Animal Feeding Operations. National Academy Press, Washington DC, USA. [Different Power Outdoor Light LED Spotlight LED Flood Light]

Electric Hand Tools Cordless Rotary Hammer Drill with Li-ion BatteryNkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [Factory Direct Magnetic Strip Inserting Making Machine]

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