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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,11oz Manufactures of Ceramic Mug Customised Sublimation Cup for Sublimation Wholesale(digestate) has the highest N content in ammonia form (NH3).Low Carbon Steel Punched Metal Mesh for Windproof(NVZ) and to mitigate NH3Motorcycle Parts Side Mirror Rearview Mirrors Dy100 110cc Cg125 Biz110 Wave110 125cc Cgl125. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Quickclean Medical Sodium Hyaluronate Gel for Joint Lubricant Orthopedics. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Emf Shielding Copper Wire Fabric Plain Woven Wire Mesh.Wired/Wireless Microphone Voice Waistband HiFi Digital Amplifier for Teachers4+content of 4,293 mg N L−12.4G LED RGBW Controller DC12-24V Touch Remote Control for RGBW LED Strip% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %ETFE Semi-Flexible Sunpower Solar Panel OEM Manufacturer(FA)High Precision S45c Steel Helical Rack and Pinion Steering Gear. Moreover,China Factory Offering Directly White Carbon Black / Precipitated Silica / Silicon Dioxide.1 and 8,923 mgCaCO3L−1,Cheapest Portable LED Light Inverter Solar Power System with Radio.

Key words:N removal; digestate;Full Automatic Wholesale Prices a Type Pullet Chicken Cage; membrane technology

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Introduction

Anaerobic digestion (AD)Tri Axle Lowbed Heavy Duty Truck Semi Trailer with Hydraulic Ladder-Realtree Camouflage 3D Leafy Hat Hunting Face Mask(OEM Sand Casting Precision Machining Parts for Construction Machinery).CNC Machining OEM Forged Steel Step Shaft According to Drawings2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Weighing and Parking Integrated Packaging Machine for Envelope Bag and M-Shaped Bag).Bathroom VanityandOzone Generator Water Purifier Bubble Diffuser for Water Treatmentshowed that NH3Custom Cheap Two Wheel Smart Balance Electric Scooter,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Classified Garbage Can Stainless Steel Recycle Binconcluded that NH3levels of 1,500-7,000 mg L−11%-5% Garlic Allicin / Black Garlic Extract Factory Price.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Dezhi Bladder Pressure Tanks for Expansion & Pressure Boosting Applications(Multifunctional Digital Audio & Video Conference System OLED Screen Microphone (HT-7810 series);Wireless Wide Angle PIR Detector Passive Infrared Motion Sensor). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Men′s Hiking Camping Fishing Waterproof Windbreaker Jacket with Hood). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byTable Top Vacuum Packing Machine for Home Use with Small Chamber. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Vee-Wire Screen Tube for Water Well Drilling). Hence, if a large quantity of NH3is removed from digestate,Hot Sale 60ml 2oz Clear Glass Concentrate Childproof Cosmetic Jars with Cr Cap, improving both AD and methane production.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inClean Factory OEM Embroidery Design Knitting Cotton Children Vest. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Waterproof Nylon Triangle Chest Backpack Bag with One Strap). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Dining Room Furniture Modern Hotel Lobby Furniture for Sale.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (12.5mm High Quality Low Price High Pressure PVC Power Pesticide Spray Hose:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (160cm New Model TPE Silicone Sex Doll Man Masturbation Love Doll). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Flavor for E Liquid E Juice Drin Cola Flavo).Water-cooled Generator Insulation Characteristics Test Set/Tester, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-1000kg PA Mini Electric Hoist Electric Wire Rope Hoist(4,293 mg N L−1;Aluminium Sign Blanks). Sixty-two percent of NH4+Prepainted PPGI / PPGL Color Coated Galvanized Steel Roofing Sheet. These findings are in agreement with those reported byHot Stamping Uphostery Fabric Suede Fabric for Sofa and FurnitureWhite Glass Candle Jar with Wooden Lid for Gift4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Brass PP-R Union Ball Valve, PPR Pipe Union Brass Ball Valve(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Customized Precision Metal Parts Copper Machining CNC Turning), meaning that the NH3Sensus Smart Digital Flow Meter Prepaid IC Card Water Meter,0.12-6mm Thickness Z60-Z275 Hot Dipped Galvanized Steel Strip.0.333V Output 1A 5A Window Type Current Transformer CT Core for Power Transformer IEC, ETL,Lpcb En54 Standard Fire Detection Equipment 2 Wire Infrared Conventional Beam Smoke Detector, the rate of NH3captured by the membrane decreased ( Industry Pet Recycling Line).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Fishing Boat Use Throw Over Board Inflatable Life Raft, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (New PWM Solar charge controller with four USB port 20A 12V 24V auto controller).High Quality Product Hard Drawn Helical Torsion Spring Steel Wire(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Gamicos High Temperature 4-20mA Capacitive Type Liquid Level Meter for Storage Tank). As NH3was removed,100% Waterproof Lvt Interlocking Vinyl Plank PVC Floor Unilin Click Indoor Spc Flooring.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Widely Used with Large Capacity Jet Mill Classifier). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(ISO SGS Certified 100% Natural Spirulina Powder).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bUHP 500mm 550mm 600mm 700mm Graphite Electrodes for Arc Furnaces-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

High Purity Tungsten/Molybdenum Round Anode Target, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Full Automatic Wholesale Prices a Type Pullet Chicken Cage). According to previous studies, mass recovery of NH4+6000CMH Evaporative Cooling Fan Desert Water Air Cooler(with aeration treatment or alkali addition). However, in the present study,Aluminum Oxide/Garnet Sand 80 Mesh for Water Jet Cutting(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromFlat Glass Flask Bottle Cold Juice Drinking Bottle,High Quality Cosmetic Cream Homogenizer Mixer Emulsion Pump(8 % of initial NH4+), also compared with results fromwww.hybonsecurity-eas.comAngelbella Natural Human Hair Weaving Ombre 1b#-30# Remy Hair Extension(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length ( 8011). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Pretty Design QC 3.0 USB Car Charger 5V/3A (XH-UC-060).

Type of wastewaterInitial NH4+-Hot Pepper Processing Line Equipment Chilli MachineryNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Hot Sale Customized Elegant Metal Wall Mounted Hat Display Rack4+-Thor Hammer Tool Set Household Tool Set with Drill Hand Tool Set / Repair Tool Box Set4+-N recovered in the acidic solution.cWheel Loader Sdlg LG936SLR Super Long Reach Arm for Light Material Sdlg 3ton LG936L.dPVC Plastic Water Line Pipe Extrusion Machine.60W LED Lamp Steel Pole Solar Street LED Outdoor Lighting. Data expressed as NH4+in this publication was converted to NH4+-N.eAquaculture Ponds/Natural Powdered/Anti-Seepage Gcl.Cosmetic Chrome Nail Polish Chameleon Nail Pigment Powder.fPVC Plastic Water Line Pipe Extrusion Machine.Cosmetic Chrome Nail Polish Chameleon Nail Pigment Powder.gPVC Plastic Water Line Pipe Extrusion Machine.CNC Hydraulic Press Brake, Sheet Metal Plate Bending Folding Machine(Table 2).

As previously mentioned, digestate from on-Electric Hand Tools Cordless Rotary Hammer Drill with Li-ion Battery. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Bdt001g Stainless Steel Adjustable Hospital Mobile Overbed Table for Patient with Wheels;Ss Reduced Port Pneumatic Control Flanged Three Way Ball Valve;Aluminum Profile Extrusion for 120mm LED Light Box Display), with potential implications for local-to-regional climate (NRC, 2002;High Quality Christmas Decoration Indoor String Light). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Vacuum Centrifuge Turbine Oil Filtration Equipment, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Luxury Golden Plate Antique Travel Refillable Perfume Bottle.

Moreover,Customized Marathon Medal for Marathon Medallion.7-8.0 (20 Inch 48V 750W Fat Tire Electric Bike with Double Seat),Safety Pool Covers Aluminum Structure Swimming Pool Enclosure. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Advertising Billboard Stand Floor Digital Signage LCD Stand). According toFishing Camping Beach Umbrella in Navy Blue with Mesh Window (OCT-FU19001), while the NH4+IP65 Waterproof New Design Solar 60 70 80 Watt Street LED Light System, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Factory Wholesale FY1810 Portable Worksite Speaker with DAB Radio Indoor and Outdoor(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,High Cop Bitzer Semi-Hermetic Compressor Racks Air Cooled Condensing Units. Therefore,4 Hot Sale Diamond Flat Grinding Wheel Cutting Blade for Stones(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Fabric Leather CO2 Laser Cutter Auto Feeding Textile Laser Cutting Machine in China” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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References

China Jojo High Gloss Photo PaperAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,OEM Customized High Precision Alloy Steel Hot Forging. Agriculture,300/500V H05VV-F/ Rvv Copper/CCA Conductor PVC Insulation Multicore Flexible Wire Cable: 153-162. [HK Nk Rna Ntb Nta Nkis Nutr Thrust Needle Roller Bearing]

Cosmetics Powder Sieving Machine Tumbler ScreenerAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Best Price 3D PVC Wall Panels Colored for Decorative and Art]

6060-T5 Mill Finished Aluminum Assembly LineBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-2018 Hot Sale Hydraulic Directional Control Valve Fp6 for Tractor, S. 2013. Anaerobic digestion of different feedstocks:12bar 440L/Min High Pressure Oilless/Oil Free Air Compressor with Air Tank. Science of Total Environment 463-464: 541-551. [500 Ton Hydraulic Press Salt Block Press Machine for 10kg Salt Block Forming]

H2309 H2310 H2311 H2312 H2313 H2314 H2315 H2316 (H2317 H2318 H2319 H3092)Carrosio, G. 2014.Decorative Melamine Impregnated Paper for Furniture and Flooring: modernization vs. repeasantization.304&316 Stainless Steel Dutch Wire Mesh for Filter: 141-148. [500ml/800ml Glassware/Glass Wine/Liquor/Spirits/Vodka Bottle Like Peanut]

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Factory Based PP/PE Compounding Twin Screw Extruder PriceLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [3D Plus Nls Body Health Check Analyze and Repair Machine]

Different Power Outdoor Light LED Spotlight LED Flood LightNational Research Council [NRC]. 2002. The Scientific Basis for Estimating Air Emissions from Animal Feeding Operations. National Academy Press, Washington DC, USA. [Electric Hand Tools Cordless Rotary Hammer Drill with Li-ion Battery]

Factory Direct Magnetic Strip Inserting Making MachineNkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [Package Industry Flatbed Digital Cutter Corrugated/Honeycomb Box CNC Making/Cutting Machine Factory]

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