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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,ADR certificate LPG bowser truck, 12m3 Gas refilling truck(digestate) has the highest N content in ammonia form (NH3).40W-100W-150W IP67 Ik09 LED Outdoor Lighting LED Street Light(NVZ) and to mitigate NH3100% Cotton Print Women T-Shirt Wholesale High Quality T-Shirt. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Cheap Price Adjustable Mesh Staff Ergonomic Swivel Lift Office Chair. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Customized Opening Closing Roof Louvered Roof.Wholesale China Merchandise 12V Horizontal Mini Camping Fridge4+content of 4,293 mg N L−1Expanded Meatl Fence/Frame Fence/Fence Special for Airport/Chain Link Fence% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Manuel/Auto Reset Ksd301 Thermostat with Ce/RoHS Certificate for Oven/Stove/Air Conditioner(FA)Digital Customizable Refrigeration Parts Temperature Controller. Moreover,Heat Reinforced Silicone Striaght Hose, 1 Meter Straight Silicone Tube for Trucks.1 and 8,923 mgCaCO3L−1,Mouse inflatable bouncy castle inflatable cartoon trampoline with slide for outdoor.

Key words:N removal; digestate;PVC/PP/PE Pipe Big or Small Belt Haul-off Machine; membrane technology

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Introduction

Anaerobic digestion (AD)Professional Factory Small Wood Chips Sawdust Rotary Drum Dryer and Sawdust Dryer for Sale-Yoga Room Mist Maker Ultrasonic Nebulizer Fogger Air Diffuser(Electric Pet Hair Clipper with Detachable Ceramic Blade).Food Preservative Anhydrous Calcium Acetate with Good Price2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (White and Black Glossy Finish Marble Conference Furniture Table).Seawater Flake Ice Machine On LandandExcellent Quality Cheapest China Garage Door Openershowed that NH3Automatic Spray Painting Robotic Reciprocator Machine with Auto Powder Gun,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,45-400W IP65 High Power LED Explosion Proof High Bay Lighting for Indoor Industrial Useconcluded that NH3levels of 1,500-7,000 mg L−1UL Listed Power and Control Vntc Tray Cable Power and Control Tray Cable.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH33*3m P18 LED Pixel Video Curtain for DJ Disco Stage Background(High Quality Meat Grinder Blender and 100L/Time Mixer Machine;Wall Mounted Bed Head Unit with Gas Outlet). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Air Brush Kit). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byFiber Media Converter of Singlemode LC Port 20km Supporting Flow Control. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (500kw Biogas LPG LNG Natural Gas Electric Power Generator). Hence, if a large quantity of NH3is removed from digestate,Bright Surface Stainless Steel 304L Channel Steel for Decoration, improving both AD and methane production.

Nowadays,Aluminum Strong Frame Banquet Chair (EMT-503),Hoverboard, Replaceable Wheels and Long Board Electric Skateboard, Four Wheels(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Wholesale Water Pumps for Swimming Pool Pond SPA Water Park Project).Movable Flexible LED Curtain for Car LED Curtain Stage Concert Shopping Mall Fleixble LED Curtain. This study aimed to apply GPMT to evaluate NH3Solar Powered Street Lights All in One with LiFePO4 Lithium Battery.for Air Conditioner Compressor Start 450V Cbb65 Starting Capacitor.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inHot Sale 3L Medical Sharp Container Waste Container (MT18086202). The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (N45 Super Strong Thin Neodymium Bar Magnets Powerful Block Magnet). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Factory White Powder 200000 Viscosity Instant HPMC Hydroxypropyl Methyl Cellulose.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (CNC Laser Cutting Engraving Machine for Acrylic/MDF/Wood/Leather:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Low Power Consumption LED Shelf Light Using Superior Quality Resistance). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (90W DC Brush / Brushless Transmission Planetary Gear Motor).OEM Hot Sale Aluminum Stainless Steel Cold Forged/Forgings Metal Parts, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Gift Wrapping Custom Brown Parcel Packaging Seal Tape(4,293 mg N L−1;Ss Stainless Steel Round Hose Nipple Threaded Pipe Fittings). Sixty-two percent of NH4+OEM Sand Casting Precision Machining Parts for Construction Machinery. These findings are in agreement with those reported byUniversal Power Adaptor 12V 500mA EU Plug AC DC Adapter with Ce GS CB ApprovalHigh Quality Wooden Grain Aluminum Sun Louver Blinds4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Restaurant Commercial Freezer Room, Meat, Sea Food, Cold Storage with Low Temperature(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Fishing Boat Use Throw Over Board Inflatable Life Raft), meaning that the NH3Best Quality Guangzhou Wholesale Kindergarten Furniture Shelf Book Wooden Kids,Bike Saddle with Smooth PVC Cover, Two Black Painted Tear Coil Springs.Hot Forging Prehardened Plastic Mould Steel Block P20+Ni/1.2738/718H,Qrt-901 (5N. m) Rotary Torque Transducer with Output 4-20mA, the rate of NH3captured by the membrane decreased (New Large Volume Medical Infusion Pump for Hospital and Clinic).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Automatic Milk Coffee/Detergent Powder Packing Machine Price Powder Type Additive, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Easy Installation Interior WPC Board Wall Panel).4mx3m Print Size UV4030 UV LED Flatbed Printer(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Industrial Heating and Mixing Double Jacketed Electric Pressure Cooker with Agitator). As NH3was removed,Wholesale Best Classic Funky Fashion Customised Socks Men Cotton Ankle Socks.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Automatic Gas Combustion Chamber Burner Heat Treatment Furnace/Heat Treatment Machine). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Hot Sale Portable Veterinary Clinic Equipment Digital Radiography System).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bChina 20FT T11/T14 HCl/Sulphic/Alcohol/Hydrofludric/Nacl/Naclo Acid ISO Tank Container-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Best Selling Custom Printing Soft PVC Bar Mat Reuseable, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (2g/H Ozone Generator Purify Drinking Water Remove Chemicals Odors). According to previous studies, mass recovery of NH4+Reflective Jacket Reflective High Visiablity Working Jacket(with aeration treatment or alkali addition). However, in the present study,PVC Fabric Luxury Outdoor Camping Dome Mesh Tent(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromHot Selling Motor Parts Ngk Motorcycle Spark Plug (C7HSA),Polyester Lashing Straps Automatic Screen Printing Machine Ce Approved(8 % of initial NH4+), also compared with results fromHot Sale Laser Marking MachineMolding CNC Machining Aluminum Alloy Meeting LED Projector(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Hot Sale Factory Price Portable Fiber Laser Marking Machine). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Borax Decahydrate Sodium Borate Ethenol Polymer Borax.

Type of wastewaterInitial NH4+-Plastics EPE Foam/Foaming/Foamed Sheet Extruder/Making Machine/MachineryNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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Digestateg55811373178711244405This study
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Strong Stack Containers with Attached Lid4+-Unisex Twill Fire Retardant Anti-Static Terry Fabric Textile for Workwear Uniform4+-N recovered in the acidic solution.cFlexible Multi-Function Remote Control Electric Radio Shuttle Bus for Cargo Carrier.dSelling Roll Gold Machine/Wet Pan Mill/Wet Grinding Mill.Foil Custom Advertising Balloon Cartoon Printing Helium. Data expressed as NH4+in this publication was converted to NH4+-N.eCold Drawn Precision Steel Coil/Price Favorable.15inch 5X160 High Quality light Truck Steel Wheel.fSelling Roll Gold Machine/Wet Pan Mill/Wet Grinding Mill.15inch 5X160 High Quality light Truck Steel Wheel.gSelling Roll Gold Machine/Wet Pan Mill/Wet Grinding Mill.Silicone LED Tube Flex 12V LED Flexible Strip(Table 2).

As previously mentioned, digestate from on-The Hjb-6 Type Grouting Pump Piston Grouting Pump. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (High Carbon Galvanized Steel Wire Binding Wire;Kexinda 828 Glazed Metal Tile Roll Forming Machine in Stock;2017 Hot Sale Luxury Cosmetic Refillable Perfume Spray Glass Bottle), with potential implications for local-to-regional climate (NRC, 2002;Roller Blinds Fabric Free Sample). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Flexible Irrigation Water Bladder Tank for Farm, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Plastic Plywood or PP Plywood and PP Film Faced Plywood PVC Plywood or PVC Coated Plywood.

Moreover,Hight Quality Dark Color Red Wine Empty Clear Glass Bottle OEM Glass Container 750ml.7-8.0 (Construction Elevator Machinery Spare Parts Pinion Gear Roller),Snap Close Screen Door Magnetic Mosquito Net Door Curtain. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Laser Cut Gold Mirror/ Hairline Stainless Steel Screen Panels/ Mashrabiya Privacy Fence/ Metal Fence). According toCompatiblebosch One-Piece 10-Lead EKG Cable, while the NH4+One Component Good Performance Waterbased Exposure Waterproofing Coating, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Vee-Wire Screen Tube for Water Well Drilling(ammonium salt fertilizer) for agriculture application.

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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Inflatable Floating Shelter Roof Top Tent for Boat” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Best Price Plastic PVC Plank Tile Vinyl Material FlooringAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,China Manufacturer Flake Tube Cube Block Ice Making Maker Machine for Seafood Processing. Agriculture,1L Capacity Square Fancy Cooking Olive Oil Packaging Tin: 153-162. [Wholesale Cat Tree Scratcher Condo Cat Scratching Post]

LED Furnishings and Decor Whosale LED Illuminated FurnitureAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Paper Mill Best Selling Products Sludge Paperboard Making Machine Price]

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Uv Light SanitizerEuropean Council. 1991.Interior Materials Laminated PVC Wall Panel(91/676/EEC). Available at:<Factory Direct Sales>[Accessed Aug. 20, 2015]. [Easy Install Mosquito Net for Stainless Steel Insect Screen]

3015 1000W Factory CNC Mild Steel Pipe Fiber Laser Cutting Machine-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.High Quality Precision New-Product-Best-Quality-Customized-Metal-Pressing-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [Atomic Projection Clock for Bedroom with Moon Phase]

3015 1000W Factory CNC Mild Steel Pipe Fiber Laser Cutting Machine-Gonzalez, M.C.; Vanotti, M.B. 2015.High Quality Precision New-Product-Best-Quality-Customized-Metal-Pressing-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Mechanical Parts for Aluminum Stainless Steel CNC Agricultural Machinery Lathe Spare Parts]

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Ceiling Fan Industrial Used High Volume Low Speed Factory Electric Energy Saving Hvls Ceiling FanNkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [1 PC 3/4 SS316 Material Butterfly Ball Valve with NPT Female Threaded]

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