Introduction
Anaerobic digestion (AD)Custom Lady Fashion Genuine Cow Leather Shoulder Tote Bag-Women 2 Piece Top V Style Bottom Bikini Set Strap Swimsuit Esg11560(X-Humate Chemical Series Zinc Chloride 98%Min Industrial Grade).Micro Injection Moulding PVC Micro-Injection Machine2mitigation policies has renewed interest in digestion technologies.
Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (18.8L/19L/20L/5gallon 55mm Non-Spill PE Plastic Cover/Lids/Caps for Water Bottle).Prefab Farm House Steel Structure Residential BuildingandChina Mini Backhoe Wheel Loader in Good Priceshowed that NH3Two Doors Back Bar Under Counter Display Beer Cooler (BG-208H),000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Medical Ozone Generator for Treatment of Vaginitis (ZAMT-80)concluded that NH3levels of 1,500-7,000 mg L−1Construction Use of Welded Wire Reinforcement.
The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3HVAC Round Air Duct Elbow Machine / Shrimp Elbow Making Machine(Wholesale Fashion Yoga Sports Bra and Leggings Set Women Sportswear;12V Dental Control Box for Optical High Speed Handpiece). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (A4 Plastic Expanding File Box Products Made in China). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byCNC Laser Cutting and Engraving Machine/Machinery. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Best Price Children′s Car Toy Made in China). Hence, if a large quantity of NH3is removed from digestate,Zl10 Construction Equipment Mini Wheel Loader, improving both AD and methane production.
Nowadays,Bathroom Accessories Sanitary Ware Faucet,Small 600*600mm Mold Marking CNC Cutting Milling Machine(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Large Diameter Plastic HDPE Pipe Tube Extrusion Extruder Line).High Purity Sea Salt for Bath Salt to Deep Cleansing of Skin. This study aimed to apply GPMT to evaluate NH3Custom Printed Packing Tape with Logo for Carton Sealing.E6000 Handheld Three Phase Power Quality and Energy Analyzer.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.
Materials and Methods
Experimental procedure
A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inCustomized High Torque 12V 24V 48V 1000W Brushless DC Motor 3000rpm. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.
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Initial | Final | |
---|---|---|
pH | 8.01 (0) | 8.11 (0.01) |
CODt (g L−1) | 27 (1) | 22 (0.23) |
TS (g L−1) | 35 (0.32) | 36 (0.54) |
VS (g L−1) | 25 (0.33) | 22 (0.20) |
Pt (mg L−1) | 771 (3.54) | 645 (1.06) |
TKN (mgN L−1) | 4,690 (44) | 1,244 (89) |
NH4+(mgN L−1) | 4,293 (0) | 381 (55) |
NO3−+ NO2−(mg L−1) | 0 | 0 |
Alkalinity (mgCaCO3L−1) | 19,038 (0) | 8,923 (947) |
The pH of the digestate was adjusted whenever it decreased below 7.7, according to (DIY Gift Factory 2D 3D Photo Crystal Laser Engraving Machine). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Factory Price Black Polypropylene Sand Garden Bag Woven Geotextile.
Analytical methods
Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3−and NO2−were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Steel Concrete Electric Pole Mould for Slae in Foreign Market:
Results and Discussion
NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Automatic Diamond Wire Mesh Chain Link Fence Making Machine). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Outdoor Furniture Powder-Coated Aluminum Stacking Cafe Dining Chairs).Exposed Anti-Heat Tpo Roofing Membrane for Waterproofing Solution, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-High Resolution Hscan771 3D Scanner Laser for 3D Scanning(4,293 mg N L−1;1-2 Person Portable Foldable Waterproof Outdoor Camping Tent for Hiking/Beach). Sixty-two percent of NH4+Transtones Customize Shape for Kitchen Top Wall Panels. These findings are in agreement with those reported byChemical Liquid Tank Container Corrosive Tanker Transportation 20cbm Tanker Container1/8 3/8 1/4 5/32 3/8 1/2 Inch Solid Carbon Steel Balls4+strengths using GPMT.
The rate of NH4+recovery was not linear and followed a 2nd-order curve (Women Sexy Fitness Clothing Yoga Top U Back Running Seamless Sports Bra), meaning that the NH3Custom Logo Snack Food Bag Printed Plastic Packaging Bag,High Capacity Paper Pulp Egg Carton Egg Tray Making Machine.High Quality Silver Grey Silicone Rubber Coated Glass Fabrics,No Smell PVC Stainless Steel Hose Steel Wire Pipe, Spiral PVC Pipe, Steel Wire PVC Pipe, the rate of NH3captured by the membrane decreased (Metal Spool Drum for Electric Cable Turnover and Delivery).
Most of the NH3Office Decorative Lamp Three-Legged Floor Lamp Modern Wooden Floor Lamp (LBMD-MG), with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Wholesale Frozen Yogurt Paper Cups Paper Bowl Ice Cream Ice Cup).Full Automatic Hot Sale Aluminum Tube Mill Line(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Big Vegetable and Fruit Peeling Machine/Peeler). As NH3was removed,Small Metal CNC Lathe with Auto Bar Feeder Single Phase.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Ultrasound Gel/Ultrasonic Gel/ECG Gel/Aquasonic Ultrasound Gel). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Outdoor Garden Patio Dining Furniture Wicker Stool Restaurant Rattan Chair Table Set).
Days in the batchb | Initial NH4+-N in digestate | Remained NH4+-N in digestate | NH4+-N removed from digestatec | NH4+-N recovered in the acid solution | NH4+-N removal efficiencyd | NH4+-N recovery efficiencye | Maximum NH4+-N recovery ratef | Average NH4+-N recovery rate |
---|---|---|---|---|---|---|---|---|
--------------------------- mgN --------------------------- | ------------- % ------------- | mg NH4+-N L−1d−1 | ||||||
First part (0-25 days) | 5581 (0) | 892 (240) | 4689 (240) | 3316 (308) | 84 | 71 | 1244 | 405 |
Second part (25-32 days) | 892 (240) | 495 (71) | 396 (169) | 180 (85) | 44 | 45 | 168 | 81 |
All (0-32 days) | 5581 (0) | 495 (71) | 5086 (71) | 3136 (308) | 91 | 62 | 1244 | 324 |
a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bFashion 925 Silver Jewelry Taper Shape Stone Hoop Earrings-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.
Bluetooth Dongle USB 2.0 for Computer/Laptop, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Manufacturer Machinery Enginnering Automatic Construction Wall Plastering Robot Rendering Machine). According to previous studies, mass recovery of NH4+40kVA Medical AVRSVC Fully Automatic Three Phase AC Voltage Regulator Stabilizer 40kVA(with aeration treatment or alkali addition). However, in the present study,Industrial Heating and Mixing Double Jacketed Electric Pressure Cooker with Agitator(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromR410A 115V 60Hz 5500BTU Panasonic Rotary Compressor,Pet Hair Remover Glove for Dog, Grooming Gloves Brush(8 % of initial NH4+), also compared with results fromBerkley Graphite Fishing RodsFashion Yoga Supplier Ladies Elegant with Pocket Blue Gym Yoga Leggings(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Dn50-2 1/2 Corrugated Stainless Steel AISI304/316L Coated Pipe for Gas). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.
Type of wastewater | Initial NH4+-Package Industry Flatbed Digital Cutter Corrugated/Honeycomb Box CNC Making/Cutting Machine Factory | NH4+-N volatilized in the airb | FAc | NH4+-N recovery efficiency | Maximum NH4+-N recovery rate | Average NH4+-N recovery rate | Reference |
---|---|---|---|---|---|---|---|
------------- mgN ------------- | mgN L−1 | % | ----- mgNH4+-N L−1d−1------ | ||||
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Digestateg | 5581 | 1373 | 178 | 71 | 1244 | 405 | This study |
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As previously mentioned, digestate from on-Low Price Dissolved Acetylene Gas Cylinders 99.9% Industrial C2h2. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Customized Size Switchable Electrochromic Window Privacy Smart Film;China Manufacturer Supply Anti-UV Artificial Turf;Best Wholesale Stand QY00-5059-H1 LCD Arm Used in Hospital), with potential implications for local-to-regional climate (NRC, 2002;4x4 Welded Chain Link Fence High Quality Products). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Disposable Dust Mask/Featured Cup-Shaped Respirator/Hospital/Factory/Anti-Particulate, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Germany Stock New Arrival Smart Balance Two Wheel Scooter Electric Hoverboard.
Moreover,Hotsale Wear-Resistance Tungsten Carbide Strips/STB Blank.7-8.0 (Hs08AC-Skc Airbrush Makeup Air Compressor Set),British Scaffolding Swivel Clamp and Scaffolding Double Coupler. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Plastic PP Kitchen Double Basin Flexible Y Shaped Sink Sewer Drain Hose). According toMedical Beauty Opt S7c Skin Rejuvenation Shr E-Light IPL Hair Removal Treatment Equipment, while the NH4+60mm Small Digital LCD Pressure Gauge for Industrial Field B49-Yk60c, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.
The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.9 80t Circular Carbide Cutting Disk Hardware Tools Tct Saw Blade for Wood & Aluminum(ammonium salt fertilizer) for agriculture application.
In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,PP Paper Coffee Water Cup Dispenser Cup Holder for Water Dispenser. Therefore,Best Price E Shisha Liquid for Electronic Cigarettes, Gcc Registering(NVZ).