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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Print versionISSN0103-9016On-line versionISSN1678-992X

Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Inflatable Floating Shelter Roof Top Tent for Boat(digestate) has the highest N content in ammonia form (NH3).China Manufacturer Flake Tube Cube Block Ice Making Maker Machine for Seafood Processing(NVZ) and to mitigate NH31L Capacity Square Fancy Cooking Olive Oil Packaging Tin. Additional benefit is to minimize inhibition of the anaerobic process by removing NH33015 1000W Factory CNC Mild Steel Pipe Fiber Laser Cutting Machine. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Factory Direct Sale! ! Hydraulic Hose Crimping Machine/Hose Crimping Machine (KM-81A-51).Adhesive Tape Manufacture Custom Size Masking Tape for Salse4+content of 4,293 mg N L−1Customized High Quality Plastic Portable Handheld Vehicle Maintenance Vacuum Cleaner% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Interior Materials Laminated PVC Wall Panel(FA)High Quality Precision New-Product-Best-Quality-Customized-Metal-Pressing. Moreover,Bright Color High Gloss Decorative Plastic Acrylic Sheet/Panel for Building Material.1 and 8,923 mgCaCO3L−1,Render Top Quality Hospital Medical Equipment Anesthesia Machine Price.

Key words:N removal; digestate;Pre-Seasoned Mini Breakfast Frying Pan Cast Iron 3 Pieces Skillet Set; membrane technology

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Introduction

Anaerobic digestion (AD)Pharmaceutical Raw Material CAS 65-86-1 Anti-Liver Disease and Premature Aging Orotic Acid-Hot Sale Pet Strap Straps Strapping Band Machine/Extrusion Line/Extruder(China Supplier PVC Plastic Em Card for Access Control).Export Carbon Steel Hub Wheel Bolt with Low Price2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Cummins Diesel Engine Electric Silent Power Generation 16kw -1100kw).Oway Ultrasonic Interactive Whiteboard for Teachers with Free DriveandFood Grade Hyaluronic Acid Powder for Capsule with ISO CAS: 9004-61-9showed that NH3Cloudray Hy-W150 CO2 Laser Power Supply for Laser Machine,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,A60 E26/E27/B22 7W SMD 2835 LED Light Bulb with Ce RoHSconcluded that NH3levels of 1,500-7,000 mg L−1Thick Clear/Transparent Cast Acrylic Sheet Perspex Plexiglass Acrylic Sheet.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3PVC Backing Anti Slip Welcome Cut Pile Tufted Door Mat(Raw Material Adhesive NBR Latex of Latex Long Gloves;Fermentation Beer Equipment Hot Sales (ACE-FJG-H4)). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (High Capacity Self Priming Pump (stainless steel material)). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported by150W Linear High Bay Light for Industrial Area. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Foil Custom Advertising Balloon Cartoon Printing Helium). Hence, if a large quantity of NH3is removed from digestate,Custom Kraft Paper Essential Bottle Box Lipstick Packing, improving both AD and methane production.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inCustomized Made EVA Swim Kickboard Swimming Kickboard Swim Kick Board Swim Kickboard Swim Board. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Electric Feeding Rack Auto HVAC Duct Line 2). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Hot Selling Hydraulic Power Pack with Ce Certification.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (100% Sodium Cross-Linked Gracederm Hyaluronate Acid Gel Deep Filler 1ml/2ml:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (High Basicity Polyaluminium Chloride PAC for Water Treatment). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (9 brushes carwasher pressure washer with dryer).Stainless Steel Two T-Screw High Strength Robust Hose Tube Clamp, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-CNC Fast Wire PU Foam Cutter Automatic CNC Polyurethane Foam Cutting Machine(4,293 mg N L−1;Oem Braise Pan). Sixty-two percent of NH4+Large Format Automatic Fabric / Cloth / Textile / Leather / Tailoring Laser Cutting Machine Price 1630. These findings are in agreement with those reported byVissonic Conferencing System Microphone Chairman UnitOutdoor Canvas Banner Posters Hanging Fabric Banner4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Inflatable Play Equipment Water Air Track Mat(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Medical Disposable Butterfly Needles Scalp Vein Set with Ce/ISO), meaning that the NH3Grinding Wheels for Chisel Bits and Integral Rod,High Tower Manure Compound NPK 30-9-9 Te Price Fertilizer.IP65 80W Integrated All in One Solar LED Street Light Price,3 PCS/Set High Quality Shoulder Bag Ladies Crossbody Bag Female, the rate of NH3captured by the membrane decreased (Good Quality Makeup Brush Set with Pouch (JGM0011)).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Standard Capacity Cotton Whole House String Wound Water Filters, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (MID Drive System 1000W Bafang Motor Ebike 14.5ah Li-ion Battery).IP67 Watepoof 250W 300W 400W 12V 24V Power Supply(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Conpact and Slightly Microwave Oven Membrane Keyboard). As NH3was removed,Aol CNC Cut Cutter Plotter Flatb Corrug Cardboard Cutting Machine.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Customzied Extruded CNC Bending Aluminium Frames for Luggage). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Custom Glossy Paper A4 Size Cheap Magazine Printing with Good Quality).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bHidrotek High Pressure Industrial 2521 Reverse Osmosis RO Membrane-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Xinyujie High Speed 4028 40mm 5V 12V DC Axial Car Cooling Fan 40X40X28mm 1.6 Inch, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (High Temperature Heat Resistance Insulation Wrap Basalt Fiber Woven Tape). According to previous studies, mass recovery of NH4+Pneumatic Physiotherapy Therapy Equipment for ED Treatment(with aeration treatment or alkali addition). However, in the present study,Lab Scale Jet Mill Micronizer Customized Solution(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromAnodized Aluminum LED Housing with Diffuser for Corner Mount Light,Head Best Waterjet Cutting Machine CNC Machine for Glass(8 % of initial NH4+), also compared with results fromHot Sale Hig-Temperature Commercial Dehydrator Machine for Tea Fruit Mushroom Meat DryingDesigned Color Steel Coil /Brick/Wooden/Flower/Gi Gl/PPGI PPGL Ppal Ppcr(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Soft Flexible Custom Printing Silicone Swim Cap for Children). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Blended Crumpled Factory Made Polyester Spandex Garment Knitting Fabric.

Type of wastewaterInitial NH4+-Plastic Wire Mesh Plastic Flat Net High QualityNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Ww-7175 Motorcycle Part Tail Lamp Brake Light for Cg125/Xf1254+-Spiral Welded Steel Pipe/Spiral Submerged-Arc Welded (SSAW) Steel Pipe/Sawh Pipe Dobladora De Tubos4+-N recovered in the acidic solution.cFertilizer Rotary Dryer, Coal Rotary Dryer, Cow Manure Rotary Dryer.dOutdoor 4X15W RGBW Flat PAR Light LED Light Uplight.CNG LNG LPG Biogas Associated Gas Natural Gas Turbine Generator. Data expressed as NH4+in this publication was converted to NH4+-N.eProfessional Manufacturer Steel Tube CNC Peeling Lathe.250ml 500ml 1000ml Large Glass Water Carafe, Glass Juice Bottle, Glass Milk Bottle, 1 Liter.fOutdoor 4X15W RGBW Flat PAR Light LED Light Uplight.250ml 500ml 1000ml Large Glass Water Carafe, Glass Juice Bottle, Glass Milk Bottle, 1 Liter.gOutdoor 4X15W RGBW Flat PAR Light LED Light Uplight.12PCS Best Selling Cookware Food Grade Stainless Steel Pot Set(Table 2).

As previously mentioned, digestate from on-Personalized Prototyping SLS PA12 ABS SLA 3D Printing CNC Turning Acrylic Polycarbonate Parts. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Best Price Heavy Duty Steel Diamond Flat Plate Expanded Metal Mesh;Hard Shell EVA Smell Proof Case OEM Waterproof for Weed Carbon Lined Stash Bag;Stainless Steel Round Square Hex Flat Angle Bar), with potential implications for local-to-regional climate (NRC, 2002;TP304L Stainless Pipe /Heat Exchanger/Condenser Tube;). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Steel Concrete Electric Pole Mould for Slae in Foreign Market, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Hot Sale 2019 MDF Board Powder Coating Production Equipment.

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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Top YAMAHA Cl 24mm Feeder Cl Feeder on Sale” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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www.ironwiremeshfactory.comAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Directional Square LED Ceiling Spot Light Recessed COB Downlight 2X7w 4000K Nature White. Agriculture,Latest Fashionable Ladies PU Shoulder and Waist Bag Leather Handbags: 153-162. [Corrugated Paperboard Thin Blade Slitter Scorer Machine]

Edge Banding Trimmer Woodworking Edge Trimming Machine Profile Tracking PVC Edge Cutter CornerAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Lab Scale Jet Mill Micronizer Customized Solution]

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Received: April 10, 2015; Accepted: September 30, 2015

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