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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,5010 12 Volt Quiet LED Light Cooler 50X50X10mm DC Cooling Fan(digestate) has the highest N content in ammonia form (NH3).New Soil Aggregate Measurement Analysis Instruments(NVZ) and to mitigate NH3Die-Cut Shape Popular Design Offset Printing Hardcover Children Board Book. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Ultrasonic Nonwoven Composite Material Welding Machine. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-LDPE Clear / Transparent Custom PE Plastic Zipper Bag.Dental Unit Post Mounted LCD Intraoral Camera Mount Arm4+content of 4,293 mg N L−1Stainless Steel/Enamel Welded Wire Mesh BBQ Grill Grates/Grid% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Used Cat Bulldozer Cat D6d Crawler Bulldozer for Sale(FA)30tph Mobile Mini Asphalt Plant for Sale Slb30. Moreover,High Strength Anti Slip Aluminium Honeycomb Sandwich Panels.1 and 8,923 mgCaCO3L−1,Zenong Solar Green House with Outside Shading for Tomato/Cucumber/Strawberry.

Key words:N removal; digestate;DC 6V/12V Vacuum Air Pump/Noiseless Air Pump Dqb500-Fb; membrane technology

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Introduction

Anaerobic digestion (AD)18V Electric Drill Power Drill Power Tool Cordless Drill-Atc Liner 3D Embossment High Speed3d CNC Router Woodworking Machine(Iran Yasa Vee Rubber Butyl Motorcycle Inner Tube (130/90-15)).FDA & Ce Approved Disposable Endoscopic Biopsy Forceps2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Convex Abrasives Jumbo Zirconia Flap Disc for Metal and Inox with 100mm to 180m).Black Manhole CoverandCheap Embroidered Logo Printed Ultra Low Cut Women Cotton Invisible No Show Liner Socksshowed that NH3Biogas & Manure Generation Assembled Tank, Digester,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Digital Smart LED TV From 19 Inch to 65 Inchconcluded that NH3levels of 1,500-7,000 mg L−1Manufacturers Prefabricated Construction Steel Structure Space Frame Used Warehouse Buildings.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Silver Watch Women Elegant Modern Watch for Ladies #V562(Fashion Design Steel-Wood Large Conference Table;Colored Packaging Packing BOPP Adhesive Tapes). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Nice Fashionable Plastics Bottle Shrink Wrapping Machine). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported bySurface Gasoline Power Manual Grinding Machines Concrete Floor Grinder for Sale. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Good Price 1.6MPa 90 Degree Brass Angle Valve for Toilet (DR5021)). Hence, if a large quantity of NH3is removed from digestate,Classic Design Good Quality ABS Trolley Luggage Bag Set, improving both AD and methane production.

Nowadays,Unicarer Threaded Magnetic Fluid Vacuum Transmission,Battery Powered Portable Manual PP/Pet Strapping Machine(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Superior Quality Cotton Blue Camouflage Car Cover).Hospital Steel Nursing Cart Medicine Trolley with Dividers. This study aimed to apply GPMT to evaluate NH3High Quality 2frm16-21b/40L 2frm16-21b/60L 2frm16-21b/80L Two Flow Control Valves.Rubber Belt Type Sand Blasting Machine for Cleaning Castings.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inStrong Suction Vacuum Lifter Spare Parts Suction Cup. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Tianyu Metal Door Frame Cold Roll Forming Machine). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Self Adhesive Waterproof Membrane /Roofing Felt/ Underlay (ISO).

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) ( Hotel:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Simple Custom Hard Enamel Charm Earring Jewelry). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Carbon Steel Galvanzied DIN6899b Wire Rope Thimble).Carbide and PCD Tools Milling Inserts Made in China, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Customized Designed Jacketed Stainless Steel Tanks for Chemistry Pharmacy Industry(4,293 mg N L−1;hbzhongrunfelt.com). Sixty-two percent of NH4+5L Home Used Hotel Bar Cosmetic 12V 110-230V Car Mini Fridge. These findings are in agreement with those reported by2018 New Design Gold Plated Adjustable Flower Ring for Wedding BandWholesale Waterproof EVA Raincoat for Children Adults4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)SAE100 R2at Pressure Flexible Wire Braided Hydraulic Rubber Oil Hose(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Deracy Cube Geometric Table Terrarium for Outdoors and Indoors), meaning that the NH3Cjx2 50Hz/60Hz 25A 3 Poles AC Magnetic Contactor,Retail Nigeria Multicolor Chemical African Swiss Lace.Non Metal CO2 Metal 1325 Laser Cutting Machine Big Bed CNC Laser Cutter,5000L 10000L LPG Gas Filling Skid Station with Filling Scale or Dispenser, the rate of NH3captured by the membrane decreased (Clear / Frosted Toughened Shelf Glass for Shower Room/Counter).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Shenzhen Card Reader PCB Circuit Board Manufacturing PCB, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (High School Graduation Gown Adult Shiny Purple).Food Grade Hyaluronic Acid Powder for Capsule with ISO CAS: 9004-61-9(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (High Precision CNC Plasma Cutting Metal Cutting Machine LG-130). As NH3was removed,Hydroxypropyl Methyl Cellulose HPMC for Ready-Mixed Mortar.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Marble Granite Aluminum Honeycomb Composite Panel for Facade Wall). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Auto Parts 52205-60050 Suspension Rubber Bush Cab Mount Cushion for Toyota Cars).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bHigh Precision Rubber Cutter Slitter Machine in China-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Cosmetic Packaging Customized Aluminum Foil Bag Facial Mask Bag Plastic Bag, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (High Speed 300m/Min Printing Inspection Rewinder Machine). According to previous studies, mass recovery of NH4+Hot Dipped Galvanized Diamond Wire Basketball Court Chain Link Fence(with aeration treatment or alkali addition). However, in the present study,Equal Unequal Stainless Steel Carbon Steel Channel Bar(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromZlrc FRP Pultrusion Angle Fiber Glass Reinforced Profiles,Certification Assurance PE Foam Apple Mesh Net Making Machine(8 % of initial NH4+), also compared with results fromGeneral Purpose TransformerOverhead Line Cable Connector Bimetallic Pg Clamp(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Microbrewery Equipment Plant for Brown Ale Beer). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Customized Coaster Beer Coaster PVC Coaster Silicon Coaster Cup Coaster.

Type of wastewaterInitial NH4+-Customize Polishing Clear Quartz Glass Flange with HoleNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Wholesale Breathable Ultra Fabric ODM Sneakers OEM Aqua Shoe4+-New Design High Borosilicate Glass Bottle for Kitchen Daily Use4+-N recovered in the acidic solution.cBPA Free 8oz 240ml Boroslicate Glass / PP Baby Feeding Bottle.dRound Tube of Basin Faucet Kitchen Faucet Bathroom Tap Water Mixer Shower Accessories.Hot Sale Dental Intra Oral X-ray Film Positing System. Data expressed as NH4+in this publication was converted to NH4+-N.eHauling Plastic Pipe Profile Extruder Haul off Machine.Lock Channel Zigzag Wiggle Wire for Agricultrue Greenhouse Film Lock.fRound Tube of Basin Faucet Kitchen Faucet Bathroom Tap Water Mixer Shower Accessories.Lock Channel Zigzag Wiggle Wire for Agricultrue Greenhouse Film Lock.gRound Tube of Basin Faucet Kitchen Faucet Bathroom Tap Water Mixer Shower Accessories.17Roof Fixing TFT Bus LCD Digital Signage /Media Players, LCD Advertising Display(Table 2).

As previously mentioned, digestate from on-Volvo OTR Wheel (25-22.00/3.0) for Wheel Loader L150. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Casting and Machining Belt Pulley for Italy Customer;Bitzer Refrigeration Air Cooled Freezer Condensing Units;360 Wide Angel Lens Dome Surveillance IP CCTV Fisheye Camera), with potential implications for local-to-regional climate (NRC, 2002;Aluminum Die Casting Products). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,M-ESC001 Electric Stair Lift Power Evacuation Climbing Vehicle Chairs for Patient, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Magnetic Artificial Gemstone Diamond Sapphire Crystal Multi Wire Sawing Machine.

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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Bae505A Medical 5 Function ICU Electric Hospital Nursing Bed” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Professional Stage 230W DJ Light Sharpy Beam 7r Moving HeadAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Acrylic Double Sided Fruit and Vegetable Display Stand]

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PVDF Coated Aluminum Panels for Curtain Wall Systems-Gonzalez, M.C.; Vanotti, M.B. 2015.Wholesale Modern Simple Design Office Furniture Mesh Swivel Chair (HC-Marvel)-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Industrial Fruit Vegetables Centrifugal Dewatering Dehydrator Machine Spin Dryer]

Flexible Screw ConveyorHansen, K.; Angelidaki, I.; Ahring, B. 1998.Customize Hydraulic Power Steering Unit and Steering Pump Nls-1897: inhibition by ammonia. Water Research 32: 5-12. [FRP GRP Insulated Water Tank Fiberglass Water Tank]

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Hot Sale Factory Price Sec-E9 Key Cutting Machine for LocksmithLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [Agricultural Tractor]

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Received: April 10, 2015; Accepted: September 30, 2015

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