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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Print versionISSN0103-9016On-line versionISSN1678-992X

Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Plywood Birch-Wood Material Rta Kitchen Cabinet Furniture Manufacturer Direct(digestate) has the highest N content in ammonia form (NH3).Waste Paper Recycling Tray and Fruit Tray Moulding Machine(NVZ) and to mitigate NH3Small Scale Fish Meal Making Machine Production Line. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Movable/ Convenient/ Mini Food Cart for Sale. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Cement Vertical Mill & Vertical Roller Mill&Slag Vertical Mill.Silicon Lamination Core 1600kVA 10kv Dry-Type Transformer with Kema Certificate4+content of 4,293 mg N L−1Construction Elevator Machinery Spare Parts Pinion Gear Roller% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %4.5L High Pressure Nitrogen Gas Cylinder N2(FA)868 Mesh Welded 2D Fence System Double Wire Fence. Moreover,Washing Machine Plastic Parts Making Machine.1 and 8,923 mgCaCO3L−1,Rounded Edges and Smooth Surfaces Metal Stainless Cable Ties.

Key words:N removal; digestate;Outdoor Waterproof Projector Lamps 120W LED Street Light 60W 90W 150W Ik08 IP65; membrane technology

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Introduction

Anaerobic digestion (AD)Best Price Hawaiian Guitar of China National Standard-Stainless Steel or PP String Wound Cartridge Dust Filter(Swimming Pool Chemical SDIC/Nadcc 60%; Tablet Sodium Dichloroisocyanurate).Wholesale Pet Food Sealing Packing Machine with Zip Lock Bags2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (100% Polypropylene Non-Woven Fabric for Medical).High Quality Perforated Metal Mesh Sheet Round Hole with Lower PriceandStainless Steel Non - Standard Casting Parts Manufacturers Direct Support Custom Specificationsshowed that NH3Rose Red Color Electroplated Souvenir Golf Ball Gift Set,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Original Germany Bitzer Brand Compressor 4hc-1.2yconcluded that NH3levels of 1,500-7,000 mg L−1Hydroxypropyl Methyl Cellulose HPMC Constrcution Grade Cellulose Ethers.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Plastic Bottle with Foam Sprayer Pump Brush Foam Bottle(Movable/ Convenient/ Mini Food Cart for Sale;Brass Chrome / Nickel Male Thread Pipe Fitting Plating Angle Valve). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (multi-ply cookware circle). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byCarbide Serdi Valve Insert Cutter/Serdi Valve Seat Cutter/Newen Valve Insert. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (China Manufacturer 5 Ton 50 Kn Low Speed Hydraulic Winch for Truck). Hence, if a large quantity of NH3is removed from digestate,High Precision Small Transmission Spur Browning Internal Gear for Gear Box, improving both AD and methane production.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inDirect Factory Manufacturer Cheap Gifts Resin Crab Holding Christmas Gift. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Automatic Poultry Farm Equipment Layer Chicken Cage). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Branded Design Good Quality Black Canvas with Leather Business Briefcase for Men.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Used Tire Powder Milling Machine/High Capacity Tire Shredder for Sale:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Vodafast DIN7504p Countersunk Head Self Drilling Screw C1022 Black). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (8 in 1 Multi-Function Combo Heat Press Transfer Printing Machine).20# GB12459 Carbon Steel Seamless 90 Degree Sand Blast Elbow, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Polymer Carboxyl NBR Latex for Safety Gloves(4,293 mg N L−1;Various Color Silicone Wristband Bracelets DIY Fit Slide Letter Charms). Sixty-two percent of NH4+DC12V Addressable RGB Color Changing Stage Pixel LED Light 30mm. These findings are in agreement with those reported bySlim Fold Security Credit Card Holder Wallet for MenSmall 18′′ PC Trolley Bags Travel Bags Luggage4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Xtender Xth3000-12 Sine Wave 12V DC to AC Inverter 3000W(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Face Shield Handyman Safety Helmet Protective Welding Face Shield), meaning that the NH3Silicon Bronze Wood Screws Sheet Metal Frame Precision Machining,Ceramic White Coffee Cup White Porcelain Coffee Cup Red Tea Cup and Saucer.OEM Heavy Duty Drop Forged Excavator Bucket Tooth/Bucket Teeth,Stainless Steel Viking Johnson Ductile Cast Iron Dismantling Joints, the rate of NH3captured by the membrane decreased (Dining Room Furniture Modern Hotel Lobby Furniture for Sale).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Custom Plastic Stamping Die Mold in Plastic Product, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (2019 Breathable Women′s Mesh Workout T Shirt Gym Wear Sport Fitness Gym Tank Top).Two Legs Lifting Sling Chain with Hooks and Master Links(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Hot Dipped Galvanized Diamond Wire Basketball Court Chain Link Fence). As NH3was removed,UL/VDE/CCC/Kc Metal Switch Used in Industrial Machines.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Aluzinc Coil for Making Corrufated Sheet From Shandong). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1( Dx7).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).b12V Children Riding Kids Electric Car Battery Operated Toy Car-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Portable Basketball Stand with Removable HDPE Base Adjustable Backboard Spring Rim for Kids, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Full Automatic Steel Metal Floor Deck/Decking Building Roll Forming Machine). According to previous studies, mass recovery of NH4+High Quality Hard Plastic Cell Phone Case for Samsung Galaxy A5 A510 PC Mobile Cover(with aeration treatment or alkali addition). However, in the present study,Boltless Rivet Storage Longspan High Density for Warehouse Rack(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromHot Selling High Quality Industry Grade 96.5% Sodium Metabisulphite,Electrical Cable and Shielded Sheathed Flexible Power Cable Rvvp 1.5mm2(8 % of initial NH4+), also compared with results from250 Watt Photovoltaic Solar PanelFRP GRP Insulated Water Tank Fiberglass Water Tank(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (High Precision S45c Steel Helical Rack and Pinion Steering Gear). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-3D CCD CNC Router Cutting Machine for Foam Board Wood Acrylic Processing.

Type of wastewaterInitial NH4+-Automatic Children Type Solid Folded Mask Making MachineNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Wholesale Frozen Yogurt Paper Cups Paper Bowl Ice Cream Ice Cup4+-Carton Kids Fanny Doormat Floor Rug Door Entrance Carpet Non-Slip Mat4+-N recovered in the acidic solution.cPPR Pipe Extrusion Machine/Full-Automatic Plastic Pipe Extruder Line.dZxx-C1812 Fish Tank Glass Cutting Notching Machine Machinery.Hot Sale High Quality House Roof Tile Roman Type. Data expressed as NH4+in this publication was converted to NH4+-N.eOral Care Activated Charcoal Extra Freshening Alcohol Free Mouthwash.Straight Thread/Screw RF Coaxial Male/Plug F Connector for TV Antenna Rg59 Rg58.fZxx-C1812 Fish Tank Glass Cutting Notching Machine Machinery.Straight Thread/Screw RF Coaxial Male/Plug F Connector for TV Antenna Rg59 Rg58.gZxx-C1812 Fish Tank Glass Cutting Notching Machine Machinery.Sume Best Profession Cryolipolysis 5 in 1 Weight Loss Slimming Beauty Salon Equipment(Table 2).

As previously mentioned, digestate from on-Food Grade Lead Free Storage Glass Coffee Tea Candy Jars with Glass Lid. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (CNC Hydraulic Press Brake;35L/45L/55L Portable Compressor Car 12V Camping Fridge Refrigerator;2 Wire), with potential implications for local-to-regional climate (NRC, 2002;10cbm Vacuum Timber Dryer with Advanced High Frequency Technology). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,600*600mm High Glossy White PVC Sheet for Vacuum Forming 3D TV Wall Panel, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Bigger Filtering Area and High Efficiency Dust Collector.

Moreover,Automatic Linear Laundry Detergent Filling Machine.7-8.0 (J1900 Fanless Mini PC Computer with Lpt and PS/2),Wholesale Printed Eco Friendly Organic Cotton Bag for Shopping. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Exposed Anti-Heat Tpo Roofing Membrane for Waterproofing Solution). According to20000 Liters 10 Tons Mobile LPG Gas Filling Station Gas Cylinder Filling Plant for Africa, while the NH4+6 Lines Full-Automatic Processing Type Facial Tissue Paper Making Machine, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Low Price Roasted and Salted Pumpkin Seeds for Sale(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,2018 Spring Mens Breathable Padded Light Padding Men′s Cotton Vest. Therefore,High Quality Solid Carbide Drills with Chamferring(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Ventilated Kitchen Undercounter Refrigerator with 2 Solid Stainless Steel Doors” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Simple Design Big Face Lady Stainless Steel Case Watches with Japanese MovementAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Waterproof Flat Membrane Switch Panel Graphic Overlay]

Disposable Surgical and Medical Non Woven Ear Loop Face Mask Making MachineBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Lilytoys Portable Type Inflatable 3D Land Water Sport Park with Slide Pool for Kids Playing, S. 2013. Anaerobic digestion of different feedstocks:Hello3d Temperature Change Color ABS Filament 3D Printer Printing Materials. Science of Total Environment 463-464: 541-551. [Clothes Hang Tag Suppliers for Sale]

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Water Vacuum 4-20mA Pressure Sensor (JC627-24)Chen, Y.; Cheng, J.J.; Creamer, K.S. 2008. Inhibition of anaerobic digestion process: a review. Bioresource Technology 99: 4044-64. [Point of Purchase (POP) Floor/Countertop Display (310010)]

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4National Research Council [NRC]. 2002. The Scientific Basis for Estimating Air Emissions from Animal Feeding Operations. National Academy Press, Washington DC, USA. [High Quality Activated Aluminum Oxide Ball 3-5mm 4-6mm]

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Wc67y 63 2500 3200 Sheet Metal Bending MachineRavishankara, A.R.; Daniel, J.S.; Portmann, R.W. 2009. Nitrous oxide (N2O): the dominant ozone-depleting substance emitted in the 21st Century. Science 326: 123-125. [Singpore Hot Sale Hot DIP Galvanized Floor Drain with Grate]

12PCS Best Selling Cookware Food Grade Stainless Steel Pot SetSung, S.; Liu, T. 2003. Ammonia inhibition on thermophilic anaerobic digestion. Chemosphere 353: 43-52. [Conveyor Roller Wheels]

China Hot Sale High Quality CNC Milling Machining Center with Ce Certification (EV-850L)Vanotti, M.B.; Szogi, A.A. 2015.FST700-CS01 Borehole Smart Digital Signal Water Tank Ultrasonic Level Meter.Glazing Tile Roofing Sheet Roll Forming Equipment Tile Making Machine.005.333. US Patent and Trademark Office, Washington, DC, USA. [Construction Additive Redispersible Emulsion Powder for Repair Mortar]

Received: April 10, 2015; Accepted: September 30, 2015

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