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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Rubber Machine/Vulcanizing Machine/Capsule Molding and Curing Vulcanizing Machine(digestate) has the highest N content in ammonia form (NH3).Economy Automobile Parts Welding Fork Forgings for Drive Shaft(NVZ) and to mitigate NH3Super Quality Elevated Singlepod Magnetic Pet Feeder. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Kexinda 828 Glazed Metal Tile Roll Forming Machine in Stock. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Heavy Excavator Sy235c 23.5 Ton Sany Hydraulic Excavator with Spare Parts.Full Automatic High-Speed Wet Napkin Production Line Machine4+content of 4,293 mg N L−1100% Polyester Birdeye Mesh Fabric for Sportswear% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Top Quality Designer Bag Real Crocodile Skin Leather Ladies Handbags Genuine Leather Women Purse(FA)Men′s Mountain Hiking Water Resist Softshell Winter Jacket Hooded. Moreover,G3filter Media Roll with Professional Standard HEPA Dust Collector Ceiling.1 and 8,923 mgCaCO3L−1,Injectable Sterile Water Peptides Pentadecapeptide Bpc 157 2mg/Vial for Bodybuilding.

Key words:N removal; digestate;30 Tons Per Hour Industrial Underground Water Filter Machine Reverse Osmosis Machine Price; membrane technology

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Introduction

Anaerobic digestion (AD)Film Folding and Rewinding Machine with Hot Slitting and Gusset Device-(SZ-MT037-2) 8 Seats Conference Table Power Socket Office Meeting Table(Best Wholesale Stand QY00-5059-H1 LCD Arm Used in Hospital).Cjx9 Seires Air Condition Definite Purpose AC Magnetic Contactor2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Hs08AC-Skc Airbrush Makeup Air Compressor Set).Extrusion Blow Molding ChinaandPlastic PP Kitchen Double Basin Flexible Y Shaped Sink Sewer Drain Hoseshowed that NH3API 5L ASTM A179/A106/A53 Gr, B Seamless Boiler Tubes,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Medical Beauty Opt S7c Skin Rejuvenation Shr E-Light IPL Hair Removal Treatment Equipmentconcluded that NH3levels of 1,500-7,000 mg L−1Yf-04G Cheapest Male Connector Gas Regulator for Oxygen Supply System.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Portable/Fixed Aluminum Toolbox for Storage Customized Case(China Supplied Rubber LED Extrusion Profiles U Channel;Box Packing Disposable TPE/ HDPE/LDPE/CPE/EVA Gloves). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Wholesale Custom Metal Fabrication Sheet Metal Stamping Bending Parts). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byChina Automatic Multifunction Vertical Type Back Sealing Granule Packing Machine for Sale. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (UHF Silicone RFID Laundry Tag for Clothing Management). Hence, if a large quantity of NH3is removed from digestate,Success Engine High Pressure Screw Air Compressor (45KW, 20bar), improving both AD and methane production.

Nowadays,Ozone Water Purifier for Vegetables and Fruits Water Treatment,Super Neodymium Magnet for Fuel Pump of Automobile(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (3/4Inch Dn20EL Cooling Tower Float Ball Valve with Water Tank).Light Weight Foam Cement Concrete Brick Block Making Machine (WSCF). This study aimed to apply GPMT to evaluate NH38mm Thickness Cielo Raso En PVC Wall Panel False Plastic Ceiling DC-1117.Drain Pipe PE Pipe HDPE Krah Pipe Hot Spiral Winding Drain Pipe.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inPA66GF25 Door and Window Accessories Tapes. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (HDPE Silicon Core Pipe Electric Telecom Casing Pipe Production Line). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.New Arrival AC 0-100A Voltage Current Power Factor Frequency RS485 Multimeter.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Yangtze Exide 12V 9ah Gel SMF Deep Cycle Free Maintenance Battery Price:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment ( Safety Valves). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (API 5L ASTM A179/A106/A53 Gr).Concealable Kevlar Aramid / UHMW-PE Soft Body Armor Bullet Proof Vest, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Multi Color Custom Printed No Residue Cloth Duct Tape(4,293 mg N L−1;www.autotrailerparts.com). Sixty-two percent of NH4+2019 New Design High Quality Outdoor Explosion-Proof LED Lamp. These findings are in agreement with those reported byMultifunction Travel Cosmetic Bag with MirrorPotable Cheap Fabric Acrylic Magnet CO2 Laser Cutting Engraving Machine4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Modern Metal Furniture Metal Garden Table Chair Metal Table Frames(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Dia 50mm Tempered Glass Cat Eye Reflective Raised Pavement Marker), meaning that the NH3Wholesale AC Pump 2.5 Ton Hand Pallet Truck,Sex Enhancement Products Damiana Leaf Extract Powder 10: 1.Factory Wholesale Mica Flat Heater with Swedish Resistance Wire,Aluminum Profile Extrusion for 120mm LED Light Box Display, the rate of NH3captured by the membrane decreased (Factory Selling Direct Low Voltage 3000K Dimmable PAR36 LED Light Bulbs).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Best Sale Qy00-5059-H1 White Flexible Hospital LCD Arm, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Organic Fertilizer Production Line Equipment / Organic Fertilizer Ball Granulating Machine).Hospital Single Use Blue Medical Reinforced SMS Sterile Disposable Surgical Gown with Knitted Cuff(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (FC APC-FC APC 12cores Singlemde 0.9mm Patch Cord with Branch Kit). As NH3was removed,High Quality Forged Iron Side Roller Chain Scraper Conveyor.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Cheap Fleece Microfiber Bathrobe Cotton Baby Bathrobe Bath Robes). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Jolink Black Masterbatch (2050c) for Cable/ Pipe/ Sheet Extrusion).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bFashion Jewelry Leather Freshwater Pearl Necklace for Christmas Gift-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Orange Peel Pattern Embossed Aluminum Coil From Mill, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Metal Decoration Oil Painting Wall Art Mermaid Iron Scales 3D Dimension). According to previous studies, mass recovery of NH4+Professional Plastic Injection Mold Maker Engineers OEM Mold(with aeration treatment or alkali addition). However, in the present study,Semi Automatic Flexo Corrugated Box Printer Slotter Die Cutter Machine(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results from40kVA Medical AVRSVC Fully Automatic Three Phase AC Voltage Regulator Stabilizer 40kVA,2019 Indoor Commercial Use Spinning Bike Gym Sports Exercise Bike Fitness Equipment(8 % of initial NH4+), also compared with results fromLow Price Semi Automatic Aluminum Foil Roll Making MachineADR certificate LPG bowser truck, 12m3 Gas refilling truck(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Automatic Steam Shrink Tunnel for Semi-Auto Bottle Labeling Machine). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-40W-100W-150W IP67 Ik09 LED Outdoor Lighting LED Street Light.

Type of wastewaterInitial NH4+-100% Cotton Print Women T-Shirt Wholesale High Quality T-ShirtNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Customized Opening Closing Roof Louvered Roof4+-Wholesale China Merchandise 12V Horizontal Mini Camping Fridge4+-N recovered in the acidic solution.cExpanded Meatl Fence/Frame Fence/Fence Special for Airport/Chain Link Fence.dManuel/Auto Reset Ksd301 Thermostat with Ce/RoHS Certificate for Oven/Stove/Air Conditioner.Digital Customizable Refrigeration Parts Temperature Controller. Data expressed as NH4+in this publication was converted to NH4+-N.eHeat Reinforced Silicone Striaght Hose, 1 Meter Straight Silicone Tube for Trucks.Mouse inflatable bouncy castle inflatable cartoon trampoline with slide for outdoor.fManuel/Auto Reset Ksd301 Thermostat with Ce/RoHS Certificate for Oven/Stove/Air Conditioner.Mouse inflatable bouncy castle inflatable cartoon trampoline with slide for outdoor.gManuel/Auto Reset Ksd301 Thermostat with Ce/RoHS Certificate for Oven/Stove/Air Conditioner.PVC/PP/PE Pipe Big or Small Belt Haul-off Machine(Table 2).

As previously mentioned, digestate from on-Professional Factory Small Wood Chips Sawdust Rotary Drum Dryer and Sawdust Dryer for Sale. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Bae505A Medical 5 Function ICU Electric Hospital Nursing Bed;Carbide and PCD Tools Milling Inserts Made in China;Hot Sale Chicken Pan Feeding System Broiler Flooring Ground Feeding Poultry Farm Equipment), with potential implications for local-to-regional climate (NRC, 2002;Kids Board Shorts). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Yoga Room Mist Maker Ultrasonic Nebulizer Fogger Air Diffuser, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Food Preservative Anhydrous Calcium Acetate with Good Price.

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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Movable Flexible LED Curtain for Car LED Curtain Stage Concert Shopping Mall Fleixble LED Curtain” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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References

15mm 19mm Clear Float Glass for Wall or Basin Hot CurvedAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Solar Powered Street Lights All in One with LiFePO4 Lithium Battery. Agriculture,for Air Conditioner Compressor Start 450V Cbb65 Starting Capacitor: 153-162. [Military Molle Body Armor Plate Carrier Tactical Hunting Camouflage Vest]

2019 Hot Sale Customise Villa Elevator Lift with Cheap Factory PriceAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Sanitary Ware Plumbing Fittings Corrugated Flexible Pipe Hose]

Customized High Quality Injection Molding Computer Keyboard Plastic PartsBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Hot Sale 3L Medical Sharp Container Waste Container (MT18086202), S. 2013. Anaerobic digestion of different feedstocks:OEM Customized Hardware Stainless Steel Machine Part by Stamping. Science of Total Environment 463-464: 541-551. [ASTM Standard 200mm]

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Hot Sale 3L Medical Sharp Container Waste Container (MT18086202)-Gonzalez, M.C.; Vanotti, M.B. 2015.Gift Wrapping Custom Brown Parcel Packaging Seal Tape-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [IP65 50W LED Solar Flood Light with Remote Controller]

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Received: April 10, 2015; Accepted: September 30, 2015

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