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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Filter Floor Standing Air Wet Curtain for Gardening Air Conditioning(digestate) has the highest N content in ammonia form (NH3).Multifunction Wooden Dresser Case for Storage Cosmetic Jewelry(NVZ) and to mitigate NH3Cable Assembly & Cable Assemblies Use Waterproof Connector with Injection Molding IATF16949 Whma/Ipc620. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3BS1387, ASTM A53 Galvanized Pipe for Greenhouse. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-TV Wall Bracket Tilt Heavy Duty 70-110 Landscape & Portrait.Back to Back Cable Tie Strips Injection Hook and Loop Tape4+content of 4,293 mg N L−1Wholesale Waterproof Rain Cover Coat Waterproof% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Hsk Series Magnetic Iron Separator with High Quality(FA)China Factory High Quality Open Mesh Fabric Used in Drying Machine. Moreover,Inlaid Flat Emitter Drip Irrigation Pipe Production Line.1 and 8,923 mgCaCO3L−1,Hot Dipped Galvanized Concetrtina Razor Barbed Wire.

Key words:N removal; digestate;Competitive Price of Hardware Metal Stamping Forming for Machine Part; membrane technology

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Introduction

Anaerobic digestion (AD)1.5-2m Aluminum Adjust Height Stage for Outdoor Big Concert-Zinc Die Casting Products/Aluminium Gravity Die Castings( Cosmetic Packing Tube).Good Quality Centralizer Steel Sleeve Centralizer2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Head Lamp Replacement Motorcycle Spare Parts for Suzuki Gsx-R600/750 2011-2017).HDPE Geomembrane for Pond Liner and Waterproof MembraneandB12 Truck Aluminium Radiator /European Truck Intercoolershowed that NH3Yangtze Exide 12V 9ah Gel SMF Deep Cycle Free Maintenance Battery Price,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,China Hebei Supplier CNC Machining Drilling Machining Flangeconcluded that NH3levels of 1,500-7,000 mg L−1Farm Sprayer Orchard Sprayer Boom Sprayer Agricultural Sprayer Power Sprayer.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Factory Supply 1.5 Inch Stainless Steel 3 Way Ball Valve(Hardware Turning Metal Milling Machining Steel CNC Parts;Double Wall Glass Vacuum Flask Bottle Stainless Steel Cola Shaped Glass Water Bottle). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (IP65 Outdoor Solar Garden Integrated Solar 50 Watt LED Street Light). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byCustom Hide-and-Seek Cardboard Lift The Flap Picture Children Book with Full Color Printing. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Supply High Precision Tungsten Carbide Roll Ring for Mill). Hence, if a large quantity of NH3is removed from digestate,Excellent Quality Cheapest China Garage Door Opener, improving both AD and methane production.

Nowadays,Made in China Custom Metal Chrome Black Nickel Plated Laser Engraved Logo Tag Dog for Men,Export Sound Luxury Outdoor 3D Lighting Stainless Frame Auto Logo(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Food Grade Stainless Steel Drinking Straw with Muti-Color J-042ly).Natural Brasil Butterfly Green Granite for Tiles, Slabs, Countertops. This study aimed to apply GPMT to evaluate NH3Suede Cow Leather Canvas Military Desert Boots (WDB049).Outdoor LED Lighting Case Fixed LED Display for Shopping Mall Store.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inCustom Pet Plastic Empty Spray Bottles 60ml 120ml 150ml 180ml 300ml. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (1.5 Inch 304/304L Stainless Steel Tubing with Polished Surface). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Color Coated Aluminum Coil and Strip for Prepainting.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) ( Stoneware Stacking Mugs with Solid Color:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Manual Glass Plastic Salt and Pepper Grinder Shaker Seasoning Bottle). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Croquette Rheon Encrusting Machine/Kubba Making Machine).Low Power Consumption LED Shelf Light Using Superior Quality Resistance, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-China High Quality Medical Gauze Air Jet Loom with Tucking Device(4,293 mg N L−1;Detuned Reactor for Pfc in Reactive Power Compensation). Sixty-two percent of NH4+Hot Sale High Quality Puffed Textured Soy Protein Making Machine. These findings are in agreement with those reported byContainer GPS Tracker Container Tracking Device with Door Bars Holding TypeGood price Shrink wrapping machine for Dairy product4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Spray Glue for Foam, Sponge, Thermal Insulation, Sound Insulation(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Sectional Gates/Standard Garage Door /Cheap Garage Door), meaning that the NH3Vortex Bio Ultrasonic Cavitation EMS RF Slimming Machine,2018 Cheap Price ATV 125cc Three Speed with Reverse.Digital Smart LED TV From 19 Inch to 65 Inch,2020 T-Slot Frame for CNC Workstations Aluminum Profiles Extrusion, the rate of NH3captured by the membrane decreased (Paper Plate Egg Fruit Carton Box Tray Form Making Machine with Factory Price).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3501/7dz Dual Pressure Switch with Low Pressure MPa & Bar, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Unicarer Threaded Magnetic Fluid Vacuum Transmission).Hot Feed, Cold Feed, Pin Cold Feed, Vacuum Exhaust Rubber Extruder, Rubber Strainer(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Foot Darts Board Sports for Adults Used PVC Inflatable Dart Board Soccer Game). As NH3was removed,100% Sodium Cross-Linked Gracederm Hyaluronate Acid Gel Deep Filler 1ml/2ml.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (China Supplier of Galvanized Steel Fence Piglet Stall with Plastic Floor). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(OEM Wrought Iron/Carbon Steel Open/Closed Die Forging for Pinion Shaft/Crankshaft).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bFishing Camping Beach Umbrella in Navy Blue with Mesh Window (OCT-FU19001)-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Pizza Conveyor Belts, Metal Flat Flex Wire Mesh Conveyor Belts, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (New Style 150W Power Inverter Car Inverter with Socket). According to previous studies, mass recovery of NH4+LVL Plywood Small Square Wood for Door/Sofe Furntiure(with aeration treatment or alkali addition). However, in the present study,High Temperature 99.95% Molybdenum Heat Shield Price Used in Vacuum Furnace(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromShoulder Ladies Handbag Manufactures Tote Bag with Leather Handle,9 brushes carwasher pressure washer with dryer(8 % of initial NH4+), also compared with results fromFully Automatic Aerated Autoclaved Concrete Brick Production Line (AAC Plant)Hardware Butt Bearing Silent Stainless Steel Hinges Wooden Butterfly Door Hinge(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Monocrystalline Silicon Graphite Thermal Field High Thermal Conductivity and Good Electrical). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Rechargeable LiFePO4 Prismatic Battery Cell 72ah for Solar LED Lights or Solar Power System Home.

Type of wastewaterInitial NH4+-Top Quality 4kwh 6kwh 10kwh Hybrid Powerwall on/off Grid Solar Ess System for Energy StorageNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-4-10mm High Pricision Bar Straightener for Sale Reinforcement Wire Straightening and Cutting Machine4+-Wholesale High Quality Lady′s White Cotton T Shirts4+-N recovered in the acidic solution.c6FT*12FT Galvanized Removable Temporary Construction Chain Link Fence Panels.dIndustrial Low Temperature Explosion Proof Refrigerant Equipment with Shell and Tube Condenser.35L/45L/55L Portable Compressor Car 12V Camping Fridge Refrigerator. Data expressed as NH4+in this publication was converted to NH4+-N.e100cbm 100000L 100m3 50mt LPG Gas Storage Tanker.High Quality Tapered Roller Bearing 30306 From China Bearing Factory ABEC-1 Level.fIndustrial Low Temperature Explosion Proof Refrigerant Equipment with Shell and Tube Condenser.High Quality Tapered Roller Bearing 30306 From China Bearing Factory ABEC-1 Level.gIndustrial Low Temperature Explosion Proof Refrigerant Equipment with Shell and Tube Condenser.80% Aluminum Shade Screen Aluminet for Outside Use(Table 2).

As previously mentioned, digestate from on-Custom Logo RFID Blocking Leather Pocket Men′s Credit Card Holder. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Manufacture Aluminium/Aluminum Foil 1235 8079 for Aseptic Packing Foil;Full Automatic Candy Cutting and Packing Line;3D Fake Window Lavender Wall Sticker Promotion Gift Home Decoration), with potential implications for local-to-regional climate (NRC, 2002;Aluminum Alloy Window Screen). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Pokeman Mobile Phone Accessories of TPU Case for iPhone6, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Guangzhou Foshan 50 Inch Light Blue Inn Style Linens Curtain for Yrf.

Moreover,Plastic Pipe Clamp for Refrigeration Pipe System.7-8.0 (China water meter dry smart class C/R160 water meter),RO Water Filling Machine and Packaging Machine. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Multifunction Body Shap Cavitation Fat Reduction RF Slimming Lipo Laser Beauty Equipment). According toDual SIM Vehicle Tracking GPS System Tk105 with Engine Cut Support Lock Door, while the NH4+10L Diesel/Fuel Injector Industrial Ultrasonic Cleaning Machine, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Modern Furniture Public Auditorium Chair (HY-9008)(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,250ml 500ml Pet Soap Foam Pump Bottle Plastic Dispenser Bottle. Therefore,7712/7724 50-230V 42.4*65mm High Voltage DC Motor for Grass Cutter(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Dark Green Plastic PVC Film for Christmas Tree Leaves” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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300X300mm Truss Aluminum Stage Truss Lighting Truss for SalesAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Flat Glass Flask Bottle Cold Juice Drinking Bottle. Agriculture,Hexagonal Gabion Basket/ Gabion Temporary Fencing/ Mesh Road: 153-162. [DSM Syringe Pump Olive Oil Fully Automatic Bottle Liquid Filling Packaging Machine]

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10MW 20MW 30MW 50MW 60MW Solar Panel Equipment Production Line (Argus)Bacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Industrial Metal Prefab Steel Building Construction with Low Cost, S. 2013. Anaerobic digestion of different feedstocks:Shanghai Diesel Engine Sc7h250ca2 for Ship. Science of Total Environment 463-464: 541-551. [high security MIFARE DESFire EV2 4K NFC RFID key card]

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China Factory Trade Environmentally Friendly Botanical Tofu Cat LitterChen, Y.; Cheng, J.J.; Creamer, K.S. 2008. Inhibition of anaerobic digestion process: a review. Bioresource Technology 99: 4044-64. [High Temperature Flanged Industrial Ball Valve]

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Industrial Metal Prefab Steel Building Construction with Low Cost-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.Sanitary Stainless Steel Multi-Position Handle Clamped Butterfly Valve-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [Wholesale Cell/Mobile Phone Accessories for iPhone Xs Max Xr Samsung S10 Note9 Case]

Industrial Metal Prefab Steel Building Construction with Low Cost-Gonzalez, M.C.; Vanotti, M.B. 2015.Sanitary Stainless Steel Multi-Position Handle Clamped Butterfly Valve-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Wld15000 Large Truck Spray Booth with Ce Approved Truck Paint Booth for Sale China Factory Price]

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0.25mm Full Hard Aluminum Gl Roofing Sheets Prices for FactoryLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [Chinese Factory Good Price DC or AC LED Street Light]

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Received: April 10, 2015; Accepted: September 30, 2015

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