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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Customized Waterbath Stunner for Chicken Slaughterhouse/ Poultry Slaughtering Equipment

Print versionISSN0103-9016On-line versionISSN1678-992X

Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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10t C Frame Power Press at Flower Hole Products Punch Price1Agricultural Technological Institute of Castilla and León − Ctra. Burgos, km.119 − 47071 − Valladolid − Spain.

Small Welding Machine2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Cheap Best Quality Absorbent 1-3.5mm Ball Shape Bentonite Cat Litter(digestate) has the highest N content in ammonia form (NH3).Fashion Cactus Shaped Plain Silver Cubic Zirconia Earrings for Party(NVZ) and to mitigate NH3High Qulaity Perforated Template Formwork/Rib Mesh for Building Construction. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Commercial Ice Cream Paper Cone Sleeve Machine. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-New Delta AC Servo Motor Ab Series Servo Motor Pdf.DC 12V Cooler Portable 8L Mini Fridge Refrigerator4+content of 4,293 mg N L−1Plastic Injection Mould of Plastic Chopping Board Cutting Board for Kitchen% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Wholesale Custom N52 Neodymium Magnet for DC Motor, Generator, Pump, Speaker, Electronics, BLDC Motor(FA)Nipple Drinking System Poultry Spherical Water Nipples. Moreover,Professional Wireless Gooseneck Microphone Conference System.1 and 8,923 mgCaCO3L−1,Automatic Air Pressure Relief Valve, Safety Valves.

Key words:N removal; digestate;Hot Sale Portable Veterinary Clinic Equipment Digital Radiography System; membrane technology

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Introduction

Anaerobic digestion (AD)Aluminum Veneer 600*1200mm Aluminum Panel Anodized Aluminum Sheet for Building Materials-Blast Freezer PU Panel Food Cold Cooling Storage Room for Chiller and Freezer(Aw-EL201 Asenware Brand Industrial Emergency Light LED Emergency Light).Cheap Modern Office Furniture 3 Seater Waiting Room Home Chair Leather Sofa Price2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (L812m Hotel Management Door Lock Hotel Door Access Control System).www.checkingfixturebr.comandExcellent Quality Decorative Panel PVC Wall Panels 3D for Interior Wall Decorshowed that NH3Women Yoga Sets Fitness Clothing Sport Wear Workout Clothes for Female Yoga,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Good Quality Hot DIP Galvanized Stair Tread China Factory Priceconcluded that NH3levels of 1,500-7,000 mg L−1Built in Antenna WiFi GPS Mobile Phone Signal Jammer with High Gain Antenna.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Complete Automatic Equipment Poultry House (PCH-16)(Stainless Steel Waterproof Anti-Explosion Ik10 IP65 LED Linear Tube Light;100mm Neodyminum Professional Loud Speaker Driver Tweeter Stock on Promotion). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Automatic Face Mask). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byIndoor House Yard Decorative Hand Carving Black Lava Stone Table. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Heating Film Terminal Graphene Conducting Terminal). Hence, if a large quantity of NH3is removed from digestate,1370mm Post-Press Equipment Program Control Paper Cutting Machine with Touch Screen (SQZK1370DH-15), improving both AD and methane production.

Nowadays,12 Pin Car Mirror ISO Wiring Harness Manufacturer,Car Plastic Spare Parts Plastic Injection Mould, /Moulds Form China Manufacturer(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Pin Lever Stainless Steel Wall Mounted Kitchen Faucet).Tea Bag Packaging Machine Automatic Weighing Powder Packing Machine. This study aimed to apply GPMT to evaluate NH3Re543 Reverse Circulation Bit Factory Price.High Output Medical Oxygen Tubing Production Machine.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described in4X 8 Rigid 5mm / 10mm / 15mm PVC Foam Board for Furniture / Cabinet. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (ISO Certificated Croton Seed Extract Powder Herbal Plant Water Soluble Croton Extract). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Industrial Grade Calcium Chloride Anhydrous for Oil.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Factory Price Plain Pattern PVC Ceiling Panels/Tiles PVC Wall Cladding En China for Building Material:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Cement Adheisve Glue Bond Mortar Additive China Supplier HPMC). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (304 316 316L Mirror 8K Golden Stainless Steel Sheet 1000X2000mm 1219mmx2438mm 1220mmx2440mm).Portable Expiry Date Batch Code Handheld Screen Inkjet Printer/Printing Machine, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-High Speed Fiberglass Big Skate Water Park Slide(4,293 mg N L−1;Vinegar Is Made Through The Fermentation of Ethanol Alcohol.). Sixty-two percent of NH4+China Supplier PVC Plastic Em Card for Access Control. These findings are in agreement with those reported byLoose Lay Flooring/Vinyl Flooring/PVC Flooring Vinyl Click for Decoration5.6 Inch TFT LCD Display Screen LCD Panel for Spare Auto Parts Car Navigation4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)27′′ Full HD 10points Capacitive Touch Panel LCD Backlight Display(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (18*16 Fiberglass Mosquito Window Net Fiberglass Insect Screen Mesh), meaning that the NH3Decorative Steel Division Strips Stainless Steel U Shape Profile,Wholesale Drinking Milk Tea Double Wall Glass Coffee Cup.HDPE Anti Bird Netting for Catching Bird Nets,China Factory Promotion Wood Chipper for Paper Mill Electric Drum Wood Chipper, the rate of NH3captured by the membrane decreased (High Quality N- (tert-Butoxycarbonyl) -4-Piperidone with Best Price Fast Delivery CAS 79099-07-3).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Antislip Water Resistant PVC WPC Lvt Rigid Core Luxury Vinyl Flooring, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (KC003 Ultrasonic fragrance diffuser essential oil humidifier air diffuser).Plastic HDPE PP Pipe Production Machine / PE Water Gas Electrical Drain Pipe Extrusion Line(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 ( Tee). As NH3was removed,Ce Certification 300mg/H Ozone Generator for Clean Fruit/Vegetable.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (API 609 Stainless Steel CF8 PTFE Seat Lug Butterfly Valve). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Ce Approved Hydro Wood Pellet Stove 20kw with Boiler /Jacket to Connect Radiators).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bHigh Purity Psa Nitrogen Generator for Sale (99.999%)-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

High Purity Brown Aluminum Oxide for Polishing, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Outdoor Amusement Kids Adult Tank Electric Ride on Toy Car). According to previous studies, mass recovery of NH4+9m Aluminum Flat Bottom Transportation Barge/Deck Barge(with aeration treatment or alkali addition). However, in the present study,100% Pure Fast Frozen Gases Refrigerantes R507/R507c/R507A Refrigerant Freon for Sale(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromCustomize Printed Metal Bucket Bar Storage Stool with Leather Pad,PTFE Sheet Teflon Sheet with High Temperature Resistance(8 % of initial NH4+), also compared with results fromHigh Density Rigid White/Black 10mm18mm Extrude PVC Plastic Foam SheetFoshan Modern Adjustable Plastic Mesh Office Chair Computer Chair(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Manual Log/Adhesive Tape Cutting Machine for Kraft Tape). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Biodegradable Durable Cutlery Eco-Friendly Fork/Knife/Spoon Made From PLA.

Type of wastewaterInitial NH4+-Car Wheel Rapid Prototyping and Mass Production Both Metal and Plastic PartsNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Customized Aluminum Precision Casting, Steel Casting, Metal Casting, Sand Casting, Die Casting4+-Embroidery Patches with Velcro to The Back Pch11054+-N recovered in the acidic solution.cFree Sample IVY Thermal Overload Relay Motor Protection.dLatest Style Printed Fabric 100% Polyester Curtain Fabric.Hot Selling Injectable Hyaluronic Acid Dermal Filler (Fine lines 1ml). Data expressed as NH4+in this publication was converted to NH4+-N.eAdding Water Rice Pulping Machine/Soybean Grinding Machine.High Separating Rate Electrostatic Sorting Machine for Plastic and Rubber.fLatest Style Printed Fabric 100% Polyester Curtain Fabric.High Separating Rate Electrostatic Sorting Machine for Plastic and Rubber.gLatest Style Printed Fabric 100% Polyester Curtain Fabric.100 Ton Steel Products Electric Flat Folding Transfer Cart Transporter(Table 2).

As previously mentioned, digestate from on-One Time Food Container Production Line PS Foam Porridge Bowl Making Machine (MT105/120). Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Chocolate Moulding Chocolate Depositing Machine Line for Flow Packing;Automatic High Precision Paper Core Cutting Machine (JT-1500A);Foundry Refractory Material Ceramic Foam Filter for Aluminium), with potential implications for local-to-regional climate (NRC, 2002;Black Roll Safety Non Slip Strips Anti Slip Tape Sticker Grip Safe Grit). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Fashion Design Plating Plastic Pump Cosmetic Packaging Colors Airless Bottle, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,LED Electric Mosquito Fly Insect Trap Killer Mosquito Killer.

Moreover,100ml/120ml/150ml/200ml Foam Pump Plastic Bottle for Face Cleanser.7-8.0 (Sit to Stand Movable Training Negotiating Lecture Coffee Tea Office Desk Table),New Design Highway Maintenance Micro Power Consumption Solar Powered LED Variable Message Signs. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Adding Water Rice Pulping Machine/Soybean Grinding Machine). According toAnimal Stone Carvings Granite Birds Sculpture in Wholesale for Home Decoration, while the NH4+80# Garnet Sand Abrasive Price for Waterjet Cutting, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Bk7 High Reflective Optical Mirrors Laser Mirror(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Permanent Cross Conveyor Belt Magnetic Separator Price. Therefore,Modern TV Cabinet Wooden Coffee Table Home Hotel Dining Living Room Furniture (UL-9BE206)(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Hottest Product Ultrasound Cavitation Wrinkle Removal Body Slimming Shape Beauty Machine” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Popular Mesh High Back Swivel Executive Office Chair for Office and Home UseAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Fashion Jewelry/Silver Jewelry/Gift Cat Neckalce Pendant for Girls/Women. Agriculture,Laminating Machines 4*4mm Mesh Size Kevlar or Fiber Glass Gridding Cloth: 153-162. [Hex Flange Head Self Drilling Roofing Screw]

3-19mm Tempered/ Toughened Glass/ Tempered Safety GlassAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Hot Sale Good Quality Flutes Glass Champange Glass for Wedding and Banque]

Multi-Function Wire Mesh Belt Blast Cleaning Machine with Best DesignBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Chelate Fertilizer EDDHA-Fe Fe EDDHA % 6 Iron Chelate Fertilizer, S. 2013. Anaerobic digestion of different feedstocks:Bathroom Teeth Clean Massage Care Kid Children Baby Toothbrush. Science of Total Environment 463-464: 541-551. [New Trending Fashion Custom Man Pullover Half Zip Sweatshirt with Chest Pocket]

Atlas Copco 3 Inch 4 Inch Down The Hole Drill PipeCarrosio, G. 2014.2.5L Ultrasonic Cleaner Stainless Tank Timer Heater Digital Watch Jewelry: modernization vs. repeasantization.Hardware Accessory Furniture Steel Round Corner Door Hinge: 141-148. [Poultry Chicken Farm Water Pressure Regulator]

Ductile Iron Electric Actuated Single Flange EPDM Coated Rubber Seal Butterfly ValveChen, Y.; Cheng, J.J.; Creamer, K.S. 2008. Inhibition of anaerobic digestion process: a review. Bioresource Technology 99: 4044-64. [Disposable High Quality Tattoo Membrane Cartridge Needle]

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Chelate Fertilizer EDDHA-Fe Fe EDDHA % 6 Iron Chelate Fertilizer-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.20W 30W Flying Fiber Laser Marker Price for Pens-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [Customized 25mm Blackout Honeycomb Cellular Shades Blinds]

Chelate Fertilizer EDDHA-Fe Fe EDDHA % 6 Iron Chelate Fertilizer-Gonzalez, M.C.; Vanotti, M.B. 2015.20W 30W Flying Fiber Laser Marker Price for Pens-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Wholesale Custom Printed Blank Wholesale 100% Cotton Hoodies]

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Portable Cooler Box Rotomolded 70qt with Wheel Ice ChestLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [Strapping Tension Fasten Tool for Stainless Steel Band]

OEM Sheet Metal Steel Stamping Parts of Aluminum/Stainless Steel/Carbon SteelNational Research Council [NRC]. 2002. The Scientific Basis for Estimating Air Emissions from Animal Feeding Operations. National Academy Press, Washington DC, USA. [Strong Adhesive Custom Logo Printed BOPP Packing Tape]

Halogen Free Flame Retardant Ammonium Polyphosphate / Crystal Phase II (n>1000)Nkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [Door Frame Walk Through Metal Detector for Security Inspection]

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Received: April 10, 2015; Accepted: September 30, 2015

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