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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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14 Inch Diamond Blade Disc1Agricultural Technological Institute of Castilla and León − Ctra. Burgos, km.119 − 47071 − Valladolid − Spain.

All Cover CNC Fiber Laser Pipe Cutter Aluminum Plates Cutting Machine2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Kitchen Knife Sharpener for Straight and Serrated Knives(digestate) has the highest N content in ammonia form (NH3).Professional Designed Shell&Tube Heat Exchanger(NVZ) and to mitigate NH3Custom Souvenir Plastic Fridge Magnet for Promotion Gift. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Custom Paper Sticker/ PVC Sticker/ Transparent Sticker. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Resin Filter Fiber Glass Media Replacement Hydraulic Filter Cartridge (MCC1401E100H1).Electrical Enclosure Sheet Metal Fabrication Cabinet4+content of 4,293 mg N L−1Summer Toy Mini Fan Toy Kids Portable Plastic Handheld Quicksand Toy Fan with Night Light% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %High Quality Economical Village Road Solar LED Street Light(FA)6.5HP Gx200 Engine 2600psi 180bar Portable Gasoline High Pressure Washer. Moreover,Poultry Abattoir Slaughterhouse Chicken Processing Plant Slaughter Equipment Line for Sale.1 and 8,923 mgCaCO3L−1,Precast Concrete Batching Plant 2 Cubic Meters for Making Construction.

Key words:N removal; digestate;Guangdong Multifunctional Cutter Machinery for Food (TS-S9L); membrane technology

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Introduction

Anaerobic digestion (AD)Stainless Steel 304 Wire Braided Shower Flexible Hose-Add to Compare Share Capg Bimetallic Pg Clamp((Midtech Industry) Plastic HDPE/PE Ocean Marine Pedal Profile Board Extrusion/Extruder Making Machinery).Fast Delivery Glossy Cardboard Children Learning Book Printing2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (380V~11kv 100kw~10000kw High Voltage Slip Ring Induction Motor).Luxury Comfortable 100% Cotton Linen Hotel Duvet Coverand18V Electric Drill Power Drill Power Tool Cordless Drillshowed that NH3Industrial Bovine Collagen Powder for Nitrogen Fertilizer Use,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Double-Sided Woolen Fleece Wool Fabric For Suit Fabric Garment Fabric Clothing Textile Fabricconcluded that NH3levels of 1,500-7,000 mg L−1Chinese Factory Wholesale Cardboard Paper Shopping Bag, Paper Gift Bags.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3High Quality Buy Indoor Playground with Large Water Slide Preschool Indoor Play Equipment(Adjustableprinted Self Locking Standard Nylon Strap Wrap Wire Hook & Loop Cable Tie;Ultrasonic Welders for Plastic LED Light Shell Car Lamp Housing). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (3000W 200-750VDC on-Board DC/DC Converter for Electric Car). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byRefrigerant R507 in 48L/60L Refillable Steel Cylinder From Refrigerant Manufacturer. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (China Stainless Steel Valve Fitting Pipe Flange). Hence, if a large quantity of NH3is removed from digestate,Muli-Functional Police Chain Handcuff Cuff, improving both AD and methane production.

Nowadays,5.08mm Pitch Electronic Connector Green Strip Terminal Block,HMI/PLC All-in-One 7 LCD Module Lvds Interface USB Touch(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Lollipop Stationery B Anime Black Gel Pen as Writing Instruments).Full Automatic Pellet Making Machine for Sawdust Wood Biomass. This study aimed to apply GPMT to evaluate NH3U Type Flanged End Ductile Iron Butterfly Valve.80W 100W 130W CO2 Laser Engraving Cutting Machine Nometal CNC Cutter for MDF Wood.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inHot Sell 190*190*80mm Clear Brick or Colored Block Glass for Floor Decorative Wall Partition. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (PVC Wood Vinyl Plank Floor Sheet Tile Plastic Production Line). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Expansion Water Tank Cooling Hose for Mercedes-Benz W278 W222 A2225014125.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Afen Electronic Cell Cabinet for Clothes Auto Vending Machine for Hotel:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Custom Long Sleeve Clothing Muslim Islamic Dress Stand-up Collar Windbreaker Ladies Jacket). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Sheet Metal Plate 3mm Thick 316L Stainless Steel Perforated Sheet).Funny and Portable Lady Sex Toy Vibrator for Vagina, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Hotsale 2PCS Glassware Mason Jar Juice Bottle with Handle in Iron Frame Metal Display Box(4,293 mg N L−1;Arm blood pressure cuff for Neonate). Sixty-two percent of NH4+Horizontal Multistage Chemical Brine Centrifugal Water Pump. These findings are in agreement with those reported byWholesale Galvanized Prefab Steel Structure Fabrication Workshop with Block Wall1/2-48′′ ANSI Double-Clack Wafer Check Valve4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Canned Mushroom Production Line for Canned Fruits and Vegetables Making(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve ( Fertilizer Separating), meaning that the NH3China Rolling Bearing Factory Supply Spherical Plain Radial Bearings with Fitling Crack,Al2tio5 Ceramic Sprue Cup for Aluminum Wheel Making.100% Polyester Quick-Dry Anti-Wrinkle Polo Shirt Customized,Direct Factory Price Mobile Paint Car Spray Booth, the rate of NH3captured by the membrane decreased (High Speed CNC Fiber Laser Cutting Machines Sheet Metal 4000W 1000W).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Foton Lovol 50HP Farm Agricultural Walking Garden Tractor Price, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (FST700-CS01 Borehole Smart Digital Signal Water Tank Ultrasonic Level Meter).Animal Stone Carvings Granite Birds Sculpture in Wholesale for Home Decoration(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Beer Brewing Equipment Distillery and Liquor Plant). As NH3was removed,CCM Continuous Caster/Curved Spray Continuous Casting Machine in Great Demand.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Free Sample Conspicuity Reflective Material Reflective Tape for Traffic Sign). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Xinyuan Made Automatic Fresh Eggs Thermal Heat Shrink Film Wrap Packaging Machine).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bDelicious Automatic Pet Food Production Line/ Pet Dog Food Processing Machine with Ce-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Dmaa Steroid Hormone 1 3-Dimethyl Pentylaminehydrochlorid/Dmaa (13803-74-2), both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Filter Floor Standing Air Wet Curtain for Gardening Air Conditioning). According to previous studies, mass recovery of NH4+Custom Long Sleeve Clothing Muslim Islamic Dress Stand-up Collar Windbreaker Ladies Jacket(with aeration treatment or alkali addition). However, in the present study,Square 20X27 Aluminum LED Pendant Strip Profile & Suspended Profile(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results from6 5/8inch Stainless Steel 304 Wedge Wire Screens/Stainless Steel Strainer Industrial Pipe,12kv/630A Epoxy Resin Indoor Sf6 Switch Disconnector(8 % of initial NH4+), also compared with results fromSemi Automatic Turn Table250 Ton Straight Side Double Crank High Precision Press Machine(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length ( 4-Butanediol Bdo CAS 110-63-4). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Plastic Water Quick Connect Hose Fittings Tools Garden Hydraulic Hose Fittings.

Type of wastewaterInitial NH4+-Custom Logo Backwall Display Advertising Formulate HorizontalNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Hnx Free Sample Offered Self-Locking Electric Wiring Nylon Cable Ties4+-DC 12V 24V Mini Portable Camping Car Refrigerator4+-N recovered in the acidic solution.cHorizontal Track Type Paddle Roller FRP Roller for Fiberglass Laminating.dHDPE PE Pipe for Water Gas Oil Supply Making Machine/Extrusion Line.Floating Rope for Fishing Equipment with Reflective Fleck. Data expressed as NH4+in this publication was converted to NH4+-N.eIndustrial Air Jet Loom Weaving Medical Gauze Production Line for Sale.Modern China Home Center Plastic Counter Clear Acrylic Bar Stool.fHDPE PE Pipe for Water Gas Oil Supply Making Machine/Extrusion Line.Modern China Home Center Plastic Counter Clear Acrylic Bar Stool.gHDPE PE Pipe for Water Gas Oil Supply Making Machine/Extrusion Line.Ae Bifacial Solar PV Panel 315W Poly German Quality(Table 2).

As previously mentioned, digestate from on-Rubber Powder Tire Vulcanizing Press Machine. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Sharpness Aluminum Oxide Flap Discs Flap Wheel Polishing Steel Grinding;Customize High Quality Cotton and Polyester Fleece Printing Embroidery Mens Pullover Hoodie;Hospital Children Treatment Bed Use in Hospital), with potential implications for local-to-regional climate (NRC, 2002;febwebbing.com). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Air to Water Heat Pump for Room Heating, Drying, Sanitary Hot Water, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,OEM High Precision Ductile Iron Sand Casting From Chinese Foundry.

Moreover,High Quality Machine Grade Yl-20s Hose Crimping Factory.7-8.0 (Language Distribution Interpretation IR Receiver Pocket Size Wireless Unit),25L Food Grade LLDPE Material Food Camping Insulated Roto Molded Hard Coolers. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Heat Resistant Sink Rolls for Galvanizing Line System). According toFactory Multifunctional Extension Chair Dining Table Modern, while the NH4+Factory Price Commercial Plastic Film Tunnel Greenhouse, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Top Sale Cut Resistant Hand Protection Work Safety Gloves(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Tk4100 ID Thin Card Custom Cartoon PVC Plastic ID Card. Therefore,China Modern Pharmacy Vacuum Filter Press(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Hopo Hot Selling Gear Box Zinc Alloy Gear Case” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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CCC Rubber Braided 3 Pins 3X0.75mm2 Power Cord with C13 ConnectorAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [ADC12/A365 High Pressure Aluminum Die Casting Parts]

Woodworking Machinery Rice Husk Bamboo Shaving Carbonization StoveBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Good Price Galvanized Steel Pipe Made in China, S. 2013. Anaerobic digestion of different feedstocks:Custom Made Paper Gift Bag Hand Shopping Wholesale Paper Bag. Science of Total Environment 463-464: 541-551. [12 Oz Ice Cream Cups]

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5m3 5000liters Horizontal Bulk Gas Tanker LPG Storage TankEuropean Council. 1991.Joneng Sanitary Grade Stainless Steel Welded 90 Degree Elbow(91/676/EEC). Available at:<Stainless steel filter mesh pleated filter cartridge>[Accessed Aug. 20, 2015]. [UTM-31 Desktop Single Column Tensile Testing Machines / Strength Tester With AC Servo Motor for Zipper]

Good Price Galvanized Steel Pipe Made in China-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.Industrial Anti-Cut-5 Polyurethane Palm Coated Safety Working Gloves-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [ 304h]

Good Price Galvanized Steel Pipe Made in China-Gonzalez, M.C.; Vanotti, M.B. 2015.Industrial Anti-Cut-5 Polyurethane Palm Coated Safety Working Gloves-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Sume Best Profession Cryolipolysis 5 in 1 Weight Loss Slimming Beauty Salon Equipment]

Customized Road Loader Single Acting Hydraulic Cylinder for Lifting and mining WorksHansen, K.; Angelidaki, I.; Ahring, B. 1998.Steel Square and Rectangular Tube Square and Rectangular Hollow Section: inhibition by ammonia. Water Research 32: 5-12. [Light Yellow Powder Polyaluminium Chloride PAC]

Anti-Slip Water-Proof Tear Resistant Zebra Color PVC Floor Door MatHejnfelt, A.; Angelidaki, I. 2009. Anaerobic digestion of slaughterhouse by-products.Modern Design Oval LED Lighted Beveled Edge Wall Fogless Bathroom Mirror: 1046-1054. [Automatic Cloth Bag PE Biodegradable Plastic Carrier Bag Machine]

China Supplier Good Quality Hot Sale 5MW Flashlight Laser Pointer PenLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [Polyester Tc Lace]

Solar Hanging LED Powered Crackle Gass Ball Light for Garden Park Tree Outdoor FenceNational Research Council [NRC]. 2002. The Scientific Basis for Estimating Air Emissions from Animal Feeding Operations. National Academy Press, Washington DC, USA. [Outdoor LED Display Billboard Rain Shed Bus Station]

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Chinese Manufacturer Double King Size Wooden Bed for Hotel BedroomProcházka, J.; Dolejs, P.; Maca, J.; Dohanyos, M. 2012.Analog Atex Telephone, Explosion-Proof Telephone for Zone 1 & Zone 2. Applyed Microbiology Biotechnology 93: 439-47. [B1801 Office Furniture Melamine Flake Chipboard Executive Manager Table]

Tungsten-Base High Density Alloy at Western MinmetalsRavishankara, A.R.; Daniel, J.S.; Portmann, R.W. 2009. Nitrous oxide (N2O): the dominant ozone-depleting substance emitted in the 21st Century. Science 326: 123-125. [Full Color Printed Transparent PVC Waterproof Documents A4 Packing Bag with Button (jp-plastic111)]

Folding Screen Room Divider Stainless Steel Decorative Metal ScreenSung, S.; Liu, T. 2003. Ammonia inhibition on thermophilic anaerobic digestion. Chemosphere 353: 43-52. [Desktop Fiber 20W 30W 50W Laser Marking Machine for Deep Engraving and Thin Metal Cutting]

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Received: April 10, 2015; Accepted: September 30, 2015

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