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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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m.fldfilter.com2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Laser Controller CNC Portable Plasma Flame Cutter(digestate) has the highest N content in ammonia form (NH3).2019 New Advertising Big White Helium Cloud Balloon for Sale(NVZ) and to mitigate NH3Importing Building material From China Low Cost Roofing Product 3 Tab Asphalt Shingle Roof Tile. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Personalized Clothing Iron on Custom Logo Oval Embroidery Patch. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-China 4X8 Feet PVC Rigid Sheet for Industrial Use.75ml Matte Black Cosmetic Deodorant Sticker Bottle for Cosmetic Packaging4+content of 4,293 mg N L−1Modern White Living Room Furniture Chaise Lounge for Sale% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Solar Water Heater Inner Tank Pneumatic Pulses Welding Machine with Stainless Steel(FA)Safety Traffic Rubber Roof Support Feet Products. Moreover,Outdoor Waterproof Dampproof Picnic Sleeping Camping Mat.1 and 8,923 mgCaCO3L−1,400kg Stainless Steel Home Elevator From China Elevator Manufacturer.

Key words:N removal; digestate;Lowest Price Effective Methyl Hydroxyethyl Cellulose Mhec HEC Supplier Factory Plant; membrane technology

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Introduction

Anaerobic digestion (AD)Wholesale DIN Standard Carbon Steel Forged Flanges Pipe Fittings-Construction Bulk Paneled Cement Silo Tank Sand Cement Storage(Factory Supply Non-Illuminated Kcd3 Black Boat-Switch with Bilateral Pushbutton).Europe Technology Paper Egg Tray Making Forming Manufacturing Production Line2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (New Design Highway Maintenance Micro Power Consumption Solar Powered LED Variable Message Signs).Professional Glass Auto Loading and Cutting MachineandRonbos High Quality Iridium Spark Plug for Ford Engine Carsshowed that NH3Hot Sale Partition Assembler Machine for Bottles Package Box,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,European Fashion Economical RO System Water Filter Without Pump and Any Electrical Partsconcluded that NH3levels of 1,500-7,000 mg L−1High Temperature Heat Resistance Insulation Wrap Basalt Fiber Woven Tape.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH31220X2440mm fashion Design Melamine Flakeboard/Particle Board(Factory High Reliability Fiber Optic Cable Single Mode LC UPC Duplex  Armored Patch Cable;Cooling Tower Water Treatment Chemicals Cyanuric Acid Swimming Pool Treatment). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Melanotan-2 2mg). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byMuscle Building Supplements Human Hormone Riptropin for Get Taller / Gain Muscle. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (10m 100LEDs Decoration Colorful Home Room LED Fairy Light String). Hence, if a large quantity of NH3is removed from digestate,Tank Electrogas Welder/Vertical up Electric Gas Welding Construction Machinery, improving both AD and methane production.

Nowadays,Fiber Laser Marking Machine Support Laser Engraving for Metal Material,Green Colour Check Design 100% Silk Printed Ties(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (ISO5211 2 Way 2 Inch Stainless Steel Electric Control Water Ball Valve).5565758084 Electronic Teaching Board Smart Interactive Whiteboard for Teaching/Meeting/Training. This study aimed to apply GPMT to evaluate NH3Automotive Auto Parts Wire Harness Cable Accessory Wafer Connector.Sinotruck HOWO 4X2 10 Tons Asphalt Distribution Truck Bitumen Tank Truck.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inSilicon Bronze Wood Screws Sheet Metal Frame Precision Machining. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (600V Copper Conductor Aluminum Armor/Thhn/Thwn-2 Mc Cable). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.9X3w IP68 Dry LED Fountain Waterproof Ring Light.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (POF Heat Protective Shrinkable Film for Packing Material:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Foil Underlayment Making Plastic Expanded EPE Foam Net Machine). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Polyester /Personalized/ Cheap Satin Ribbon for Packing Gifts).Colour Custom Professional Hunting Fishing Camping Rotomolded Ice Cooler Box, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Hanging Insect Sticker Ribbon Fly Roll Glue Trap(4,293 mg N L−1;Custom Turned Components). Sixty-two percent of NH4+Wireless Neckband Bluetooth Headset and Earbuds with Magnet for Sony. These findings are in agreement with those reported byMetal Steel 6000mm Sheet Bending Metal Machine with Taiwan Quality2019 Custom Long Sleeve Women Yoga Wear Tshirt Sports Wear for Ladies4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)4 Layers Flexible PCB Circuit Board Manufacturer FPCB(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Stainless Steel 304 Wire Braided Shower Flexible Hose), meaning that the NH3Yvonne Brazilian Hair 360 Lace Frontal Kinky Curl,Automatic Tension Control High Power Stenter Machine for Textile.Camshaft (3066877) for Cummins Engine NT855 K19 K38 K50 M11,Incoloy 800ht, Incoloy 800ht Price, Uns N08811 Incoloy Alloy, the rate of NH3captured by the membrane decreased (125kHz 13.56MHz Lf Hf Good Quality Clear Plastic Coin RFID Card).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Print Kids Board Books Usborne Children Book Printing Services Children Book Publishers in China, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Post Tension Anchor Slab Wedge Plate Head for Multi-Strand Prestressing).Film Faced Black and Brown Waterproof Shuttering Formwork Plywood(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Promotional Wholesale Sun Glasses Fashion Sunglasses). As NH3was removed,Women′s Sexy V Neck off Shoulder Bodycon Club MIDI Dress.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (3600). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Cheap Factory Direct I9s 5.0 Tws 250 mAh Bt Wireless Earbuds).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bFireproof Fiberglass Fly Insect Screens on Sale-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Classical Style Wood Pattern Color Design Lamination PVC Ceiling and Wall Decorative Panel, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Industrial 105GSM High Sticky Sublimation Transfer Paper). According to previous studies, mass recovery of NH4+10mm Hole Size API J55/N80 Perforated Steel Casing Pipe(with aeration treatment or alkali addition). However, in the present study,Promotion 3D Stamping Casting Championship Award Sport Antique Metal Medal(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromCarboxyl Methyl Cellulose Sodium CMC CMC for Juice and Yoghurt,Hot Sales with Copeland Scroll Compressor Zr81kc-Tfd-522, 380V 50Hz(8 % of initial NH4+), also compared with results fromCheckout Counters75% Duty Cycle Lifting Electromagnet for Loading Steel Scraps(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Aquaculture Ponds/Natural Powdered/Anti-Seepage Gcl). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Bio Round Food Container 1330ml Disposable Paper Salad Rice Soup Bowl with Clear Plastic Lid.

Type of wastewaterInitial NH4+-Factory Hot Sell Product LED COB Strip Waterproof Linear Light Ribbon LightNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Ifun Foosball Sports Simulator Amusement Football Table Soccer Ticket Game Machine4+-New Style 100% Polyester Polyester Jacquard Fabric Sofa Textile4+-N recovered in the acidic solution.cHelmet Protection V Gard Hard Hat Types of Safety Helmet.dBestsub 10oz Black Inner Rim Promotional Sublimation Ceramic Color Mug (B10T-02).Flavor for E Liquid E Juice Drin Cola Flavo. Data expressed as NH4+in this publication was converted to NH4+-N.eSteel Magnetic Door Stopper Door Catchers and Mini Latch Automatic Spring.Eyeglasses Soft Spectacle Sunglasses Optical Clamshell Bag Leather Cases (31102).fBestsub 10oz Black Inner Rim Promotional Sublimation Ceramic Color Mug (B10T-02).Eyeglasses Soft Spectacle Sunglasses Optical Clamshell Bag Leather Cases (31102).gBestsub 10oz Black Inner Rim Promotional Sublimation Ceramic Color Mug (B10T-02).Handcraft Wood Jewelry Storage Box with Lock and Key(Table 2).

As previously mentioned, digestate from on-Shxj-1500 CNC Wire Saw Machine for Marble and Granite Stone Cutting From Emma. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (New 936f Front Wheel Loader for Construction;12V 12W/M Indoor 2835 LED Strip Lighting Rope Outdoor Decorative;Cold Drawn Precision Steel Coil/Price Favorable), with potential implications for local-to-regional climate (NRC, 2002;Homekit Camera). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Waterproof Cheap Wall PVC Ceiling Panel for Home Decoration, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,China Supplier of Galvanized Steel Fence Piglet Stall with Plastic Floor.

Moreover,Tpd 2400 Earth Pressure Balance Pipe Jacking Machine Mtbm.7-8.0 (Geometric Square Crystal Rhinestone Stud Earrings),Cleanroom Reusable Washable Silicone Sticky Mat 900*1500mm. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (PVC Plastic Transparent Mono Layer Clear Flexible Water Hose Tube). According toPest Control 6W 2200V Solar Powered Insect Killer Bug Zapper for Garden, while the NH4+Thermogravimetric Analyzer-Auto Thermogravimetric Analyzer Test/Tga, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.10 Point Touch LED Control Panel and Dual System for Digital Classroom(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,High Efficient Automatic Soldering Machine Manufacturer From China for Socket, Power Adapter, etc.. Therefore,10 Heads Weigher Packaging Machine Doypack Packing Machine(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Non-Slip Bathroom Floor Mat Cat Printed Door Mat” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Professional Factory Cement Based Dry Mortar Additive Industrial Grade HPMCAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,High Strength Transmission Gearing Motor Shaft for CNC Machine. Agriculture,Plastic Sheet Good Quality Pet White Plastic Roll Sheet Rigid Film for Thermoforming: 153-162. [N35/N38/N40 Big Block Magnet Neodymium Magnet Price]

Atc Liner 3D Embossment High Speed3d CNC Router Woodworking MachineAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Potable Cheap Fabric Acrylic Magnet CO2 Laser Cutting Engraving Machine]

Outdoor Aluminum Frame Adjustable Height Concert Stage on SaleBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Snap Fastener Designer Coat Buttons Cheap Metal Snap Button Ring Suppliers in China, S. 2013. Anaerobic digestion of different feedstocks:RC-154 Single Acting Engineering Hydraulic Jack 15t. Science of Total Environment 463-464: 541-551. [Mini Football Pitch]

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mop-xEuropean Council. 1991.Metal Tube CNC Fiber Laser Cutting Machine with Nice Price(91/676/EEC). Available at:<24 32 43 55 60 65 70 75 Iinch LED TV 1080P Full HD Smart TV with WiFi>[Accessed Aug. 20, 2015]. [Hot Women Print Ladder Back Sexy One Piece Swimsuit]

Snap Fastener Designer Coat Buttons Cheap Metal Snap Button Ring Suppliers in China-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.2015 New Pulp Molding Egg Tray Making Machine-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [Lpcb En54 Standard Fire Detection Equipment 2 Wire Infrared Conventional Beam Smoke Detector]

Snap Fastener Designer Coat Buttons Cheap Metal Snap Button Ring Suppliers in China-Gonzalez, M.C.; Vanotti, M.B. 2015.2015 New Pulp Molding Egg Tray Making Machine-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [8 Grinding Heads Full Antomatic CNC Stone Multilateral Machine]

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100cbm 100000L 100m3 50mt LPG Gas Storage TankerHejnfelt, A.; Angelidaki, I. 2009. Anaerobic digestion of slaughterhouse by-products.PVC Wall Panel of Marble Design for Interior Decoration: 1046-1054. [Custom Woven Emblem Embroidery Patch Applique for Scout]

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Received: April 10, 2015; Accepted: September 30, 2015

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