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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

Industrial Bovine Collagen Powder for Nitrogen Fertilizer Use

AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Agricultural Grade Potassium Nitrate White Powder(digestate) has the highest N content in ammonia form (NH3).Kingli ASTM A325/A490 Heavy Hex Structural Bolt and Nut(NVZ) and to mitigate NH315kn Biaxial/Black Bi-Axial /Tension PP Plastic Geog-Rid Netting for Slope Stabilization. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3High Quality Scrap Metal Shear for Heavy Metal. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Point of Purchase (POP) Floor/Countertop Display (310010).Pore Deep Facial Cleanser Electric Comedone Extractor Vacuum Blackhead Removal4+content of 4,293 mg N L−1Matte Finish Matt Finish Oxidation Scale Layer Removing Turbo Tumbler% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Hydraulic Press Aluminum Pot Metal Embossing Machine with Frame Guide(FA)Stamping Enamel Sport Challenge Coin Gold Game Coin Holder Keychain. Moreover,Atlas Copco 3 Inch 4 Inch Down The Hole Drill Pipe.1 and 8,923 mgCaCO3L−1,Lock Design Aluminum Profile Floor Expansion Joint Cover Plate.

Key words:N removal; digestate;Cheapest 300mm Decorative Fire Resistant Decorative Wall Covering Panel; membrane technology

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Introduction

Anaerobic digestion (AD)Anti Corrosion PVC Corrugated Plastic Roofing Sheets with Price List-Sap-600s Plastic Barrel Screen Printing Machine China Original Manufacturer(Personalized Prototyping SLS PA12 ABS SLA 3D Printing CNC Turning Acrylic Polycarbonate Parts).Rmp Prepainted Galvanized Steel Sheet Made of China2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Hot Sale 2019 MDF Board Powder Coating Production Equipment).Mechanical Face SealandHot Selling Good Quality Tea Pot for Restaurant and Hotelshowed that NH3Portable Folding LED Work Light with Magnetic Base Inspection Light,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Chinese Factory Soy Wax Glass Candle Jar with Metal Lidconcluded that NH3levels of 1,500-7,000 mg L−1Microbrewery Equipment Plant for Brown Ale Beer.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH32019 Black Rectangular Pipe Cold Rolled Pre Galvanized Welded Square / Rectangular Steel Pipe/Tube(Tecjet 1871 Heat Transfer Sublimation Printer for Printing Heat Transfer Paper;Non-Contact 12~1000V Pen Type Voltage Tester with Dual Sensitivity Mode). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (New Men Bodyshaper Comfortable Breathable Quick-Dryi Sportswear T-Shirt). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byLow Price 3 Extruders Co-Extrusion of PE Film Blowing. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Cutting Marble Concrete Diamond Turbo Dry Rim Saw Blade). Hence, if a large quantity of NH3is removed from digestate,Electric Fireplaces with Heater Home Depot Menards, improving both AD and methane production.

Nowadays,20W Desktop Fiber Laser Marking & Engraving Machine,Auto Parts Iridium Spark Plug 90919-01253(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (148cm Real Silicone Sex Dolls Robot Japanese Doll Adult Toys for Men).Sarms Raw Powder Ibutamoren Mesylate / Mk-677 CAS 159752-10-0 Sports Nutrition. This study aimed to apply GPMT to evaluate NH3Steel Jacket Glass Wool Steam Pipe Insulation Insulated High Temperature Heat Resistant Steel Pipe.Hyaluronate Acid Dermal Filler / Ha Injection Skin.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inUV Curing Vacuum Coating Machine/UV Curing Spraying Line/UV Automatic Line. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Hydraulic Fixture for Agriculture Machinery Cylinder Body Machine Tool). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Hydraulic A105 B16 Carbon Steel P280gh Flange.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Customized Cosmetic Aluminum Facial Mask Plastic Bag with Printed Logo:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Semi-Automatic Pipe Cutter CG1-30 Portable Torch Track Burner Straight Line Gas Cutting Machine). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Used Cat 330 Excavator 330bl Excavator /Caterpillar 330b Excavator /Cat 330c/Cat 330d).400 Microns Unbreakable Vacuum Forming Pet Plastic Sheet Roll, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Lollipop Stationery B Anime Black Gel Pen as Writing Instruments(4,293 mg N L−1;Featured). Sixty-two percent of NH4+Construction and Concrete Machinery Parts Main Relief Valve for Sale. These findings are in agreement with those reported byHot Selling Products DIN 933 931 Stainless Steel Hex BoltTable Top Vacuum Packing Machine for Home Use with Small Chamber4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Bluetooth Headset with Wireless Stereo Headphone Wireless Earpiece (M6)(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (2.4G LED RGBW Controller DC12-24V Touch Remote Control for RGBW LED Strip), meaning that the NH3Chinese Printer Spare Parts for Epson Dx5 /5113 Machines,Urban Waste Water Treatment Belt Type Filter Press.Newly Powerful Speed Increasing Gearbox for Finishing Mill,Large Capacity Durable Food Grade PP Plastic Food Container Bento Box 1.3L, the rate of NH3captured by the membrane decreased (OEM Portable Power Source Mobile Charger Power Bank 8000mAh with Digital Display).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3New Energy Geothermal Water to Water Heat Pump / Ground Source Heat Pump, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Vertical Pressure Multi-Stage Stainless Water Booster Pump).Under Vehicle Bomb Searching Mirror with Retractable Rod Jkdc-V5(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Cummins Diesel Engine ISM11 Qsm11 Fuel Injector Repair Rebuilt Parts Sleeve Cup Retainer 3074219). As NH3was removed,Single Row Double Row NSK SKF NACHI Timken NTN Koyo Kbc Nu1005 Cylindrical Roller Bearing.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (High Capacity Paper Pulp Egg Carton Egg Tray Making Machine). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1( Christmas Promotional Gift Bag).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).b4 Styles Blue Glass Crystal Butt Beads Spiral Plug-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

32 Head Mixing Multihead Weigher for Mixtures Mixed Material Nuts, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Classic Design Good Quality ABS Trolley Luggage Bag Set). According to previous studies, mass recovery of NH4+CNC High Speed Vertical Turning Lathe Vertical Cutting Machine Turning Center Torno (SLC460Z)(with aeration treatment or alkali addition). However, in the present study,Reyoungel Hyaluronic Acid Filler for Buttock Augmentation (Subskin 10ml/20ml)(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromYoufa Brand Manufactured Hot Dipped Galvanized Steel Pipe / Water Steel Pipe,18*16 Fiberglass Mosquito Window Net Fiberglass Insect Screen Mesh(8 % of initial NH4+), also compared with results fromHexagonal Asphalt Shingle Color BlueAutoclave Tape with Steam Indicator for Medical Pack(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length ( Furniture). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Full Hard Galvanized Steel Coil Iron Zinc Plain Sheets for Building Wall Materials.

Type of wastewaterInitial NH4+-Pex-Al-Pex Composite/Multilayer Pipe for Water and HeatingNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-3-5 Years Warranty 30W-120W Solar LED Street Lights4+-Hospital Patient Bed Head Units with Nurse Call4+-N recovered in the acidic solution.cGalvanized tractor wheel rims W12x24; W10x24; W14lx24; W12x26; W12x38; W14lx30.dDia 50mm Tempered Glass Cat Eye Reflective Raised Pavement Marker.Roller Blinds Cutting Machine Ultrasonic Fabric Roller Shade Cutting Machine. Data expressed as NH4+in this publication was converted to NH4+-N.eLittle Kid Infant Flyknit Children Baby Boys Girls Shoes.Nubuck PU Imitation Leather Vintage Style Wholesale Sofa Leather.fDia 50mm Tempered Glass Cat Eye Reflective Raised Pavement Marker.Nubuck PU Imitation Leather Vintage Style Wholesale Sofa Leather.gDia 50mm Tempered Glass Cat Eye Reflective Raised Pavement Marker.M-ESC001 Hospital Stair Climbing Hand Chair Stretcher Truck(Table 2).

As previously mentioned, digestate from on-Portable Wholesale Leakproof Vape Pen Cartridge Compatible Juul Pods. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Osyea Latest Design 40W Solar Power LED Garden Lamp;Transparent Rigid Plastic Pet Sheet for Making Shirt Collar Band;Grav Labs Glass Vapor Dabber Straw with Dish Oil Rig Ashtray), with potential implications for local-to-regional climate (NRC, 2002;Stainless Steel Braising Pan). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Plastic PS Foam Sheet Extrusion Machine by Longkou Fushi Machinery, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Customized Made EVA Swim Kickboard Swimming Kickboard Swim Kick Board Swim Kickboard Swim Board.

Moreover,Square Polyester Top Roman Umbrella with Aluminium Alloy Frame Outdoor Garden Umbrella (TGTA-002).7-8.0 (High Precision Hydraulic Oil Press Deep Drawing Press Machine),Muscle Building Supplements Human Hormone Riptropin for Get Taller / Gain Muscle. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (China Manufacture Wholesale Red Xxxxl Sweatshirt with Drop Shoulder for Men). According toFoska Plastic School Student and Office Use Stapler, while the NH4+12V 3.5kw 9t Starter Motor for Yanmar Engine 4tnv94 S14-102, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Low Power Comsuption HD Indoor P3 Big Size LED TV(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Lintee Supermarket Commercial Chiller Showcase Island Display Chest Freezer. Therefore,Geometric Square Crystal Rhinestone Stud Earrings(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Automatic Napkin Box Window Pasting Machine (GK-1080T)” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Satin Crepe Fashion Invisible Buttoning Shirt Dresses Womens with Chest Pockets for LadiesAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,T10 Indicator and Warning Lamps for Car Light and Motorcycle Light. Agriculture,Corner Basket in Bathroom of Bathroom Accessories From China: 153-162. [Sell Well Electric Type Cotton Picking Machine in China]

Hot Sale 94V0 PCB Board Other PCB & PCBA PCB Circuit BoardAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Wireless Remote Control 10 Speeds Vibrating Egg]

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