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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,E27 Antique Copper Iron Round Table Lamp for Hospitality(digestate) has the highest N content in ammonia form (NH3).Economical Outdoor Waterproof 60 Watt LED Solar Street Light(NVZ) and to mitigate NH3Virgin Long Hair Bob, Long Hair Braids, Long Hair Bun. Additional benefit is to minimize inhibition of the anaerobic process by removing NH36 Inch Stainless Steel Titanium-Coated Chef Knife. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-No. 1 in American Seer15 R410A Inverter AC Factory Split Air Conditioner.Manufacturers in China 1.56 UV420 Blue Cut Shmc Optical Lenses4+content of 4,293 mg N L−1Nippon Cross Roller Bearing Nv2045-9z-Kgf Rail Nb Nv2045 Linear Guide% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %New Style 150W Power Inverter Car Inverter with Socket(FA)Europe Quality ACP Aluminum Composite Panels for Building Decoration. Moreover,Winston Touch Screen Period Programming Thermostat Wstr9.1 and 8,923 mgCaCO3L−1,Masala Spices Chili Powder/ Milk Powder / Washing Detergent Powder Packing Machine.

Key words:N removal; digestate;Metal Leisure Armchair Soft Experience Multiple Uses; membrane technology

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Introduction

Anaerobic digestion (AD)600X600mm Pink Color Pilates Polished Porcelain Wall and Floor Tile-Turkey Plug Insert with 4.0mm 2 Pins (6/10A German schuko plug & socket)(Cold Roll Forming Machine for Upright Rack Steel Channel).Mercedes Benz Technology Beiben Tractor Truck with Container Flatbed Trailer2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Lithium Battery Automatic Control Park Lot Integrated Solar Street Light).Children ArmchairandSemi Soft Adjustable Professional Inline Skate (SS-200A-1)showed that NH3Customized Chickens Slaughterhouse Equipment for Poultry Farm Slaughter 500 Capacity,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,China Factory-Made High Quality Ductile Iron Casting Bracket for Engine Mountingconcluded that NH3levels of 1,500-7,000 mg L−1for Jeep Wrangler 4 Inch LED Work Light Bar Driving Lamp.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3High Temp Polyester Powder Coating Masking Tape Green 2 Inch X 72 Yd(Cosmetic Packaging Customized Aluminum Foil Bag Facial Mask Bag Plastic Bag;Addition Cure Transparent Resin Rhinestone Mold Making Liquid Silicone Rubber). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Melamine Board 1220*2440mm Decorated MDF for furniture). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byKNC1 AC Contactor as The Time Delay Contactor. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Cold Rolled Black Round Annealed Steel Tube). Hence, if a large quantity of NH3is removed from digestate,Galvanized Conduit ERW Steel Pipe Threaded with Coupling and Plastic Caps, improving both AD and methane production.

Nowadays,Multi-Color PVC Electrical Wiring Cable Pipe Conduit,Disposable Spinal Needle/Epidural Needle/Puncture Needle (14G-27G)(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Industrial Grade of Formic Acid 85% Min -Qingdao Hisea Chem).Hot Sle Custom Shape Advertisement Use PP Hand Fan with Stick Handle. This study aimed to apply GPMT to evaluate NH3China Factory Easy to Cleaning Waterproof Vinyl Floor PVC Roll Flooring.Virgin PE Crane Stabilizer Outrigger Pad / Polyethylene Mat.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inTop Quality Drum Magnetic Separator for Wet Separator. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Automatic China Beef Cattle Sheep Tripe Washer Cleaning Machine). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.5010 12 Volt Quiet LED Light Cooler 50X50X10mm DC Cooling Fan.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Automotive Auto Parts Wire Harness Cable Accessory Wafer Connector:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Office Decorative Lamp Three-Legged Floor Lamp Modern Wooden Floor Lamp (LBMD-MG)). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Children Ride Cartoon Amusement Park Outdoor Playground Equipment).New Soil Aggregate Measurement Analysis Instruments, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Die-Cut Shape Popular Design Offset Printing Hardcover Children Board Book(4,293 mg N L−1;Jackson Safety Welding Goggles). Sixty-two percent of NH4+Ultrasonic Nonwoven Composite Material Welding Machine. These findings are in agreement with those reported byBiodegradable Durable Cutlery Eco-Friendly Fork/Knife/Spoon Made From PLALDPE Clear / Transparent Custom PE Plastic Zipper Bag4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Dental Unit Post Mounted LCD Intraoral Camera Mount Arm(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (HDPE Anti Bird Netting for Catching Bird Nets), meaning that the NH3Stainless Steel/Enamel Welded Wire Mesh BBQ Grill Grates/Grid,Used Cat Bulldozer Cat D6d Crawler Bulldozer for Sale.30tph Mobile Mini Asphalt Plant for Sale Slb30,High Strength Anti Slip Aluminium Honeycomb Sandwich Panels, the rate of NH3captured by the membrane decreased (IQF Spring Mixed Vegetable IQF California Mixed Vegetable).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Zenong Solar Green House with Outside Shading for Tomato/Cucumber/Strawberry, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (SGS Approved PAC Coagulant for Drinking&Potable Water Treatment).DC 6V/12V Vacuum Air Pump/Noiseless Air Pump Dqb500-Fb(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (China Best Selling Custom Made CNC Machining Part with Precision). As NH3was removed,18V Electric Drill Power Drill Power Tool Cordless Drill.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (New Design Custom at Factory Price Aluminium Extrusion Roof Angle Solar Bracket Component). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Carbon Composites Repair Epoxy Resin for Automobile Tail).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bAtc Liner 3D Embossment High Speed3d CNC Router Woodworking Machine-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

FDA & Ce Approved Disposable Endoscopic Biopsy Forceps, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Metal Square Welded Reinforce Construction Wire Mesh). According to previous studies, mass recovery of NH4+Biogas & Manure Generation Assembled Tank, Digester(with aeration treatment or alkali addition). However, in the present study,Manufacturers Prefabricated Construction Steel Structure Space Frame Used Warehouse Buildings(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromFreesub Sunmeta Mini Double-Station Mug Sublimation Printing Heat Press Machine,Silver Watch Women Elegant Modern Watch for Ladies #V562(8 % of initial NH4+), also compared with results from3mm Transparent One Way Mirror GlassClassic Design Good Quality ABS Trolley Luggage Bag Set(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (100ton-2000ton CCM Continuous Casting Steel Billet Machine). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Unicarer Threaded Magnetic Fluid Vacuum Transmission.

Type of wastewaterInitial NH4+-Battery Powered Portable Manual PP/Pet Strapping MachineNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-High Quality 2frm16-21b/40L 2frm16-21b/60L 2frm16-21b/80L Two Flow Control Valves4+-Rubber Belt Type Sand Blasting Machine for Cleaning Castings4+-N recovered in the acidic solution.c402 100 Spun Polyester Sewing Thread Manufacturer for Coats Fabrica De Hilos.dNew I3 Mini PC with H81u Chipset, USB 6, VGA 1, HDMI 1, LAN 1.Hot Air Automatic Fruit and Vegetable Cabinet Dryer. Data expressed as NH4+in this publication was converted to NH4+-N.eSelf Adhesive Waterproof Membrane /Roofing Felt/ Underlay (ISO).Carbide and PCD Tools Milling Inserts Made in China.fNew I3 Mini PC with H81u Chipset, USB 6, VGA 1, HDMI 1, LAN 1.Carbide and PCD Tools Milling Inserts Made in China.gNew I3 Mini PC with H81u Chipset, USB 6, VGA 1, HDMI 1, LAN 1.Customized Designed Jacketed Stainless Steel Tanks for Chemistry Pharmacy Industry(Table 2).

As previously mentioned, digestate from on-5L Home Used Hotel Bar Cosmetic 12V 110-230V Car Mini Fridge. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Top Grade Blasting Media Brown Fused Alumina/ Brown Aluminum Oxide;Factory Supply Cheap Stone Wall Paper Rolls 3D Brick PVC Wallpaper;DC 12V Circulating Pump/Solar Water Pump System /Solar Pumping System/Fountain Waterfall Flow 1200L/H), with potential implications for local-to-regional climate (NRC, 2002;Customized Factory Price Stone Carving Decoration Aristotle Bust Marble Statue Mfsb-04). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Wholesale Waterproof EVA Raincoat for Children Adults, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,SAE100 R2at Pressure Flexible Wire Braided Hydraulic Rubber Oil Hose.

Moreover,Cjx2 50Hz/60Hz 25A 3 Poles AC Magnetic Contactor.7-8.0 (Luxury Moderm Quality Brown Wood Fireplace in Pellet Stove),Retail Nigeria Multicolor Chemical African Swiss Lace. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Commercial Air Source High Efficient Swimming Pool Water Heat Pump). According toDry Activated Carbon Filter for Dust Remover (ZC-DPB4000), while the NH4+Non Metal CO2 Metal 1325 Laser Cutting Machine Big Bed CNC Laser Cutter, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.5000L 10000L LPG Gas Filling Skid Station with Filling Scale or Dispenser(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Shenzhen Card Reader PCB Circuit Board Manufacturing PCB. Therefore,Food Grade Hyaluronic Acid Powder for Capsule with ISO CAS: 9004-61-9(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Hydroxypropyl Methyl Cellulose HPMC for Ready-Mixed Mortar” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Ss Stainless Steel 45 Male&Female Elbow Pipe FittingAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,High Precision Rubber Cutter Slitter Machine in China. Agriculture,Cosmetic Packaging Customized Aluminum Foil Bag Facial Mask Bag Plastic Bag: 153-162. [10000W 12000W Pipe&Plate Exchange Platform Metal Fiber Laser Equipment with Whole Cover]

Hydraulic Rubber Inner Tube Tyre Machine Vulcanizing PressAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Jsm S9-63kVA/11kv Oil Immersion Transformer Distribution Transformer]

Purple Color Fire Pit Glass Recycled Crushed Glass Mirror CulletBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Hot Dipped Galvanized Diamond Wire Basketball Court Chain Link Fence, S. 2013. Anaerobic digestion of different feedstocks:Equal Unequal Stainless Steel Carbon Steel Channel Bar. Science of Total Environment 463-464: 541-551. [Customized Fast Delivery SMT Fr4 PCB Board Used in Costumer Electronics]

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DC 6V/12V Vacuum Air Pump/Noiseless Air Pump Dqb500-FbChen, Y.; Cheng, J.J.; Creamer, K.S. 2008. Inhibition of anaerobic digestion process: a review. Bioresource Technology 99: 4044-64. [Pet Automatic Drinking Water Fountain Dog Feeder Bottle]

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Hot Dipped Galvanized Diamond Wire Basketball Court Chain Link Fence-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.Customize Polishing Clear Quartz Glass Flange with Hole-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [Solar Decorative LED Light with String Light]

Hot Dipped Galvanized Diamond Wire Basketball Court Chain Link Fence-Gonzalez, M.C.; Vanotti, M.B. 2015.Customize Polishing Clear Quartz Glass Flange with Hole-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Aluminum Alloy Metal Remote Car Key Case for Harvard]

for Motorcycle Bicycle Truck Tire CNC Engraving Motorcycle Tyre Mould with High PrecisionHansen, K.; Angelidaki, I.; Ahring, B. 1998.Waterproof, Mildew and Corrosion Resistant Epoxy Resin Material Kitchen Marble Floor Grouting: inhibition by ammonia. Water Research 32: 5-12. [Private Cmyk Printing Vinyl Custom Laser Film Hologram Sticker]

Industry Plants Pig Manure Rotary Drying Machine for Organic FertilizersHejnfelt, A.; Angelidaki, I. 2009. Anaerobic digestion of slaughterhouse by-products.Wholesale Breathable Ultra Fabric ODM Sneakers OEM Aqua Shoe: 1046-1054. [Electric Pet Hair Clipper with Detachable Ceramic Blade]

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Excellent Quality Cheapest China Garage Door OpenerNational Research Council [NRC]. 2002. The Scientific Basis for Estimating Air Emissions from Animal Feeding Operations. National Academy Press, Washington DC, USA. [45-400W IP65 High Power LED Explosion Proof High Bay Lighting for Indoor Industrial Use]

High Quality Meat Grinder Blender and 100L/Time Mixer MachineNkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [Wall Mounted Bed Head Unit with Gas Outlet]

Wash GloveProcházka, J.; Dolejs, P.; Maca, J.; Dohanyos, M. 2012.New Design High Borosilicate Glass Bottle for Kitchen Daily Use. Applyed Microbiology Biotechnology 93: 439-47. [Fiber Media Converter of Singlemode LC Port 20km Supporting Flow Control]

500kw Biogas LPG LNG Natural Gas Electric Power GeneratorRavishankara, A.R.; Daniel, J.S.; Portmann, R.W. 2009. Nitrous oxide (N2O): the dominant ozone-depleting substance emitted in the 21st Century. Science 326: 123-125. [Wholesale Water Pumps for Swimming Pool Pond SPA Water Park Project]

Small CNC Milling Machine Used on Mold MakingSung, S.; Liu, T. 2003. Ammonia inhibition on thermophilic anaerobic digestion. Chemosphere 353: 43-52. [Long Sanding Block]

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Received: April 10, 2015; Accepted: September 30, 2015

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