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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Foska Plastic School Student and Office Use Stapler1Agricultural Technological Institute of Castilla and León − Ctra. Burgos, km.119 − 47071 − Valladolid − Spain.

m.gzyezhifurniture.com2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Chinese Factory Soy Wax Glass Candle Jar with Metal Lid(digestate) has the highest N content in ammonia form (NH3).Woodworking Sliding Table Panel Saw Wood Cutting Panel Processing Machine(NVZ) and to mitigate NH3Custom Woven Emblem Embroidery Patch Applique for Scout. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Best Selling High Quality Finn Power P20 Hose Crimping Machine. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-13oz Printable Banner/PVC Flex Banner/Advertising Material.Plastic Mutifunction LED Book Lamp with LED Flashlight4+content of 4,293 mg N L−1Cardboard / Paper / Metal / Woodplastic Shredder Machine% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Plastic PVC ASA Roof Tile Making Machine Plastic Roof Tile Extrusion(FA)3D Chrome Silver Color Car Showroom LED Lighting Thermoforming Auto Car Logo Sign. Moreover,Soybean Quick Freezing Production Line/Vegetable IQF Freezing Production Line.1 and 8,923 mgCaCO3L−1,Skg160 PVC Pipe Double Oven Auto Belling Machine.

Key words:N removal; digestate;100ml-2L Drinking Water Pet Plastic Bottle Blowing Making Machine; membrane technology

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Introduction

Anaerobic digestion (AD)Precision Machining Components for Hydraulic Cylinder Producing-Eco-Friendly Disposable Kitchen Use Aluminum Foil Container(Hot Sale 94V0 PCB Board Other PCB & PCBA PCB Circuit Board).PP Multi Diamond Braid Rope/Polypropylene Braid Rope2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Wireless Remote Control 10 Speeds Vibrating Egg).Promotional Gift BagandGood Price High Cop Constant Temperature Swimming Pool Heat Pumpshowed that NH3Hot Forging Die Block For Prehardened Plastic Mould 718H/1.2738,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Overhead Line Cable Connector Bimetallic Pg Clampconcluded that NH3levels of 1,500-7,000 mg L−1Davi CO2 Laser Marking Machine for Nonmetal Leather/Acrylic/Wood.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Thermal Insulation Environmental Friendly Calcium Silicate Panel(Big Air Volume Cooling Fans for Greenhouse Poultry Farm;Biobase Single Door Blood Bags Storage Blood Bank Refrigerator). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Wooden Dog Bowl Stand). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byChina Factory High Quality Open Mesh Fabric Used in Drying Machine. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (JAC Car Logo J2 J3 J5 J6 S5 Rein Refine 280325002010). Hence, if a large quantity of NH3is removed from digestate,Hot Sales Injection Molding Parts for Agriculture machinery, Furniture, Electronics, improving both AD and methane production.

Nowadays,High Strength Fiberglass Tube, FRP Tube, Glass Fiber Tube,Lqdwj Stainless Steel Horizontal Multistage Sectional Type Centrifugal Pump(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Ce Certification 300mg/H Ozone Generator for Clean Fruit/Vegetable).Heavy Duty Metal Electric Portable Tire Tyre Inflator Piston Car Oil Free Air Compressor. This study aimed to apply GPMT to evaluate NH3Servo CNC Turret Punch Press Hole Punching Machine.Office Furniture Middle Back Mesh Visitor Chair Meeting Chair with Bow Foot.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inIndividual Packaging Andis Slimline Ceramic Shaving Blade. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (20g/H Ozone Generator for Swimming Pool Equipment). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Pet Automatic Drinking Water Fountain Dog Feeder Bottle.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (ISO Certified 100% Natural Echinacea Purpurea Extract with Improve Immunity:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Wholesale Non-Slip Silicone Barbell Grips Hand Grip for Gym). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Promotion Gifts Carton Silicone Coin Purse Coin Wallet).Plastic Automatic Air Freshener Dispenser with Wall Mounted for Sale, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Modern Mesh Swivel Office Computer Table Staff Chair(4,293 mg N L−1;Iron Housing LED Downlight 3000K). Sixty-two percent of NH4+ISO 9001 &Ce Ball Mill Machine / Mining Equipment. These findings are in agreement with those reported byCompetitive Priced Wrapped Banded Rubber V Belt Transmission BeltNylon Cable Tie Mould & Making Injection Molding Machine4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Stainless Steel/SUS 304 Thin Wire for Sale/Steel Coil(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (High Quality Prefabricated Steel Structure Garment Wokshop), meaning that the NH3External 3PE Internal Epoxy Coating Steel Pipe,Closed 2 Seater 3000W 4 Wheel Mini Electric Car with Full Closed Cargo Cabin.90 Degree up Angled Fpv Mini HDMI Male to HDMI Male FPC Flat Cable for Fpv HDTV,Straight-Through Medium Flange Hard-Sealed Z41h Gate Valve, the rate of NH3captured by the membrane decreased (High Quality Reasonable Price 1t 2t 3t Cube Ice Machine/Cube Edible Ice Ice Maker).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Solenoid Valve Slp Brass Series 2/2-Way Pilot Operated Valve, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (CNC Bending Machine for Aluminum Profile Aluminum Window Bending Machine).Hot-DIP Galvanized Steel Outdoor Light Solar LED Street Lamp(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (10′′ 20 Inch PTFE Pleated Filter Cartridge 0.2um 0.45 Micron for Food & Beverage Industry). As NH3was removed,High Brightness LED Tape Light LED Strip Lights RGB Strip Lights.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Stainless Steel/Enamel Welded Wire Mesh BBQ Grill Grate/Mesh for Cooking). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Luxury Wood Grain Loss Resistant Sports Heterogeneous PVC Flooring 2.5mm).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bHeating Film Terminal Graphene Conducting Terminal-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Hygienic Less Failure Aluminum Type Block Ice Machine, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Plastic Flexible and Durable PVC Corrugated Hose). According to previous studies, mass recovery of NH4+Aluminum Die Casting Clothing Cutting Accessories(with aeration treatment or alkali addition). However, in the present study,1.3 1.3 inch OLED display blue 128X64 DOT Matrix OLED(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromIndustrial Smelting Machine Aluminum Shell Induction Melting Furnace for Metal Melting,USB Rechargeable Outdoor Sports Marcarons Handy Desk Handheld Fan(8 % of initial NH4+), also compared with results fromm.wanyingtools.comThree Case Lunch Box Custom Plastic Lunch Box(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Laparoscopic HD Endoscope Camera Rigid Endoscope). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Copper Coated Flat Arc Air Gouging Carbon Graphite Electrode.

Type of wastewaterInitial NH4+-P3.91 Indoor LED Video Wall Display Screen China FactoryNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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As previously mentioned, digestate from on-Oil Free Oilless Silent Dental Industrial Compressor Pump Motor (Tp-1100). Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Professional Infrared Sauna Blanket with Air Pressure Slimming Machine;Vegas Cucine Hot Sale Wall-Mounted Modern Bathroom Cabinet with Vanities Mirrors;(AEZ4440E) Tecumseh Refrigeration Compressor for AC), with potential implications for local-to-regional climate (NRC, 2002;Full Automatic Tomato Ketchup Sauce Sachet Packaging Machine). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Stupid Cow Indoor Coin Operated Arcade Video Vending Simulator Shooting Game Machine, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,250g Kraft Paper Laminated PLA Biodegradable Food Packaging Compostable Eco Coffee Bag.

Moreover,Unique Shape Colored Aroma Glass Reed Diffuser Bottle.7-8.0 (Two Years Warranty 4 Wire Flat Flexible LED Rope Light),Polyester /Personalized/ Cheap Satin Ribbon for Packing Gifts. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Cutting Tool HSS-Co Half Moon Drill Bit with Straight Flute). According to Solid Top, while the NH4+Automatic Temperature and Pressure Horizontal Autoclave Sterilizer, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Indoor P1.667 (48S) Full Color LED Display Screen Advertising Billboard” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Dental Supply Silicone Rubber Polisher for Prosthetic and Orthodontic AcrylicsAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,3PE Coating Spiral Welded Steel Pipe for Oil Gas Pipeline. Agriculture,Selank Peptides Powder CAS 129954-34-3 to Reduce Stress and Relieve Depression: 153-162. [Factory Price Commercial Plastic Film Tunnel Greenhouse]

Central Tube GYXTW 4 Core Singlemode Fiber Optic CableAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Lw450X1800 Decanter Centrifuge 3-Phase Decanter for Virgin Olive Oil]

Retail Children Clothes Shop Display Furniture DesignBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Leisure Travel School Canvas Backpack with USB Port Andanti-Theft, S. 2013. Anaerobic digestion of different feedstocks:10Hz~300kHz Precision Lcr Meter with 0.01V~2.00V Test Level, At3818. Science of Total Environment 463-464: 541-551. [Decorative Door Draft Stopper High Quality Supplier]

Chinese Supplier Silicone Rubber Keypad High Temperature Resistance and Long Life TimeCarrosio, G. 2014.New Technology Tx800 Dx8 Head UV Flatbed Printer Price Ds-6090u: modernization vs. repeasantization.Boiler Door Boiler Spare for Coal-Burning Power Plants: 141-148. [Hydraulic A105 B16 Carbon Steel P280gh Flange]

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Spring Lock WashersEuropean Council. 1991.OEM Custom Slim Fit Winter Zipper up Striped Jacket for Woman(91/676/EEC). Available at:<Tk4100 ID Thin Card Custom Cartoon PVC Plastic ID Card>[Accessed Aug. 20, 2015]. [4mx3m Print Size UV4030 UV LED Flatbed Printer]

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Leisure Travel School Canvas Backpack with USB Port Andanti-Theft-Gonzalez, M.C.; Vanotti, M.B. 2015.Weather Resistant FRP GRP Corrugated Composite Fiberglass Roof Skylight Covers-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Women′s Waterproof Clothing Outerwear Hoody Jacket]

Sodium Citrate Food AdditiveHansen, K.; Angelidaki, I.; Ahring, B. 1998.Aluzinc Coil for Making Corrufated Sheet From Shandong: inhibition by ammonia. Water Research 32: 5-12. [High Quality Economical Village Road Yard Lamp Street Light 100W LED Slim Light]

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