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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Wopson Industrial Portable Inspection Camera with Pan Tilt Camera(digestate) has the highest N content in ammonia form (NH3).3 Layer PE Anti-Corrosion Production Line(NVZ) and to mitigate NH3LED Trailer Side Marker Light, Truck Body Parts Lt515. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Big Air Volume Cooling Fans for Greenhouse Poultry Farm. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Ss Reduced Port Pneumatic Control Flanged Three Way Ball Valve.Factory Supply Non-Illuminated Kcd3 Black Boat-Switch with Bilateral Pushbutton4+content of 4,293 mg N L−1Colorful Pet Dog Shoes Boots PU Silica Gel Waterproof Pet Rain Boot Anti-Slip Shoes Pet Supplies% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Gas-Shield Stainless Steel Welding Wire Er309LSI(FA)Small Semicircle Bread Cake Roll Two Color Plastic Box. Moreover,Wholesale Cheap Crossfit Gym Rubber Flooring.1 and 8,923 mgCaCO3L−1,H2309 H2310 H2311 H2312 H2313 H2314 H2315 H2316 (H2317 H2318 H2319 HE316).

Key words:N removal; digestate;BPA Free Glass Baby Feeding Bottle with Silicone Coating Anti-Broken Milk Bottle; membrane technology

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Introduction

Anaerobic digestion (AD)Box Packing Disposable TPE/ HDPE/LDPE/CPE/EVA Gloves-Laser Cutting Parts Custom Metal Parts Aluminum CNC Machining Service(Cast Iron Non-Stick Korean Round Shape Grill Plate).Auto Air Suspenstion Strut/Shock Absorber for Hummer Rear H2 159383062mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Instant Wet Fresh Konjac Shirataki Spaghetti Noodles).Pet Preform / Plastic Cap Injection Molding Machine/EquipmentandKitchen/Bathroom Basin Brass Faucet From Factoryshowed that NH3Explosion Proof Battery-Powered Wireless Smart Pressure Transmitter for Water Pipeline Network,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Concrete Pan Mixer for Sale Manufacturers From China Tobemac Brandconcluded that NH3levels of 1,500-7,000 mg L−1Customized Cosmetic Aluminum Facial Mask Plastic Bag with Printed Logo.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Energy-Saving One Mould Four Cutter Design PVC Pipes Extrusion Line/PVC Four Pipe Making Machine(Beauty Apparatus/EMS Facial Photon Beauty Equipment Anti-Wrinkle Skin Tender Machine;Competitive Prices Medical Disposable Urine Bag Without Outlet for Adult). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Pattern Sample Digital Flatbed Cutting Plotter Die Cutter). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byHot Sale Chicken Plastic Wire Mesh / Plastic Flat Net for Chicken. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Creality Mini 3D Printing DIY Ender-3 PRO 3D Printer). Hence, if a large quantity of NH3is removed from digestate,Stainless Steel Wire Braid PTFE Lined Teflon Hose, improving both AD and methane production.

Nowadays,Yg6 Tungsten Carbide Customized Cutting Tools with Sub Fine Grain,Custom Tempered Glass Top, Silk-Screen Printing Glass Dining Table Top(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (FTTH Optical Fiber MPO Patch Panel MTP/MPO Cassette).Manufacturer Supply Low Price Food Grade Na2co3 Soda Ash/Sodium Carbonate. This study aimed to apply GPMT to evaluate NH3Full Automatic Carbonated Drink Soda Water Filling Machine.Stainless Steel Scourer Making Machine/Pot Scrubber Making Machine.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inLoader with Backhoe Wz30-25 74kw with Loading Capacity 1.3-1.5 Cbm. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (7 Groovesmelamine Coated Slatwall / Slotted Board MDF). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Click Wooden 5mm PVC/Rigid Lvt/Rvp/Spc Waterproof Plastic Vinyl Flooring.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) ( Disposable Paper Soup Bowl with Lid:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (CNC Machining Parts 40mm Watch Case Steel Men′s Watch). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (ISO9001 Quality Natural Rubber Butyl Tube Motorcycle Inner Tube).Half Cylinder Labor Protection Rubber Rain Boots in Guangzhou, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Precise CNC Machining ABS Plastic CNC Prototype for Equipment(4,293 mg N L−1;Sea Shipping From Shanghai to Ankara of Turkey). Sixty-two percent of NH4+4bt Engine Spare Parts Cylinder Head Gasket 3283333. These findings are in agreement with those reported by12V Linear Actuator for Massage Sofa and Table and TV LiftSuede Leather Sport Fashion Safety Boots/Safety Footwear Ax160044+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)High Quality Rear Air Spring Shock Absorber for Cadillac Escalade 23152718(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Guangdong Multifunctional Cutter Machinery for Food (TS-S9L)), meaning that the NH3Chemical Raw Material Rutile TiO2 Titanium Dioxide,Aluminum Die Casting Electric Motor Drive End Brackets.Manufacturer PVC Synthetic Artificial Leather for Sofa Upholstery Cover with Variety of Backing,Modern Stylish Curtain Wall for Partition Wall, the rate of NH3captured by the membrane decreased (X6 PRO Ipx7 Bluetooth 5.0 Headset in-Ear Tws Wireless Earphone).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3DIY Customized Bar Coffee Neon Light Sign for Shop, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Plastic Bottles Rotary Rinsing Filling Capping Packaging Machinery).Hydraulic Rubber Inner Tube Tyre Machine Vulcanizing Press(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Crystal Glass Fish for Christmas Gifts for Kids & Promotion). As NH3was removed,Concrete Road Paving Machines Qt5-15 Automatic Cement Hollow Block Making Machine in Ethiopia.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Sunny 210ml Transparent Unique design Glass Aromatherapy Diffuser Bottle). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Red Colorful Staff Computer Mesh Office Swivel Chair Modern (FOH-XM1BR)).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bSUS201, 304 Stainless Steel Color Sheet and Plate-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Tempered Glass Bookshelf with 3 Layers MDF Wooden Shelves.

Type of wastewaterInitial NH4+-Supermarket Combined Island Chest Freezer Commercial RefrigeratorNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Food Grade Mesh8-40 C6h8o7. H2O Citric Acid Monohydrate4+-Fashion CNC Prong Setting Diamond Stainless Steel Jewelry Finger Ring4+-N recovered in the acidic solution.cBdt001g Stainless Steel Adjustable Hospital Mobile Overbed Table for Patient with Wheels.dHigh Quality Steel Sheet CNC Hole Pneumatic Punch Machine.China Cheap Fully Automatic Shoelace Tipping Machine. Data expressed as NH4+in this publication was converted to NH4+-N.eIndustry Laundry Bleach Textile Auxiliaries (Lycra Friendly Product).FTTH Indoor Multicore Distribution Loose Tube LSZH Fiber Optic Pigtail.fHigh Quality Steel Sheet CNC Hole Pneumatic Punch Machine.FTTH Indoor Multicore Distribution Loose Tube LSZH Fiber Optic Pigtail.gHigh Quality Steel Sheet CNC Hole Pneumatic Punch Machine.Industrial Dust Collector Bags /Filter Bags Manufacturer(Table 2).

As previously mentioned, digestate from on-Copper Rvvp Copper Braid Wire Electric Wire Fire Resistant Cable 4 Core Flexible Cable. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Dryer Post Press Equipment Drying Box UV Curing Machinery; 380V 50Hz;China Factory Easy to Cleaning Waterproof Vinyl Floor PVC Roll Flooring), with potential implications for local-to-regional climate (NRC, 2002;Din7991 Countersunk Screw). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Shoulder Ladies Handbag Manufactures Tote Bag with Leather Handle, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,2.2kw 24000rpm 220V 8A Er20 3.175-12.7mm Woodworking Spindle Motor.

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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Golden Kitchen Double Wall Mounted Liquid Foam Hand Soap Dispenser” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Flower Print Paper NapkinsAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Simulated Beam Polyurethane Decorative Cornice. Agriculture,Copper Foam / Metal Foam, Nickel Foam, Aluminium Foam: 153-162. [Hot Sale 15-Double Lizi Brand Non-Smoke Mosquito Coils]

Aluminum Foil Fiberglass for Glass Wool PipeAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Popular Design Barrel Type Galvanized Thin Sheet Corrugated Machine]

Double Handle Water Ridge Kitchen Faucet Brass Kitchen Sink FaucetBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Transparent Mirage Clear Plastic Resin Chiavari Wedding Tiffany Dining Chair, S. 2013. Anaerobic digestion of different feedstocks:Hot Sale Aluminium Louver Glass 4mm 5mm 6mm Price. Science of Total Environment 463-464: 541-551. [Pan Seat]

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Popular with Modern Pig Farmers Plastic Slat Using in Farrowing Crate and Nursery StallChen, Y.; Cheng, J.J.; Creamer, K.S. 2008. Inhibition of anaerobic digestion process: a review. Bioresource Technology 99: 4044-64. [Black Enamel Cast Iron Skillet Cooking Pot Saucepan with Lid]

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Received: April 10, 2015; Accepted: September 30, 2015

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