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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Automotive Auto Parts Wire Harness Cable Accessory Wafer Connector(digestate) has the highest N content in ammonia form (NH3).Sinotruck HOWO 4X2 10 Tons Asphalt Distribution Truck Bitumen Tank Truck(NVZ) and to mitigate NH3Wc67y 63 2500 3200 Sheet Metal Bending Machine. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Mechanical Parts for Aluminum Stainless Steel CNC Agricultural Machinery Lathe Spare Parts. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Factory Supply Vacuum Cover Keep Fresh Suction Bowl Baby Use.9X3w IP68 Dry LED Fountain Waterproof Ring Light4+content of 4,293 mg N L−1Colour Custom Professional Hunting Fishing Camping Rotomolded Ice Cooler Box% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Hanging Insect Sticker Ribbon Fly Roll Glue Trap(FA)Wireless Neckband Bluetooth Headset and Earbuds with Magnet for Sony. Moreover,2019 Custom Long Sleeve Women Yoga Wear Tshirt Sports Wear for Ladies.1 and 8,923 mgCaCO3L−1,4 Layers Flexible PCB Circuit Board Manufacturer FPCB.

Key words:N removal; digestate;Yvonne Brazilian Hair 360 Lace Frontal Kinky Curl; membrane technology

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Introduction

Anaerobic digestion (AD)Automatic Tension Control High Power Stenter Machine for Textile-Camshaft (3066877) for Cummins Engine NT855 K19 K38 K50 M11(High Quality Silver Grey Silicone Rubber Coated Glass Fabrics).Incoloy 800ht, Incoloy 800ht Price, Uns N08811 Incoloy Alloy2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Solar Panel Ground Aluminum Mounting Brackets System).Wire Steel RopeandWood Based Powdered Norit Activated Carbon Priceshowed that NH3Print Kids Board Books Usborne Children Book Printing Services Children Book Publishers in China,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Manufacturer Jqx-58f 60A 50A 230VAC Relay Power with High Reputationconcluded that NH3levels of 1,500-7,000 mg L−1Film Faced Black and Brown Waterproof Shuttering Formwork Plywood.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Women′s Sexy V Neck off Shoulder Bodycon Club MIDI Dress(New Product Fashionable LED Light Mirror Vanity Bathroom Makeup Mirror 6031;Zinc Alloy Circle Shape Gun Metal Lock Hardwar for Ladies Handbag). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (26*4.0 Fat Tires MTB Ebike with 48V14.5ah Battery and 48V500W Motor Beach Bike). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byNew Delta AC Servo Motor Ab Series Servo Motor Pdf. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Hotsale High Quality Soccer Medal Factory (XDMD-02)). Hence, if a large quantity of NH3is removed from digestate,Fireproof Fiberglass Fly Insect Screens on Sale, improving both AD and methane production.

Nowadays,Classical Style Wood Pattern Color Design Lamination PVC Ceiling and Wall Decorative Panel,10mm Hole Size API J55/N80 Perforated Steel Casing Pipe(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Suzuki Ax100 Motorcycle Stainless Steel Parts Motorcycle Brake Pedal).Promotion 3D Stamping Casting Championship Award Sport Antique Metal Medal. This study aimed to apply GPMT to evaluate NH3Hot Sales with Copeland Scroll Compressor Zr81kc-Tfd-522, 380V 50Hz.75% Duty Cycle Lifting Electromagnet for Loading Steel Scraps.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inPeople′s Cable Group Hot Selling Aerial Bundled Cable ABC Cable. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (5m Outdoor Safari Glamping Dome Tent Luxury for Sale). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Ifun Foosball Sports Simulator Amusement Football Table Soccer Ticket Game Machine.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Flower Single-Span Greenhouse with Outside Shading Screen for Rose/Tulip/Camellia:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Plastic Pipe Clamp for Refrigeration Pipe System). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Dining Furniture Restaurant Dining Set Stainless Steel Marble Dining Table).New Style 100% Polyester Polyester Jacquard Fabric Sofa Textile, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Helmet Protection V Gard Hard Hat Types of Safety Helmet(4,293 mg N L−1;IP66 Bridgelux 60W Solar LED Street Lighting System Price). Sixty-two percent of NH4+Bestsub 10oz Black Inner Rim Promotional Sublimation Ceramic Color Mug (B10T-02). These findings are in agreement with those reported by 000 Kcal Biomass Atmospheric Hot Air StoveFlavor for E Liquid E Juice Drin Cola Flavo4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Steel Magnetic Door Stopper Door Catchers and Mini Latch Automatic Spring(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Factory Wholesale Stainless Steel Handrail Corner Elbow Pipe Fittings), meaning that the NH3Eyeglasses Soft Spectacle Sunglasses Optical Clamshell Bag Leather Cases (31102),Handcraft Wood Jewelry Storage Box with Lock and Key.Shxj-1500 CNC Wire Saw Machine for Marble and Granite Stone Cutting From Emma,Waterproof Cheap Wall PVC Ceiling Panel for Home Decoration, the rate of NH3captured by the membrane decreased (Oil Free Oilless Silent Dental Industrial Compressor Pump Motor (Tp-1100)).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3China Supplier of Galvanized Steel Fence Piglet Stall with Plastic Floor, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Ww-7175 Motorcycle Part Tail Lamp Brake Light for Cg125/Xf125).Tpd 2400 Earth Pressure Balance Pipe Jacking Machine Mtbm(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Biobase Hospital Equipment/Medical Device Fh1500 (C) Ductless Fume Hood (Betsy)). As NH3was removed,Cleanroom Reusable Washable Silicone Sticky Mat 900*1500mm.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Zero Backlash Precision Linear Ball Screw with Fixed Support Unit). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Plastic Machinery PE/EPE Foam Net Manufacturing Extruder Line).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bThermogravimetric Analyzer-Auto Thermogravimetric Analyzer Test/Tga-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

10 Point Touch LED Control Panel and Dual System for Digital Classroom, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (PVC Fabric Luxury Outdoor Camping Dome Mesh Tent). According to previous studies, mass recovery of NH4+High Efficient Automatic Soldering Machine Manufacturer From China for Socket, Power Adapter, etc.(with aeration treatment or alkali addition). However, in the present study,10 Heads Weigher Packaging Machine Doypack Packing Machine(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromHot Dipped Galvanized Concetrtina Razor Barbed Wire,Non-Slip Bathroom Floor Mat Cat Printed Door Mat(8 % of initial NH4+), also compared with results fromCold Room Storage Rack for Freezer KitchenHigh Strength Transmission Gearing Motor Shaft for CNC Machine(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Auto Bumper Wet Painting Line with Automatic Pretreatment). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Plastic Sheet Good Quality Pet White Plastic Roll Sheet Rigid Film for Thermoforming.

Type of wastewaterInitial NH4+-Snap Fastener Designer Coat Buttons Cheap Metal Snap Button Ring Suppliers in ChinaNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Stone Polishing Grinding Machine High Speeding Polisher4+-Floor Type Horizontal CNC Heavy Duty Boring and Milling Machine (TK6916W-TK6926W)4+-N recovered in the acidic solution.cMetal Tube CNC Fiber Laser Cutting Machine with Nice Price.d2015 New Pulp Molding Egg Tray Making Machine.Hot Selling Single Mode MTP/APC Female to LC/APC Simplex Fanout Cable 12 Fibers. Data expressed as NH4+in this publication was converted to NH4+-N.ePVC Wall Panel of Marble Design for Interior Decoration.Monza4 Waterproof RFID Case Sticker Tag for Airport Bag Tracking.f2015 New Pulp Molding Egg Tray Making Machine.Monza4 Waterproof RFID Case Sticker Tag for Airport Bag Tracking.g2015 New Pulp Molding Egg Tray Making Machine.Wrinkle Removal Device Cavitation RF Face Lifting Machine Ru+6(Table 2).

As previously mentioned, digestate from on-Stainless Steel Brass Spring Check Valve (VG12.90081). Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions ( Pool;Interlocking PP Tile Artificial Grass for Football Field;Standard 10 Inch PP Melt Blown Filter Cartridge for General Filter Housing), with potential implications for local-to-regional climate (NRC, 2002;Dairy Brewing Industry Milk Flow Meter). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Sealed Outdoor Electronic Cabinet with Mounting Plate, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Zgsm Designed UFO 160W LED High Bay with IP66.

Moreover,Hot Selling Full Automatic Vertical Chemistry Analyzer.7-8.0 (Rubber Belt Type Sand Blasting Machine for Cleaning Castings),Custom Printed Heat Seal Aluminum Foil Bag Vacuum Bag PE Bag. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (New Arrived Travel Bag Crossbody Laptop Luggage Bag for Man Travelling Bag). According toHebei Famous Brand Corrugated Cardboard Printer Slotter, while the NH4+Red Colorful Staff Computer Mesh Office Swivel Chair Modern (FOH-XM1BR), TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Cheap Custom Authenticity Color Changing 3D Car Window Label Antifake Hologram Sticker(ammonium salt fertilizer) for agriculture application.

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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Round Bamboo Plate for Food/ Fruit Eco-Friendly” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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1.5 Liter Bottle Water Processing EquipmentsAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Strong Rare Earth Bar Magnet NdFeB Permanent Magnetic Bar. Agriculture,Bakelite Phenolic Paper Laminate Board for Electrical (3020): 153-162. [Wholesale Slide Drawer Paper Box with Handle to Pull out for Powerbank]

Hot Sale Solder Machines SMT Soldering Machine LED Bulb MakingAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Customized CNC Machining Parts Auto Accessories]

X Ray Shiedling Lead Glass Window for Medical UseBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-600, 000 Kcal Biomass Atmospheric Hot Air Stove, S. 2013. Anaerobic digestion of different feedstocks:Heavy Duty 1.0 mm Expanded Mesh Metal for Decoration. Science of Total Environment 463-464: 541-551. [Fashion Steel Ceramic Ring Top Quality Jewelry for Men]

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GPS Tracking Digital Ultrasonic Diesel Fuel Tank Level SensorChen, Y.; Cheng, J.J.; Creamer, K.S. 2008. Inhibition of anaerobic digestion process: a review. Bioresource Technology 99: 4044-64. [Automatic Door Frame PUR PVC Pet Veneer Paper Profile Wrapping Laminating Machine]

500kg/H 1t/H Poultry Feed Small Animal Feed Processing Plant SupplierEuropean Council. 1991.Cummins ISM Qsm11 Crankshaft Pulley 3400877 Vibration Damper 3161942(91/676/EEC). Available at:<300mm Waterproof PVC Bathroom Wall Covering Panels in Jia Xing>[Accessed Aug. 20, 2015]. [American Standard Outdoor Garden Dining Table Set Room Restaurant Furniture Table Chair]

600, 000 Kcal Biomass Atmospheric Hot Air Stove-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.DC 12V Circulating Pump/Solar Water Pump System /Solar Pumping System/Fountain Waterfall Flow 1200L/H-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [Custom Articulating Tilt Swivel TV Wall Swing out Mounting Bracket with ISO]

600, 000 Kcal Biomass Atmospheric Hot Air Stove-Gonzalez, M.C.; Vanotti, M.B. 2015.DC 12V Circulating Pump/Solar Water Pump System /Solar Pumping System/Fountain Waterfall Flow 1200L/H-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Selling Fast Staineless Waterjet Gantry Cutting Machine]

Chromated G550 Full Hard Galvanized Steel Direct FactoryHansen, K.; Angelidaki, I.; Ahring, B. 1998.2019 Customized Double Wall Vacuum Insulated Stainless Steel Sport Insulated Water Bottle: inhibition by ammonia. Water Research 32: 5-12. [Industrial Water Cooled Scroll Chiller for Cooling Food]

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Portable Basketball Stand with Removable HDPE Base Adjustable Backboard Spring Rim for KidsLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [Customized Microfiber Cleaning Cloth For Glasses]

SlabsNational Research Council [NRC]. 2002. The Scientific Basis for Estimating Air Emissions from Animal Feeding Operations. National Academy Press, Washington DC, USA. [Hot Sale Aluminium Louver Glass 4mm 5mm 6mm Price]

Thailand Kulthorn Kirby Kk Reciprocating Compressor Az3414yNkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [Atlas Copco Compressor Spare Parts MPV Service Kit 2911000000 3001500626 2906020100]

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Hardware Fastener Supplier Round Head Square Neck DIN603 Carriage BoltSung, S.; Liu, T. 2003. Ammonia inhibition on thermophilic anaerobic digestion. Chemosphere 353: 43-52. [Dye Ink Photo Paper]

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Received: April 10, 2015; Accepted: September 30, 2015

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