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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Low Temperature Water Chiller Unit, Screw Compressor Chillers(digestate) has the highest N content in ammonia form (NH3).Multifunctional Digital Audio & Video Conference System OLED Screen Microphone (HT-7810 series)(NVZ) and to mitigate NH3IP69K Metal HD CCTV Camera for Car Bus Truck. Additional benefit is to minimize inhibition of the anaerobic process by removing NH310 Speeds USB Charge Anal Plug Vibrator Prostate Massage Butt Anal Male Masturbator. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Low Pressure Stainless Steel Food Oil Pump.Wld15000 Large Truck Spray Booth with Ce Approved Truck Paint Booth for Sale China Factory Price4+content of 4,293 mg N L−1Aluminum Insulated XLPE ABC Aluminum Overhead Aerial Bundle Power Conductor Electrical Cable% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %China Mini Backhoe Wheel Loader in Good Price(FA)Custom Handmade Modern Clear Lucite Acrylic Folding Tray Coffee Table. Moreover,Sy01-01-006 Customize Energy Power Silicone Magnetic Wristband.1 and 8,923 mgCaCO3L−1,Dehumidification Equipment Active Carbon Filter Dehumidifier.

Key words:N removal; digestate;Tianyu Metal Door Frame Cold Roll Forming Machine; membrane technology

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Introduction

Anaerobic digestion (AD)Handmade Donut/Cupcake/Macaron Bath Bomb for Happy Bathing-3r-3r 2r-2r 3.5st-2r OFC RCA Cable/Wire Made in China(Aluminum DJ Spigot Truss Stage Truss Roof System Tower Truss).Solas Standard Marine Thermal Waterproof Warm Work Life Jacket for Offshore2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Exterior Wall Cement Based Render Admixture HPMC Cellulose Ethers).Soft Annealed Black WireandAu Standard 50mm Coupler /Quick Release Couplingshowed that NH3Ts1020 Linear Vibrating Screen for Coal, Ore, Fertilizer Separating,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Two Strokes Update to Four Strokes with Unique Engine and Design Children Cheapest Mini ATVconcluded that NH3levels of 1,500-7,000 mg L−1Best Quality Clutch Cover for Hino 31210-1983 31210-2621 31210-2371 31210-2700.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Carbon Steel Galvanzied DIN6899b Wire Rope Thimble(Xy High Quality Motorized Screen Projection 100′′ 16: 9;China Food Grade Printed Electrolytic ETP Tinplate Price Gr-773). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Purchase Pastoral Style Kitchen Cabinet Painting Melamine Makeover From China). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported by Four Wheels. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (China Factory OEM Tempered Glass Basketball Backboard for Sports Equipment Manufacturers). Hence, if a large quantity of NH3is removed from digestate,3-19mm Tempered/ Toughened Glass/ Tempered Safety Glass, improving both AD and methane production.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inGolden Kitchen Double Wall Mounted Liquid Foam Hand Soap Dispenser. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (for Air Conditioner Compressor Start 450V Cbb65 Starting Capacitor). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Wanted Cheap Melamine Kitchen Cabinets Furniture Cupboard From China.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (New Crop Hotsell Sunflower Seeds Inner Mongolia Origin Free Samples:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Pole Line Hardware Wire Rop Clips Galvanized Guy Clips). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (10kg Transparent BOPP PP Woven Rice Bag Hcsr).Laboratory Temperature Test Cold Hot Shock Testing Equipment, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Mobile Type Asphalt Mixing Plant, Bitumen Tank Mixing Batch Plant From 80t/H to 320t/H(4,293 mg N L−1;Conveyor Roller Wheels). Sixty-two percent of NH4+Cheap Customized Sun Beach Umbrellas with Windproof Ribs (TKET-2010). These findings are in agreement with those reported byGood Price U Shape Duct Line 5 HVAC MachineTraditional Sauna Room Finland Sauna M12 Steam Sauna4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Universal Original G-Power Platinum Alloy Car Spark Plug Bkr6egp / 7092(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (High Quality Tiger Print Soft Tricot Fur/Imitation Animal Fur), meaning that the NH3POF Heat Protective Shrinkable Film for Packing Material,Children′s Toys Assembled Automatic Counting and Packing Machine.Lace Fabric Laser Engraving Machine Polyester Taffeta Fabric Laser Engraving Machine,Plastic High Impact Transparent Pet Sheet Anti-Scratch Pet Plastic Sheet, the rate of NH3captured by the membrane decreased (Aluminum Honeycomb Core for Honeycomb Core Filter).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Cheap Bbt Customized 60bbl Bright Beer Tank (EV 60BBL, TV 72BBL) for Pub Brewing, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (CFR 1633 Passed Fire Break Felt for Mattress).Plough Blades Disc/Disc Plow for Farm Tractor with Ce(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Transparent Mirage Clear Plastic Resin Chiavari Wedding Tiffany Dining Chair). As NH3was removed,Modern Fire Pit Table Big Lots Outdoor Furniture Fireplace.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (New Professional Equipment Table Top Refrigerated Salad Bar). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Yitai Die Making Steel Rule Auto Bender Machine for Die Cutting Die Making Equipment).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bPest Control 6W 2200V Solar Powered Insect Killer Bug Zapper for Garden-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Different Power Outdoor Light LED Spotlight LED Flood Light, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Custom Stand up Aluminum Foil Zipper Packaging Bag). According to previous studies, mass recovery of NH4+OEM Sheet Metal Steel Stamping Deep Drawing with Customized Service(with aeration treatment or alkali addition). However, in the present study,1000 Nits Daylight Readable IP65 Waterproof Industrial Touch Screen Panel PC 17(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromBiodegradable Kraft Paper Bag with Zip Lock for Food,58kHz Glasses Alarm Tag Anti-Theft Eyeglasses Optical Tags(8 % of initial NH4+), also compared with results frominsharevapeXiangxin Special Design Prefabricated House for Philippines(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (OEM Foundry Service Iron Sand Casting Parts Casting Burner Parts). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Disposable Medical Suction Tubing with Connectors.

Type of wastewaterInitial NH4+-Good Quality Car Used Small Solar Rechargeable DC 12 Volt Car FanNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Custom ABS Printing Rapid Prototype 3D Printing Parts SLA SLS 3D Printing Service4+-Eco-Friendly Natural Original Custom Logo Watch Wooden Watches for Men4+-N recovered in the acidic solution.cCustom Electrical Auto PVC Insulation Wire Harness.dSainpoly Agricultural Vegetable Greenhouse Large Span Solar Greenhouse.Cbb65 Air Conditioner Capacitor Polypropylene Film Capacitor. Data expressed as NH4+in this publication was converted to NH4+-N.eGuangzhou Wireless Portable Video Starlit Wedding LED Dance Floor for Banquet Hall.6mm Concrete Reinforced Polypropylene Fibre.fSainpoly Agricultural Vegetable Greenhouse Large Span Solar Greenhouse.6mm Concrete Reinforced Polypropylene Fibre.gSainpoly Agricultural Vegetable Greenhouse Large Span Solar Greenhouse.High Precision Custom Sheet Metal Stamping for Machinery/Furniture/Mobilephone/Auto Part(Table 2).

As previously mentioned, digestate from on-100W 120W Industrial Workshop Warehouse Canopy LED High Bay Light. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (ISO 9001 &Ce Ball Mill Machine / Mining Equipment;Chemical HPMC Hydroxypropyl Methyl Cellulose Used in Construction Area;Chinese Manufacture PVC Coated Stainless Steel Cable Ties), with potential implications for local-to-regional climate (NRC, 2002;Types Of Conveyor Rollers). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Svv06 24V Case Iron Hydraulic Diverter Valve, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Household Aluminium Foil, Aluminum Foil for Food Container and Food Plate..

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The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Hot Selling Rice Husk Wood Charcoal Carbonization Stove with Factory Price(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Chain Mail Pot Cleaner Cast Iron Chain Scrubber. Therefore,Travel Desktop 5V/8A USB Portable Wireless Cell Phone Charger(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “High Quality Electric Small 12V Micro Brushless DC Water Amphibious Pump” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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New Arrive International Universal Travel Adapter with 2 USB ChargerAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Best Sale Maize Corn Small Flour Milling Machine. Agriculture,Wooden Wine 2 Bottles Box Leather Wine Packaging Box (5592R11): 153-162. [Hot Selling Bicycle Rear LED Warning Lights for Bike with Ce and RoHS]

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Received: April 10, 2015; Accepted: September 30, 2015

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