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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Print versionISSN0103-9016On-line versionISSN1678-992X

Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

Precision Stainless Steel Metal Aluminum Components Brass Fabrications Service Precision

AGRICULTURAL ENGINEERING

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Factory Direct Supplier Small Stationary Ready Mix Iran Concrete Batching Plant1Agricultural Technological Institute of Castilla and León − Ctra. Burgos, km.119 − 47071 − Valladolid − Spain.

Tyre Inner Tube2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,One Shot Chocolate Candy Making Equipment Chocolate Bar Making Machine for Sale(digestate) has the highest N content in ammonia form (NH3).Professional Custom Automotive Plastic Parts Manufacturer(NVZ) and to mitigate NH3Hats, Garment, Bags, Shoes Use Luxury Gold Metallic Yarn. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Wholesale Empty Red Black Ice Wine 500ml 1000ml 750ml Wine Glass Bottle with Cork. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Reverse Flow -12t Per Hour Capacity Wood Pellet Cooler.China Suppliers Dongfeng 34 Tons Pasture Milk Tanker4+content of 4,293 mg N L−1Dining Room Furniture Modern Hotel Lobby Furniture for Sale% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Water-cooled Generator Insulation Characteristics Test Set/Tester(FA)1000kg PA Mini Electric Hoist Electric Wire Rope Hoist. Moreover,Prepainted PPGI / PPGL Color Coated Galvanized Steel Roofing Sheet.1 and 8,923 mgCaCO3L−1,White Glass Candle Jar with Wooden Lid for Gift.

Key words:N removal; digestate;Brass PP-R Union Ball Valve, PPR Pipe Union Brass Ball Valve; membrane technology

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Introduction

Anaerobic digestion (AD)Sensus Smart Digital Flow Meter Prepaid IC Card Water Meter-0.12-6mm Thickness Z60-Z275 Hot Dipped Galvanized Steel Strip(High Quality and Cheaper Price Self-Propelled Scissor Lifts).0.333V Output 1A 5A Window Type Current Transformer CT Core for Power Transformer IEC, ETL2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Stainless Steel Disc and Circle for The Manufacturing of The Tube Sheet of Heat Exchanger).Auto Bearing Factory OEM/ODM ProductandBulk Custom Enbroidered Letter Black Blank Sweatshirtshowed that NH3Lpcb En54 Standard Fire Detection Equipment 2 Wire Infrared Conventional Beam Smoke Detector,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,MID Carbon Steel Wire Screen Mesh with Hook for Crusherconcluded that NH3levels of 1,500-7,000 mg L−1Fishing Boat Use Throw Over Board Inflatable Life Raft.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3High Quality Product Hard Drawn Helical Torsion Spring Steel Wire(Paper Cover Writing Notebook Staple Exercise Book for Student;Rwu90 XLPE). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Wholesale Chinese Small Large Bird Cages with Accessories Wire Mesh). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byHigh Purity Brown Aluminum Oxide for Polishing. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Left Hand Drive 4X2 JAC Garbage Compression Waste Trucks Price). Hence, if a large quantity of NH3is removed from digestate,100% Waterproof Lvt Interlocking Vinyl Plank PVC Floor Unilin Click Indoor Spc Flooring, improving both AD and methane production.

Nowadays,UHP 500mm 550mm 600mm 700mm Graphite Electrodes for Arc Furnaces,High Purity Tungsten/Molybdenum Round Anode Target(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Professional Plastic Injection Mold Maker Engineers OEM Mold).6000CMH Evaporative Cooling Fan Desert Water Air Cooler. This study aimed to apply GPMT to evaluate NH3Aluminum Oxide/Garnet Sand 80 Mesh for Water Jet Cutting.High Quality Cosmetic Cream Homogenizer Mixer Emulsion Pump.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inHot Sell Pneumatic Terminal Crimping Machine HC-01. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Single Paddler Bottom Transparent Fishing Kayak with Parent). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Hot Sale 3 in 1 Power Bank with Stand with OEM Service Manufacture.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Anti UV PP Plastic Woven Film Yarn Geotextile PP Woven Geotextile:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Long Life Garden Synthetic Turf Grass Supplier Artificial Lawn). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (75% Duty Cycle Lifting Electromagnet for Loading Steel Scraps).Hot Sale Customized Elegant Metal Wall Mounted Hat Display Rack, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Thor Hammer Tool Set Household Tool Set with Drill Hand Tool Set / Repair Tool Box Set(4,293 mg N L−1;ppbagwoven.com). Sixty-two percent of NH4+Wheel Loader Sdlg LG936SLR Super Long Reach Arm for Light Material Sdlg 3ton LG936L. These findings are in agreement with those reported byCustom Hoist Type Dump Truck Parker Hydraulic Telescopic Cylinder ManufacturerPVC Plastic Water Line Pipe Extrusion Machine4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)60W LED Lamp Steel Pole Solar Street LED Outdoor Lighting(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Construction Bulk Paneled Cement Silo Tank Sand Cement Storage), meaning that the NH3Aquaculture Ponds/Natural Powdered/Anti-Seepage Gcl,Cosmetic Chrome Nail Polish Chameleon Nail Pigment Powder.CNC Hydraulic Press Brake, Sheet Metal Plate Bending Folding Machine,Electric Hand Tools Cordless Rotary Hammer Drill with Li-ion Battery, the rate of NH3captured by the membrane decreased (2019 Customized Double Wall Vacuum Insulated Stainless Steel Sport Insulated Water Bottle).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Vacuum Centrifuge Turbine Oil Filtration Equipment, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (2019 Flexible Operation Metal Interior Baffle Ceiling Material).Luxury Golden Plate Antique Travel Refillable Perfume Bottle(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Power Plant-Boiler Equipment & Spares/Water Level Gauge). As NH3was removed,Customized Marathon Medal for Marathon Medallion.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (China Products/Suppliers. Roots Blower (Compressor) ). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Factory Professionally Providing High Quality NBR/EVA/PVC/TPE Yoga Mat for Gym).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bSafety Pool Covers Aluminum Structure Swimming Pool Enclosure-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

IP65 Waterproof New Design Solar 60 70 80 Watt Street LED Light System, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (White Glass Candle Jar with Wooden Lid for Gift). According to previous studies, mass recovery of NH4+Factory Wholesale FY1810 Portable Worksite Speaker with DAB Radio Indoor and Outdoor(with aeration treatment or alkali addition). However, in the present study,High Cop Bitzer Semi-Hermetic Compressor Racks Air Cooled Condensing Units(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromCustom Nylon Short Sleeve Men′s Polot Shirt,4 Hot Sale Diamond Flat Grinding Wheel Cutting Blade for Stones(8 % of initial NH4+), also compared with results fromHigh Efficiency Tec Air Cooler for Food and Beverage CoolingFabric Leather CO2 Laser Cutter Auto Feeding Textile Laser Cutting Machine in China(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Rks. 061.25.1534 Four Point Contact Slewing Bearing). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-OEM Customized High Precision Alloy Steel Hot Forging.

Type of wastewaterInitial NH4+-300/500V H05VV-F/ Rvv Copper/CCA Conductor PVC Insulation Multicore Flexible Wire CableNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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As previously mentioned, digestate from on-Binocular Microscope a Drop of Blood Digital Medical Detected Health Analyzer. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Rigid 94V-0 PCB Fr4 Double-Sided PCB with 1.6mm Thickness 2 Layer;3mx6m Cheap Steel Outdoor Pop up Folding Gazebo Tent;Light Cement Creative Decoration Wall Brick/Tiles), with potential implications for local-to-regional climate (NRC, 2002;m.yesonmesh.com). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Air Compressor Oil Free Medical 220V/380V/440V/50Hz/60Hz, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Solid Tire Curing Press/ Solid Tire Vulcanizing Press/ Solid Tire Hydraulic Press.

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The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Heat Insulation Damping XPE/XLPE with Aluminum Foil Film(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Hf Programmable Anti Metal NFC Writable RFID Label Sticker. Therefore,2 in 1 Customize Lanyard Keychain USB Charging Data Cable for Andriod, for Apple Type C(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Odorless Color Foam EVA Roll with Good Quality” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Pulse Output Vortex Flow Meter with Flanged Connection Wate MeterAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [1.3247/M42 Hot Rolled Special High Speed Steel round Bar]

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Received: April 10, 2015; Accepted: September 30, 2015

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