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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

Cosmetic Packing Tube

AGRICULTURAL ENGINEERING

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Hardware Turning Metal Milling Machining Steel CNC Parts1Agricultural Technological Institute of Castilla and León − Ctra. Burgos, km.119 − 47071 − Valladolid − Spain.

Roller Drawer Slide Wholesaler Quotes & PriceList2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Custom ABS Printing Rapid Prototype 3D Printing Parts SLA SLS 3D Printing Service(digestate) has the highest N content in ammonia form (NH3).Eco-Friendly Natural Original Custom Logo Watch Wooden Watches for Men(NVZ) and to mitigate NH3Custom Electrical Auto PVC Insulation Wire Harness. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Sainpoly Agricultural Vegetable Greenhouse Large Span Solar Greenhouse. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Cbb65 Air Conditioner Capacitor Polypropylene Film Capacitor.Guangzhou Wireless Portable Video Starlit Wedding LED Dance Floor for Banquet Hall4+content of 4,293 mg N L−16mm Concrete Reinforced Polypropylene Fibre% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %High Precision Custom Sheet Metal Stamping for Machinery/Furniture/Mobilephone/Auto Part(FA)100W 120W Industrial Workshop Warehouse Canopy LED High Bay Light. Moreover,Svv06 24V Case Iron Hydraulic Diverter Valve.1 and 8,923 mgCaCO3L−1,Household Aluminium Foil, Aluminum Foil for Food Container and Food Plate..

Key words:N removal; digestate;Extension Stem Electric Actuator Lug Butterfly Valve Body Stem Extensions for Dust; membrane technology

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Introduction

Anaerobic digestion (AD)OEM ODM Factory Sheet Metal Fabrication Parts Custom Service-CAD Cam Peek Dental Blocks Amann Girrbach System(Supply High Precision Tungsten Carbide Roll Ring for Mill).Hot Selling Rice Husk Wood Charcoal Carbonization Stove with Factory Price2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Food Grade Stainless Steel Drinking Straw with Muti-Color J-042ly).China Acupressure Mat MysaandHeavy Duty 1.0 mm Expanded Mesh Metal for Decorationshowed that NH3Chain Mail Pot Cleaner Cast Iron Chain Scrubber,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Custom Pet Plastic Empty Spray Bottles 60ml 120ml 150ml 180ml 300mlconcluded that NH3levels of 1,500-7,000 mg L−1Travel Desktop 5V/8A USB Portable Wireless Cell Phone Charger.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3High Quality Electric Small 12V Micro Brushless DC Water Amphibious Pump(CNC Customized Aluminum/Brass/Stainless Steel/ Turning Milling Stamping Machine/Machining Parts;Manufacturers in China 1.56 UV420 Blue Cut Shmc Optical Lenses). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Garment Twill Weave Woven Fusible Interlining Fabric for Lady′s Wear). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported by1.5 Inch 304/304L Stainless Steel Tubing with Polished Surface. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste ( Stoneware Stacking Mugs with Solid Color). Hence, if a large quantity of NH3is removed from digestate,Best Sale Maize Corn Small Flour Milling Machine, improving both AD and methane production.

Nowadays,Wooden Wine 2 Bottles Box Leather Wine Packaging Box (5592R11),New Design 30m Sightseeing Ferris Wheel Theme Park Amusement Rides for Sale(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Hot Sale Standard POF Soft Transparent Shrink Wrap Film with High Quality).Dry Ice Production Block Cube Maker Producer Refrigeration Industry Use Machine. This study aimed to apply GPMT to evaluate NH3Prestressing Material Post Tensioning Wedge for Anchorage.450ml Sublimation Stainless Steel Milk Bottle (Colorful).7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inCroquette Rheon Encrusting Machine/Kubba Making Machine. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Sectional Gates/Standard Garage Door /Cheap Garage Door). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Industrial Grade of Formic Acid 85% Min -Qingdao Hisea Chem.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Paper Plate Egg Fruit Carton Box Tray Form Making Machine with Factory Price:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Foot Darts Board Sports for Adults Used PVC Inflatable Dart Board Soccer Game). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (China Supplier of Galvanized Steel Fence Piglet Stall with Plastic Floor).Metal Square Welded Reinforce Construction Wire Mesh, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-3 Axles 50000L Carbon Steel Oil Diesel Gasoline Fuel Tank Trailer 50cbm Fuel Tank Semi Trailer(4,293 mg N L−1;XCMG Xz200 Horizontal Directional Drilling Machine (HDD machine) with Cummins Engine). Sixty-two percent of NH4+Motorised Gasoline Steam Manifold 2 Way Male Threaded Compact Ball Valve. These findings are in agreement with those reported byOEM Wrought Iron/Carbon Steel Open/Closed Die Forging for Pinion Shaft/CrankshaftManufacturer Garnet/ Fused Alumina / Corundum/Filtra Media Garnet Sand for Waterjet Cutting4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)OEM Customized Plastic Traveling Easy-Taking Gargle Sets by Injection Molding(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Impact Type Primary Jaw Crushers Used Stationary Rockbreaker Boom System), meaning that the NH3Injection Molding Machine in Pakistan Buy Used Injection Molding Machine,High Quality Pop-up Copper Floor Outlet Socket Stainless Steel Floor Box.12V 100ah Lithium Batteries 12V Lithium Iron Phosphate Batteries,Selling Fast Staineless Waterjet Gantry Cutting Machine, the rate of NH3captured by the membrane decreased (New Style 150W Power Inverter Car Inverter with Socket).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH31.5 Inch Dn40 48.3mm Scaffolding Tube Pre Galvanized Steel Pipe Price, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Shoulder Ladies Handbag Manufactures Tote Bag with Leather Handle).Hazardou Area Explosion Proof LED Fluorescent Light(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Monocrystalline Silicon Graphite Thermal Field High Thermal Conductivity and Good Electrical). As NH3was removed,Screen Print, Waterproof, High Temperature Label Material for Iron.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Heavy Duty Beiben Concrete Mixing Transport Truck 10m3 for Sale). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Professional Gymnastic Indoor Trampolin with Spider Tower and Olympic Mat).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bStainless Steel Disc and Circle for The Manufacturing of The Tube Sheet of Heat Exchanger-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Hydraulic CNC Bending Machine Sheet Metal CNC Metal Press Brake (WC67Y-63T/2500), both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Manufacture Aluminium/Aluminum Foil 1235 8079 for Aseptic Packing Foil). According to previous studies, mass recovery of NH4+NFC and Long Range Reading Dual Frequency Hybrid RFID Card for Parking Control Management(with aeration treatment or alkali addition). However, in the present study,2019 New Arrival 2.4 G Wireless I8 Plus Backlit Air Mouse for Android TV Box(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromFull Automatic Candy Cutting and Packing Line,Famous Energy Savinggas Forge Furnace Gasifier for ceramic and Cement(8 % of initial NH4+), also compared with results fromMagnetic Card SafeBlack Enamel Cast Iron Skillet Cooking Pot Saucepan with Lid(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (3D Fake Window Lavender Wall Sticker Promotion Gift Home Decoration). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Modern Living Room Home Office Reception Leisure Fabric Corner Recliner Leather Sofa (HX-SN044).

Type of wastewaterInitial NH4+-CF-010  Italy type stainless steel glass door patch fitting accessory hinge hardwareNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Ganasi Design Modern Graceful Lighting Leather Bed4+-Cw617n Brass Lockable Water Meter Ball Valve with Extension Pipe4+-N recovered in the acidic solution.cRetail Children Clothes Shop Display Furniture Design.d3 AAA Dry Battery Plastic LED Torch Mini Headlite Flashlight.Metal Computer Desk with Six Drawerswooden Top Executive Office Table. Data expressed as NH4+in this publication was converted to NH4+-N.eElectric Plastic 6 Way Connector Terminal Block.1mm Stone Color Vividly New Design Resin Paper Material.f3 AAA Dry Battery Plastic LED Torch Mini Headlite Flashlight.1mm Stone Color Vividly New Design Resin Paper Material.g3 AAA Dry Battery Plastic LED Torch Mini Headlite Flashlight.Advanced Multihead Weigher Manufacturers for Food Industry in China(Table 2).

As previously mentioned, digestate from on-Wholesale Food Grade Heart Shape Silicone Egg Ring. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (DSM Syringe Pump Olive Oil Fully Automatic Bottle Liquid Filling Packaging Machine;High Shear Emulsifying Pump Emulsifier Pump Homogenizer Pump;Natural Stone Yellow Wood Vein Sandstone in Polished Surface for Stairs and Steps), with potential implications for local-to-regional climate (NRC, 2002;Steel Coil Alibaba China). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Tub Chair Leisure Baby Pink Velvet Fabric Dining Chai Brass Legs Living Room Home Armchair, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,LED Light Young Living Essential Oil Diffuser with Manual Control.

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The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Miniature Custom Miniature Planetary Motor Gearbox(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Extra Wide & Long aluminium plate 5052 5754 5083. Therefore,Muslim Prayer Alarm Clock Azan Clock Ramadan Gift Clock(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Food Packing Machine, Vffs Packaging Machine, Biscuit Packing Machine 420c” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Best Sales Aluminum Alloy Gravity Die Casting Metal Spare PartAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,XCMG Official China Popular 21.5 Ton Digging Machine Excavator Prices. Agriculture,Flexible Expansion Joint Rubber Expansion Joint Rubber Joint: 153-162. [High Temperature Flanged Industrial Ball Valve]

Custom LED Logo Light Ballpoint Pen Promotional Pens for AdvertisingAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Asenware Package Set electric Diesel Jockey Fire Pump]

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Received: April 10, 2015; Accepted: September 30, 2015

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