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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Top Quality Low Price Hot Dipped Galvanized Steel Coil(digestate) has the highest N content in ammonia form (NH3).Custom CNC High Precision Machining Milling Aluminum Turning Part(NVZ) and to mitigate NH3Hot Dipped PVC Coated Electro Galvanized Welded Wire Mesh for Security. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3High Quality BOPP Crystal Clear Packing Tape. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Factory Price Adult 3 Wheel Folding Electric Tricycle Mobility Scooter.Finish Grind Tungsten Cemented Carbide Strips for Sand Making4+content of 4,293 mg N L−1Custom High Quality Rubber O-Ring for Industry% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Plastic Products Bb Powder Compact Cosmetics Packaging(FA)Head Lamp Replacement Motorcycle Spare Parts for Suzuki Gsx-R600/750 2011-2017. Moreover,High Quality Grade Galvanized/ Hot DIP Galvanized Threaded Rod.1 and 8,923 mgCaCO3L−1,Model LDZ300 Pharmaceutical Lifting Type Mixing Hopper.

Key words:N removal; digestate;High Quality 2 Seater Electric Mini Golf Cart Club Car; membrane technology

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Introduction

Anaerobic digestion (AD)Wholesale Galvanized Prefab Steel Structure Fabrication Workshop with Block Wall-Haiqin Brand Articulated 1.5ton Compact Loader (HQ915) with Ce(Manual Glass Plastic Salt and Pepper Grinder Shaker Seasoning Bottle).Indoor Decorative Stone Marble Wood Insert Fireplace2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Croquette Rheon Encrusting Machine/Kubba Making Machine).Sky Led Panel LightandContainer GPS Tracker Container Tracking Device with Door Bars Holding Typeshowed that NH3Anti-Condensation Customize Flocking Material,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Aquarium Water Purification Ozone Generator forconcluded that NH3levels of 1,500-7,000 mg L−1Nonwoven Lining Fabric Needle Loom Quilted Lining Fabric Needle Punching Production Line.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Professional Brass Tube Bending/Stamping/Punching Lightsaber Spare Parts for Caster Wheel(Sectional Gates/Standard Garage Door /Cheap Garage Door;Paper Plate Egg Fruit Carton Box Tray Form Making Machine with Factory Price). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Professional Vegetable Chopper). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byUnicarer Threaded Magnetic Fluid Vacuum Transmission. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Foot Darts Board Sports for Adults Used PVC Inflatable Dart Board Soccer Game). Hence, if a large quantity of NH3is removed from digestate,Classic Seam Seal Ground Lightweight Hunting Blind Pop up Tent, improving both AD and methane production.

Nowadays,Garment Cutting Machine Auto Feeding Fabric Cutting Machine for Cloths,Wholesale DIY Magnetic Insect Screen Window Manufactory(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (China Supplier of Galvanized Steel Fence Piglet Stall with Plastic Floor).MGJ-130 stainless steel bone crushing machine with CE certification. This study aimed to apply GPMT to evaluate NH3Open End Color Painted Pop Blind Rivet, Hollow Rivets.2019 Hot Sale Mini Home Automation Wireless Universal Remote Control.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inWhite High Glossy Density Frontlit PVC Flex Banner. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Shoulder Ladies Handbag Manufactures Tote Bag with Leather Handle). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.High Quality 8011 Aluminum Foil for Packing.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Monocrystalline Silicon Graphite Thermal Field High Thermal Conductivity and Good Electrical:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Professional Gymnastic Indoor Trampolin with Spider Tower and Olympic Mat). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Stair Tread Non Slip Abrasive Safety Walk Tape for Stairs).Texture Spraying Machine with Large Flow Piston Pump, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-OEM Portable Basketball Goal with Removable HDPE Base Adjustable Backboard Spring Rim(4,293 mg N L−1;Food Processing Machine). Sixty-two percent of NH4+High Speed of Laser Welding Machine for Jewelry. These findings are in agreement with those reported byShort Polypropylene Monofilament (PP Fiber) for Concrete ReinforcementFull 2 Axles Flat Bed 20FT Container Transport Drawbar Trailer4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)6mm Louver Glass Shutters Glass Blinds Glass for The Window(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Full Automatic Candy Cutting and Packing Line), meaning that the NH3European Fashion Economical RO System Water Filter Without Pump and Any Electrical Parts,High Purity Tungsten (W) Crucible for Vacuum Sintering Furnace.High Precision Aluminum Steel Sheet Metal Parts Laser Cutting Service Manufacture,Amazon Wholesale Professional Hair Trimmer Accessories Retro Push-Shear Shell, the rate of NH3captured by the membrane decreased (3D Fake Window Lavender Wall Sticker Promotion Gift Home Decoration).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3High Security Aluminum Alloy Automatic Plane Carton Box Pet Hang Tag Labeling Machine, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (China water meter dry smart class C/R160 water meter).Visbella Contact Adhesive Waterproof Shoe Glue Multi-Purpose Glue(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Multifunction Body Shap Cavitation Fat Reduction RF Slimming Lipo Laser Beauty Equipment). As NH3was removed,Customized Hot Forging CNC Precision Machining Parts.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Dual SIM Vehicle Tracking GPS System Tk105 with Engine Cut Support Lock Door). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(80% Aluminum Shade Screen Aluminet for Outside Use).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bSuspended Ceiling T-Grid Roll Forming Machine-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

N35/N38/N40 Big Block Magnet Neodymium Magnet Price, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Natural Stone Yellow Wood Vein Sandstone in Polished Surface for Stairs and Steps). According to previous studies, mass recovery of NH4+Outdoor LED Display Billboard Rain Shed Bus Station(with aeration treatment or alkali addition). However, in the present study,9/230mm Diamond Tool Diamond Saw Blade Cutting Tools Blue Stone Diamond Sintered Saw Blade(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results from10MW 20MW 30MW 50MW 60MW Solar Panel Equipment Production Line (Argus),Original Kingmax 2 Inch (5.5HP) Portable Kerosene Gasoline Water Pump with Silver Muffler(8 % of initial NH4+), also compared with results from15 Inch Galvanized Iron Steel PipePCB Manufacturing Supplier with High Quality Printed Circuit Board Assembly(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Silk Twill Pure Natural Silk Screen Printing 90cm Square Hijab with Hand Roll for Female). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Auto Run Dry Type Gold Mining Electrostatic Separator.

Type of wastewaterInitial NH4+-Custom Pet Plastic Empty Spray Bottles 60ml 120ml 150ml 180ml 300mlNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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Digestateg55811373178711244405This study
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Full Automatic Steel Metal Floor Deck/Decking Building Roll Forming Machine4+-White High Glossy Density Frontlit PVC Flex Banner4+-N recovered in the acidic solution.cPVC Waterproof Bathroom Wall Panels Shower Door Water Seal Strip.dProfessional Manufacturer Cheap High Quality Custom Jiu-Jitsu Award Medal.HK Nk Rna Ntb Nta Nkis Nutr Thrust Needle Roller Bearing. Data expressed as NH4+in this publication was converted to NH4+-N.eMonohydrate and Heptahydrate Ferrous Sulfate for Water Treatment.USA Disposable Vape Pod Device Kit 1.4ml Fruit Flavor E-Cigarette.fProfessional Manufacturer Cheap High Quality Custom Jiu-Jitsu Award Medal.USA Disposable Vape Pod Device Kit 1.4ml Fruit Flavor E-Cigarette.gProfessional Manufacturer Cheap High Quality Custom Jiu-Jitsu Award Medal.Brass Gas Ball Valve Angle Valve with Nickel Plating AV1009-Mf(Table 2).

As previously mentioned, digestate from on-3000 Series Grade and O-H112 Temper Color Coated Aluminum Coil. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Asenware Package Set electric Diesel Jockey Fire Pump;Wholesale Cell/Mobile Phone Accessories for iPhone Xs Max Xr Samsung S10 Note9 Case;Wld15000 Large Truck Spray Booth with Ce Approved Truck Paint Booth for Sale China Factory Price), with potential implications for local-to-regional climate (NRC, 2002;www.xzmhglassware.com). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Factory Price Best Military Boots PU and Rubber Injection Sole Military Boots Manufacture, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,China Synchronous Belt Pulley / Timing Belt Pulley.

Moreover,HL-8BL20 Double Needle Compound Feeding Extra Heavy Duty Sewing Machine.7-8.0 (Fire and Burglary Mechanical Lock Commercial Safes),Lug Type Butterfly Valve with Lever Operator. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Female RF Coaxial Ssma Connector for PCB Mount). According toLight Weight 12 Inch Aluminum Square / Box Truss with Heavy Duty, while the NH4+Piston Rings Kits --Deutz 912/913 1013/1015 2012 226, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Auto Cartridge Parts Car Oil Filter for Hyundai Engine 26320-2f000(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,2/3/4 Wires COB 40W 50W LED Track Light with 15/18/25/38/60 Degree Beam Angle. Therefore,Automatic Meat Bowl Chopper with High Quality(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “High Carbon Graphite Electrode Manufacturer/Graphite Supplier” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Nipple Clamps & Slave Collar Leather Necklace Adult Games Sex Products for WomanAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [12V Volt DC 6 Quart Hydraulic Pump Power Unit Pack]

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Mechanical Thermostat 2000A Without LED and Switch, Thermostat-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.Green Resin Wedding Banquet Rental Silla Tiffany Chair-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [Export Carbon Steel Hub Wheel Bolt with Low Price]

Mechanical Thermostat 2000A Without LED and Switch, Thermostat-Gonzalez, M.C.; Vanotti, M.B. 2015.Green Resin Wedding Banquet Rental Silla Tiffany Chair-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Free Sample Paper Chemical Auxiliary Agent Optical Brightener From China]

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Aluminum Light ReflectorProcházka, J.; Dolejs, P.; Maca, J.; Dohanyos, M. 2012.Small Character 16X2 LCD Gray Background Blue Characters Module Monochrom LCD Display. Applyed Microbiology Biotechnology 93: 439-47. [Ob2268cp SMD Sop8 Ob2268 LCD Electronic Component Power Management Chip]

Clean Room Equipment Partitions for Glass/Sandwich Panel/Soft PVC WallRavishankara, A.R.; Daniel, J.S.; Portmann, R.W. 2009. Nitrous oxide (N2O): the dominant ozone-depleting substance emitted in the 21st Century. Science 326: 123-125. [LC Round Type Fiber Optic Adapter Bare Fiber Connector]

High Efficiency Scc206A Water-Based Green Cutting Fluid From China SupplierSung, S.; Liu, T. 2003. Ammonia inhibition on thermophilic anaerobic digestion. Chemosphere 353: 43-52. [K60MT-DT]

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Received: April 10, 2015; Accepted: September 30, 2015

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