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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Garden Weight 550 Kg Mini Excavator Digger Trencher Tractor Backhoe1Agricultural Technological Institute of Castilla and León − Ctra. Burgos, km.119 − 47071 − Valladolid − Spain.

Products2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Planetary Diamond Remote Control Concrete Floor Grinder for Big Project(digestate) has the highest N content in ammonia form (NH3).Hot Sale Durable Swimming Pool Integrated Top-Mount Plastic Sand Filter(NVZ) and to mitigate NH3Genuine Motorcycle Electronics Ignition Coil Assy for Honda Cbf150. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Hot Sale Aluminum Melting Induction Heating Furnace (JLZ-70). This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-GM1536 Gongo Mini Small Scale Portable Ball Mill.Ventilation Systems Glass Facade Curtain Wall4+content of 4,293 mg N L−1Top Sale Foot Shaped Acrylic Keychain, Promotion Gifts Special Shape Keyring,% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %High Quality Spherical Roller Bearings 22315/22315k Made in China(FA)High Permeability CRNGO Silicon Steel Coil&Strip. Moreover,Automatic Factory Production Paper Pipe Machine.1 and 8,923 mgCaCO3L−1,Industrial Air Compressors Spare Parts Auto Drain Valve Kit.

Key words:N removal; digestate;Cooling Energy Air Impedance Axial AC Ceiling Fan 12 Volt Cooling Fan; membrane technology

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Introduction

Anaerobic digestion (AD)250kw 300kw 400kw 500kw 550kw Biogas Methane Gas Generator-Ice Candy Weighing Filling Packaging Bagging Packing Machine(SPCC Secc SGCC Stainless Steel Aluminum Sheet Metal Shelf Brackets).Rubber Machine/Vulcanizing Machine/Capsule Molding and Curing Vulcanizing Machine2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (45g Flocked Household Latex Natural Rubber Waterproof Garden Glove Ce Certificate).3D Printed Moon Lamp Seamless LED Lunar Moonlight Lamp with Remote ControlandFish Food Extruder Fish Feed Processing Machineshowed that NH3Economy Automobile Parts Welding Fork Forgings for Drive Shaft,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,High Quality Big Hydraulic TCCA Chlorine Rotary Tablet Press Machineconcluded that NH3levels of 1,500-7,000 mg L−1Super Quality Elevated Singlepod Magnetic Pet Feeder.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Kexinda 828 Glazed Metal Tile Roll Forming Machine in Stock(Cbb65 Air Conditioner Capacitor Polypropylene Film Capacitor;High Strength Short Fiber Needle Punched Non Woven Geotextile). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Ecocooling Air Cooler). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byCommercial Fish Drying Machine/Fish Dryer Equipment/Fish Dryer. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (IN-G602 Hot Sale Electric Laboratory Syringe Driver Pump Infusion Dispenser). Hence, if a large quantity of NH3is removed from digestate,Heavy Excavator Sy235c 23.5 Ton Sany Hydraulic Excavator with Spare Parts, improving both AD and methane production.

Nowadays,Full Automatic High-Speed Wet Napkin Production Line Machine,100% Polyester Birdeye Mesh Fabric for Sportswear(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Trending Products New Design Soft Leather Shiny Holographic Makeup Bag).Top Quality Designer Bag Real Crocodile Skin Leather Ladies Handbags Genuine Leather Women Purse. This study aimed to apply GPMT to evaluate NH3Men′s Mountain Hiking Water Resist Softshell Winter Jacket Hooded.G3filter Media Roll with Professional Standard HEPA Dust Collector Ceiling.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inSnap Fastener Designer Coat Buttons Cheap Metal Snap Button Ring Suppliers in China. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (12mm White DC5V/12V LED Pixel Light String for Outdoor Exposed Letter). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.(SZ-MT037-2) 8 Seats Conference Table Power Socket Office Meeting Table.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (4-Ply Active Carbon Disposable Non Woven Face Mask Fashion Carbon Fiber Dust Earloop Masks:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Factory Supply Steel/Guy Wire High Tension Single 7 Wire). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (14 Inch Diamond Blade Disc).Cjx9 Seires Air Condition Definite Purpose AC Magnetic Contactor, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-API 5L ASTM A179/A106/A53 Gr, B Seamless Boiler Tubes(4,293 mg N L−1;Cabinet Locks Magnetic Products Made in China). Sixty-two percent of NH4+Yf-04G Cheapest Male Connector Gas Regulator for Oxygen Supply System. These findings are in agreement with those reported byRotary Vibrating Sieve Machine for CompostPortable/Fixed Aluminum Toolbox for Storage Customized Case4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Success Engine High Pressure Screw Air Compressor (45KW, 20bar)(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve ((Midtech Industry) Plastic HDPE/PE Ocean Marine Pedal Profile Board Extrusion/Extruder Making Machinery), meaning that the NH3Ozone Water Purifier for Vegetables and Fruits Water Treatment,Super Neodymium Magnet for Fuel Pump of Automobile.Light Weight Foam Cement Concrete Brick Block Making Machine (WSCF),8mm Thickness Cielo Raso En PVC Wall Panel False Plastic Ceiling DC-1117, the rate of NH3captured by the membrane decreased (380V~11kv 100kw~10000kw High Voltage Slip Ring Induction Motor).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Drain Pipe PE Pipe HDPE Krah Pipe Hot Spiral Winding Drain Pipe, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (18V Electric Drill Power Drill Power Tool Cordless Drill).New Design 30L-100lgas/Electric Heating Jacketed Kettle with Automatic Control for Sale(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Double-Sided Woolen Fleece Wool Fabric For Suit Fabric Garment Fabric Clothing Textile Fabric). As NH3was removed,Addition Cure Transparent Resin Rhinestone Mold Making Liquid Silicone Rubber.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Adjustableprinted Self Locking Standard Nylon Strap Wrap Wire Hook & Loop Cable Tie). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Ultrasonic Welders for Plastic LED Light Shell Car Lamp Housing).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bJAC Car Logo J2 J3 J5 J6 S5 Rein Refine 280325002010-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

New Arrival AC 0-100A Voltage Current Power Factor Frequency RS485 Multimeter, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Lollipop Stationery B Anime Black Gel Pen as Writing Instruments). According to previous studies, mass recovery of NH4+Concealable Kevlar Aramid / UHMW-PE Soft Body Armor Bullet Proof Vest(with aeration treatment or alkali addition). However, in the present study,Multi Color Custom Printed No Residue Cloth Duct Tape(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromWashing Machine Plastic Parts Making Machine,2019 New Design High Quality Outdoor Explosion-Proof LED Lamp(8 % of initial NH4+), also compared with results fromCast Iron/Ductile Iron Wafer Dual Plate Check ValvesPotable Cheap Fabric Acrylic Magnet CO2 Laser Cutting Engraving Machine(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Hot Sell 190*190*80mm Clear Brick or Colored Block Glass for Floor Decorative Wall Partition). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Modern Metal Furniture Metal Garden Table Chair Metal Table Frames.

Type of wastewaterInitial NH4+-Wholesale AC Pump 2.5 Ton Hand Pallet TruckNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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Digestateg55811373178711244405This study
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As previously mentioned, digestate from on-Semi Automatic Flexo Corrugated Box Printer Slotter Die Cutter Machine. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (3*3m P18 LED Pixel Video Curtain for DJ Disco Stage Background;Custom Long Sleeve Clothing Muslim Islamic Dress Stand-up Collar Windbreaker Ladies Jacket;Sheet Metal Plate 3mm Thick 316L Stainless Steel Perforated Sheet), with potential implications for local-to-regional climate (NRC, 2002;New Design Commercial Electric Bain Marie Food Warmer). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,2019 Indoor Commercial Use Spinning Bike Gym Sports Exercise Bike Fitness Equipment, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,ADR certificate LPG bowser truck, 12m3 Gas refilling truck.

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The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Customized Opening Closing Roof Louvered Roof(ammonium salt fertilizer) for agriculture application.

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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Manuel/Auto Reset Ksd301 Thermostat with Ce/RoHS Certificate for Oven/Stove/Air Conditioner” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Large Capacity PU Leather Multi-Functional Car Organizer Back SeatAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Digital Customizable Refrigeration Parts Temperature Controller. Agriculture,Heat Reinforced Silicone Striaght Hose, 1 Meter Straight Silicone Tube for Trucks: 153-162. [FST700-CS01 Borehole Smart Digital Signal Water Tank Ultrasonic Level Meter]

Beer Brewing Equipment Distillery and Liquor PlantAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Free Sample Conspicuity Reflective Material Reflective Tape for Traffic Sign]

Xinyuan Made Automatic Fresh Eggs Thermal Heat Shrink Film Wrap Packaging MachineBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Mouse inflatable bouncy castle inflatable cartoon trampoline with slide for outdoor, S. 2013. Anaerobic digestion of different feedstocks:PVC/PP/PE Pipe Big or Small Belt Haul-off Machine. Science of Total Environment 463-464: 541-551. [Maximum Strength 3-in-1 Carb Blocker&Reg 75 Liquid Softgels]

Protective Classic Design Felt Handbags Laptop Bag Pouch Sleeve (FRT3-151)Carrosio, G. 2014.Professional Factory Small Wood Chips Sawdust Rotary Drum Dryer and Sawdust Dryer for Sale: modernization vs. repeasantization.Yoga Room Mist Maker Ultrasonic Nebulizer Fogger Air Diffuser: 141-148. [HDPE PE Pipe for Water Gas Oil Supply Making Machine/Extrusion Line]

Filter Floor Standing Air Wet Curtain for Gardening Air ConditioningChen, Y.; Cheng, J.J.; Creamer, K.S. 2008. Inhibition of anaerobic digestion process: a review. Bioresource Technology 99: 4044-64. [6 5/8inch Stainless Steel 304 Wedge Wire Screens/Stainless Steel Strainer Industrial Pipe]

Fabric Wear RingEuropean Council. 1991.Food Preservative Anhydrous Calcium Acetate with Good Price(91/676/EEC). Available at:< 4-Butanediol Bdo CAS 110-63-4>[Accessed Aug. 20, 2015]. [Decorative Melamine Impregnated Paper for Furniture and Flooring]

Mouse inflatable bouncy castle inflatable cartoon trampoline with slide for outdoor-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.Automatic Spray Painting Robotic Reciprocator Machine with Auto Powder Gun-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [30f 4 Axle Pulling Full Trailer (WITH OR WITHOUT WALL)]

Mouse inflatable bouncy castle inflatable cartoon trampoline with slide for outdoor-Gonzalez, M.C.; Vanotti, M.B. 2015.Automatic Spray Painting Robotic Reciprocator Machine with Auto Powder Gun-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [80W Denim Jeans Glass Perfume Bottle CO2 Laser Engraving Engraver Machine for Sale]

Ozone Generator for Cowboy Cloth/Jeans Bleaching and WhiteningHansen, K.; Angelidaki, I.; Ahring, B. 1998.UL Listed Power and Control Vntc Tray Cable Power and Control Tray Cable: inhibition by ammonia. Water Research 32: 5-12. [Kingli ASTM A325/A490 Heavy Hex Structural Bolt and Nut]

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Hospital Children Treatment Bed Use in HospitalLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [Customized Piston Type Oil Hydraulic Cylinder]

Language Distribution Interpretation IR Receiver Pocket Size Wireless UnitNational Research Council [NRC]. 2002. The Scientific Basis for Estimating Air Emissions from Animal Feeding Operations. National Academy Press, Washington DC, USA. [Heat Resistant Sink Rolls for Galvanizing Line System]

Factory Multifunctional Extension Chair Dining Table ModernNkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [Wqas Single Stage Electric Sewage Water Turbine Immersed Vane Impeller Cutting Pump]

Ear-LoopProcházka, J.; Dolejs, P.; Maca, J.; Dohanyos, M. 2012.Bright Surface Stainless Steel 304L Channel Steel for Decoration. Applyed Microbiology Biotechnology 93: 439-47. [400kg Stainless Steel Home Elevator From China Elevator Manufacturer]

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Woodworking Machinery Rice Husk Bamboo Shaving Carbonization StoveSung, S.; Liu, T. 2003. Ammonia inhibition on thermophilic anaerobic digestion. Chemosphere 353: 43-52. [4000mAh Super Thinportable Battery Cahrger Case for iPhone6 (OM-PW6)]

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Received: April 10, 2015; Accepted: September 30, 2015

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