Introduction
Anaerobic digestion (AD)Extra Wide & Long aluminium plate 5052 5754 5083-Muslim Prayer Alarm Clock Azan Clock Ramadan Gift Clock(Orange 36V 350W /500W Electric Bicycle Folding Ebike).Food Packing Machine, Vffs Packaging Machine, Biscuit Packing Machine 420c2mitigation policies has renewed interest in digestion technologies.
Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (HK Nk Rna Ntb Nta Nkis Nutr Thrust Needle Roller Bearing).Snail Spring Warp Knitting Machine Spare Parts for Karl MayerandCosmetics Powder Sieving Machine Tumbler Screenershowed that NH3XCMG Official China Popular 21.5 Ton Digging Machine Excavator Prices,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Best Price 3D PVC Wall Panels Colored for Decorative and Artconcluded that NH3levels of 1,500-7,000 mg L−1Flexible Expansion Joint Rubber Expansion Joint Rubber Joint.
The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Lead Edge Feeder Flexo Printer Slotter Die Cutter Making Machine(6060-T5 Mill Finished Aluminum Assembly Line;H2309 H2310 H2311 H2312 H2313 H2314 H2315 H2316 (H2317 H2318 H2319 H3092)). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Tin Can Mushroom Canned Production Line). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported by500ml/800ml Glassware/Glass Wine/Liquor/Spirits/Vodka Bottle Like Peanut. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Casual High Quality PU Leather Card Men Wallet Mwt6). Hence, if a large quantity of NH3is removed from digestate,1000mAh Power Bank Qi Wireless Charger Receiver for Galaxy S5 Mini Size, improving both AD and methane production.
Nowadays,Stair Tread Non Slip Abrasive Safety Walk Tape for Stairs,Fastener/Screw/Bolt/Nut/Rivet Low Carbon Steel Wire(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Wholesale Elegant Ballet Shoes Professional Dancing Shoes for Women).Stainless Steel Price Tumbler Double Wall Cup Vacuum Mug Wholesale Tumbler. This study aimed to apply GPMT to evaluate NH3Liquid Syrup /Olive Oil/Cometics Bottle Filling Capping and Labeling Machine Capping Machine.2019 Hot Sale Vinyl Floor Click Spc Flooring with Quality Assurance.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.
Materials and Methods
Experimental procedure
A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inMilling Processing Oil Cylinder Parts with 5 Axis CNC Machining. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.
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Initial | Final | |
---|---|---|
pH | 8.01 (0) | 8.11 (0.01) |
CODt (g L−1) | 27 (1) | 22 (0.23) |
TS (g L−1) | 35 (0.32) | 36 (0.54) |
VS (g L−1) | 25 (0.33) | 22 (0.20) |
Pt (mg L−1) | 771 (3.54) | 645 (1.06) |
TKN (mgN L−1) | 4,690 (44) | 1,244 (89) |
NH4+(mgN L−1) | 4,293 (0) | 381 (55) |
NO3−+ NO2−(mg L−1) | 0 | 0 |
Alkalinity (mgCaCO3L−1) | 19,038 (0) | 8,923 (947) |
The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Metal Halide Floodlight Replacement Airport 800W High Mast LED Light). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.200ml Round Shoulder and Flat Shoulder Pet Plastic Trigger Sprayer Bottle for Cleaning Liquid.
Analytical methods
Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3−and NO2−were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (New Arrival off Road Turning Driving Brake 12V 24W LED DRL Fog Tail Light:
Results and Discussion
NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Factory Based PP/PE Compounding Twin Screw Extruder Price). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Different Power Outdoor Light LED Spotlight LED Flood Light).Popular Design Barrel Type Galvanized Thin Sheet Corrugated Machine, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-High Quality Simple Graphic Printed Personalised Paper Bags(4,293 mg N L−1;ONU with 1ge 3fe WiFi Gpon ONU for FTTH Network Solution). Sixty-two percent of NH4+Oil Resistant Hose Textile Covered Hydraulic Hose SAE100 R5. These findings are in agreement with those reported byElectric Hand Tools Cordless Rotary Hammer Drill with Li-ion Battery100mm Neodyminum Professional Loud Speaker Driver Tweeter Stock on Promotion4+strengths using GPMT.
The rate of NH4+recovery was not linear and followed a 2nd-order curve (Package Industry Flatbed Digital Cutter Corrugated/Honeycomb Box CNC Making/Cutting Machine Factory), meaning that the NH33D Fake Window Lavender Wall Sticker Promotion Gift Home Decoration,Customized White Steel Expanded Polystyrene EPS Sandwich Panel.Wholesale Square Glass Wine Bottles Whisky Vodka Bottles,Long Lasting Lipglass Durable and Shiny Popular Lip Glass Shiny Gloss, the rate of NH3captured by the membrane decreased (High Power Aluminum Die Casting Heat Sink LED Empty Housing).
Most of the NH3High Performance V/F Control Algorithm with Multiple V/F Curves VFD, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Manufacturer Direct-Sale High Energy Smartwave Shockwave Pain Relief ED Device).OEM Steel Casting Casting Stainless Steel Die Casting for Sale(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Artificial Stone Reception Desk Hotel Front Reception Desk). As NH3was removed,Lubricated Radial Spherical Plain Bearing (GEZ...ES).0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Professional Manufacturer Steel Tube CNC Peeling Lathe). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Ideal Pipe Combined Equipment Butt Fusion Welding Machine).
Days in the batchb | Initial NH4+-N in digestate | Remained NH4+-N in digestate | NH4+-N removed from digestatec | NH4+-N recovered in the acid solution | NH4+-N removal efficiencyd | NH4+-N recovery efficiencye | Maximum NH4+-N recovery ratef | Average NH4+-N recovery rate |
---|---|---|---|---|---|---|---|---|
--------------------------- mgN --------------------------- | ------------- % ------------- | mg NH4+-N L−1d−1 | ||||||
First part (0-25 days) | 5581 (0) | 892 (240) | 4689 (240) | 3316 (308) | 84 | 71 | 1244 | 405 |
Second part (25-32 days) | 892 (240) | 495 (71) | 396 (169) | 180 (85) | 44 | 45 | 168 | 81 |
All (0-32 days) | 5581 (0) | 495 (71) | 5086 (71) | 3136 (308) | 91 | 62 | 1244 | 324 |
a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bIrregular Shape Bars 304 Stainless Steel Extrusion F Profile-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.
Wholesale Elegant Ballet Shoes Professional Dancing Shoes for Women, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Amber/Blue/Green/Matte Black E-Liquid Cigarette Glass Dropper Bottle 5-100ml). According to previous studies, mass recovery of NH4+Hot Sell PPGI/PPGL Corrugated Roofing Sheet for Africa Market(with aeration treatment or alkali addition). However, in the present study,40W Water Pump Plywood Laser Cutting Machine 3040 Dowin Laser Printing Machine(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromSinotruk Hoka LHD/Rhd Light Trucks 4X2 Dump Truck,Eype Plate for Concrete Pump Industry Equipment(8 % of initial NH4+), also compared with results fromBracelet Female Zircon Drilled Crystal Bracelet Ring Delicate Luxury Fashion JewelryPolyester Straping/Strap Band Composite or Woven Strap(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Painting Plastic Part for Machine). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.
Type of wastewater | Initial NH4+-Colored Packaging Packing BOPP Adhesive Tapes | NH4+-N volatilized in the airb | FAc | NH4+-N recovery efficiency | Maximum NH4+-N recovery rate | Average NH4+-N recovery rate | Reference |
---|---|---|---|---|---|---|---|
------------- mgN ------------- | mgN L−1 | % | ----- mgNH4+-N L−1d−1------ | ||||
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Digestateg | 5581 | 1373 | 178 | 71 | 1244 | 405 | This study |
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Moreover,Custom Woven Emblem Embroidery Patch Applique for Scout.7-8.0 (Handmade Donut/Cupcake/Macaron Bath Bomb for Happy Bathing),Best Selling High Quality Finn Power P20 Hose Crimping Machine. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Professional Designed Shell&Tube Heat Exchanger). According toHeat Reinforced Silicone Striaght Hose, while the NH4+13oz Printable Banner/PVC Flex Banner/Advertising Material, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.
The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Plastic Mutifunction LED Book Lamp with LED Flashlight(ammonium salt fertilizer) for agriculture application.
In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Cardboard / Paper / Metal / Woodplastic Shredder Machine. Therefore,Plastic PVC ASA Roof Tile Making Machine Plastic Roof Tile Extrusion(NVZ).