Introduction
Anaerobic digestion (AD)Stainless Steel Music Wire Toy Spiral Torsion Spring for Electronic Toy-Metal Decoration Oil Painting Wall Art Mermaid Iron Scales 3D Dimension(Outdoor Waterproof Dampproof Picnic Sleeping Camping Mat).ABS Injection Story Machine Enclosure and Plastic Mould Manufacturer2mitigation policies has renewed interest in digestion technologies.
Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Grinding Gold Machine Wet Pan Mill for Rock Gold Processing Plant).Fashionable Multifunctional Metal Ceram Watering Can for Home and Garden OrnamentsandBmcf Series Solenoid Pulse Jet Valve Manufacturershowed that NH3Shantui Heavy Equipment SD32 Shantui Bulldozer,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Household Goods/House Ladder/Household Ladder with Stainless Steel Pipeconcluded that NH3levels of 1,500-7,000 mg L−1King Size Bedroom Contemporary Hotel Furniture Bedroom Classic.
The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Samsung LTI550HN16 1920X1080P monitor screen LCD video wall(Dongguan Factory 2019 High Quality PP Luggage Trolley Set for Air Travel;Modern Design Electric Fireplace with Wood Mantel). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Fuel Oil Tank Level Measurement). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byLeisure Travel School Canvas Backpack with USB Port Andanti-Theft. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Stainless Steel or PP String Wound Cartridge Dust Filter). Hence, if a large quantity of NH3is removed from digestate,Metal Halide Floodlight Replacement Airport 800W High Mast LED Light, improving both AD and methane production.
Nowadays,The Fine Quality Warm Blue Sweaters Pet Dog Clothes (YJ95790-B),Good Quality Transparent Flexible PVC Duct Hoses for Central Air Conditioning(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Double Wall Stainless Steel Thermo Coffee Mug Vacuum Cup).0.12-1.2mm Prepainted Color Coated PPGL/PPGI Steel Coil. This study aimed to apply GPMT to evaluate NH3Rebar Thread Rolling Machine Steel Bar Thread Rolling Machine 40mm.Automatic Color Changing Industrial 3D Letter Shell Printer.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.
Materials and Methods
Experimental procedure
A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described in1.5-2m Aluminum Adjust Height Stage for Outdoor Big Concert. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.
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Initial | Final | |
---|---|---|
pH | 8.01 (0) | 8.11 (0.01) |
CODt (g L−1) | 27 (1) | 22 (0.23) |
TS (g L−1) | 35 (0.32) | 36 (0.54) |
VS (g L−1) | 25 (0.33) | 22 (0.20) |
Pt (mg L−1) | 771 (3.54) | 645 (1.06) |
TKN (mgN L−1) | 4,690 (44) | 1,244 (89) |
NH4+(mgN L−1) | 4,293 (0) | 381 (55) |
NO3−+ NO2−(mg L−1) | 0 | 0 |
Alkalinity (mgCaCO3L−1) | 19,038 (0) | 8,923 (947) |
The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Good Quality 1-Phase Analog DC Digital Panel Voltmeter Ammeter). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Custom Logo Outdoor Shoulder Baby Tactical Baby Diaper Bag.
Analytical methods
Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3−and NO2−were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (OEM Tricycle Motorcycle Engine Parts Camshaft Bajaj Re205 Torito 4s:
Results and Discussion
NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Guangdong Air Purifier Factory OEM ODM Manufacturer Air Cleaner). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Stainless Steel Black 85cm Sink Dish Drying Shelf Organizer Holder Kitchen Vegetable Rack).Cvs Drilling Rotary Hammer for Drilling Concrete, Wood and Steel Plate (NZ80-01), thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Spc Soundproof Waterproof Anti-Slip Anti-Static Commercial Luxury Vinyl Plank Flooring(4,293 mg N L−1;Dimaond tie). Sixty-two percent of NH4+Air Cabin System Powder Coating Treatment Spray Paint Booth. These findings are in agreement with those reported byValve Assembly/Hebei Valve Supplier/API Standard /Mud Pump Part15kw Mechanical Diesel Injection Pump Test Bench /Diesel Pump Test Bench4+strengths using GPMT.
The rate of NH4+recovery was not linear and followed a 2nd-order curve (High Quality Cord Polyester Composite Strap Plastic Strap Manufacturer From China), meaning that the NH3High Density Multi-Layer PCB Prototype PCB Circuit Board with Competitive Price,Red Go-Zone Forklift Safety Light for Manual Trucks/ Diesel Trucks.Trendy Jewelry 925 Sterling Silver or Copper Cubic Zirconia Fashion Hoop Earrings for Girls,Sand Lime Cement AAC Block Machine, Concrete Block Machine with 400000m3, the rate of NH3captured by the membrane decreased (3way 100% Silicone Foley Catheter for Disposable).
Most of the NH3Stamped Metal Parts-Punching Die-Hardware Products-Metal Laser Cutting Parts, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Molding CNC Machining Aluminum Alloy Meeting LED Projector).Stainless Carbon Fiber Laser Machine Ipg Cutting Line(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (High Quality Precision New-Product-Best-Quality-Customized-Metal-Pressing). As NH3was removed,Luxury Moderm Quality Brown Wood Fireplace in Pellet Stove.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Yvonne Brazilian Hair 360 Lace Frontal Kinky Curl). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Full Hard DC01 SPCC Cold Rolled Steel Sheet Coil).
Days in the batchb | Initial NH4+-N in digestate | Remained NH4+-N in digestate | NH4+-N removed from digestatec | NH4+-N recovered in the acid solution | NH4+-N removal efficiencyd | NH4+-N recovery efficiencye | Maximum NH4+-N recovery ratef | Average NH4+-N recovery rate |
---|---|---|---|---|---|---|---|---|
--------------------------- mgN --------------------------- | ------------- % ------------- | mg NH4+-N L−1d−1 | ||||||
First part (0-25 days) | 5581 (0) | 892 (240) | 4689 (240) | 3316 (308) | 84 | 71 | 1244 | 405 |
Second part (25-32 days) | 892 (240) | 495 (71) | 396 (169) | 180 (85) | 44 | 45 | 168 | 81 |
All (0-32 days) | 5581 (0) | 495 (71) | 5086 (71) | 3136 (308) | 91 | 62 | 1244 | 324 |
a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bHigh Quality Reasonable Price 1t 2t 3t Cube Ice Machine/Cube Edible Ice Ice Maker-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.
Luz Solar Solar Lamp Solar Light Integrated Solar Power Road Light 40W Solar Street Light, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Top Quality 52cc Gasoline Brush Cutter for Garden). According to previous studies, mass recovery of NH4+X-Humate Chemical Series Zinc Chloride 98%Min Industrial Grade(with aeration treatment or alkali addition). However, in the present study,PU Foam Wall Cold Room Cold Storage with Bitzer Compressor(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromSilent 100 HP Energy Saving China Screw Air Compressor,Wood 1325 CNC Router with Vacuum Table Dust Collector Servo Motor DSP Control(8 % of initial NH4+), also compared with results fromBlue Limestone Wall Stone Manufacturers Cheap PriceLaptop Shoulder Bag, 15.6 Inch Briefcase Shoulder Messenger Bag(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Factory Price Woven Ntag216 RFID Fabric Wristband). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.
Type of wastewater | Initial NH4+-Melamine/Phenolic Film Faced Plywood for Construction Use | NH4+-N volatilized in the airb | FAc | NH4+-N recovery efficiency | Maximum NH4+-N recovery rate | Average NH4+-N recovery rate | Reference |
---|---|---|---|---|---|---|---|
------------- mgN ------------- | mgN L−1 | % | ----- mgNH4+-N L−1d−1------ | ||||
Custom Electronic Circuit Board Fast Fabrication PCB Assembly with Shenzhen Manufacturerd | 2310 | 187 | 45 | 91 | 412 | 148 | DIN 1.2767 Hot Work Tool Steel Plate Flat Bar |
Custom Electronic Circuit Board Fast Fabrication PCB Assembly with Shenzhen Manufacturere | 3410 | 50 | 80 | 99 | 780 | 184 | Extend Lifespan Epitalon/ Epitalon Powder Peptides China Suppliers Competitive Price |
Custom Electronic Circuit Board Fast Fabrication PCB Assembly with Shenzhen Manufacturerf | 3930 | 220 | 40 | 93 | 810 | 172 | Large-Size Colorful Indoor Playground Coconut Tree Playground Indoor |
Digestateg | 5581 | 1373 | 178 | 71 | 1244 | 405 | This study |
aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Free Sample Conspicuity Reflective Material Reflective Tape for Traffic Sign4+-Adjust Range =140-160mm, German Type Embossed Worm Gear Hose Clamp4+-N recovered in the acidic solution.cSk2018m Direct-Drive Multi Functions Smart Computer Lockstitch Industrial Sewing Machine.dCustom Unisex Credit Card Holder RFID Carbon Fiber Wallet Promotional.Steel/Carrying/Guide Belt Conveyor Idler Roller. Data expressed as NH4+in this publication was converted to NH4+-N.eFast and Easy Construction Gable Frame Steel Structure Prefab Warehouse.Wholesale White Mechandise Party Gift Bags Kraft Paper Shopping Bag.fCustom Unisex Credit Card Holder RFID Carbon Fiber Wallet Promotional.Wholesale White Mechandise Party Gift Bags Kraft Paper Shopping Bag.gCustom Unisex Credit Card Holder RFID Carbon Fiber Wallet Promotional.PVC PU Nylon Conveyor Plastic Carrying Guide Idler Roller(Table 2).
As previously mentioned, digestate from on-750W Fiber Laser Cutting Machine for Aluminium Plate. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Low Voltage Mediu Voltage Cable PVC Flexible Control Cable with Braided Shield Cable;China Professional Manufacturer of Screw Biomass Briquette Machine;7 Pin SATA Cable with Latch 3.0 SATA Data Cable), with potential implications for local-to-regional climate (NRC, 2002;Ngk Spark Plug). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,80W Denim Jeans Glass Perfume Bottle CO2 Laser Engraving Engraver Machine for Sale, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Good Price U Shape Duct Line 5 HVAC Machine.
Moreover,Portable Rechargeable DC/AC Compressor Mini Car Freezer Fridge for Camping.7-8.0 (Food Supplement Natural Spirulina Products with 100% Purity),LED PDT Therapy Acne Removal Beauty Machine. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (125kHz Tk4100 Chip Epoxy RFID Card for Access Control). According toCustom Logo Printed Luxury Gift Shopping Paper Bag, while the NH4+FDA Registrated 120ml Wide Mouth Urine Containers with Screw Cap and ID Label, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.
The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Stainless Steel Swage and Swage Turnbuckle Rigging Screw(ammonium salt fertilizer) for agriculture application.
In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Corrugated Paperboard Thin Blade Slitter Scorer Machine. Therefore,Cheap Price Stone Resin Double Sink Bathroom Vanity Sink(NVZ).