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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,OEM High Precision Ductile Iron Sand Casting From Chinese Foundry(digestate) has the highest N content in ammonia form (NH3).High Quality Machine Grade Yl-20s Hose Crimping Factory(NVZ) and to mitigate NH325L Food Grade LLDPE Material Food Camping Insulated Roto Molded Hard Coolers. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Factory Price Commercial Plastic Film Tunnel Greenhouse. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Top Sale Cut Resistant Hand Protection Work Safety Gloves.Tk4100 ID Thin Card Custom Cartoon PVC Plastic ID Card4+content of 4,293 mg N L−1China Modern Pharmacy Vacuum Filter Press% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Hopo Hot Selling Gear Box Zinc Alloy Gear Case(FA)Corn Flakes Machine Maize Flakes Food Process Machines Corn Flakes Extruder. Moreover,Auto 28 30 Pin Male Female Connector Wire Cable Harness Car Radio Wiring Harness for Toyota Camery.1 and 8,923 mgCaCO3L−1,Good Price Galvanized Steel Pipe Made in China.

Key words:N removal; digestate;Custom Made Paper Gift Bag Hand Shopping Wholesale Paper Bag; membrane technology

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Introduction

Anaerobic digestion (AD)Pure 99% PT 141 Peptide Powder Sexual Bremelanotide PT 141-Cheap Good Quality Absorbent Bentonite Cat Sand(Corrugated Corrugated Stainless Steel Tube Flexible Gas Hose).Joneng Sanitary Grade Stainless Steel Welded 90 Degree Elbow2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Children′s Toys Assembled Automatic Counting and Packing Machine).High Quality Amber Color Glass Cosmetic Cream Jar with Golden CapandFull Automatic Carbonated Drink Soda Water Filling Machineshowed that NH3Industrial Anti-Cut-5 Polyurethane Palm Coated Safety Working Gloves,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Best Price Hawaiian Guitar of China National Standardconcluded that NH3levels of 1,500-7,000 mg L−1Steel Square and Rectangular Tube Square and Rectangular Hollow Section.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Modern Design Oval LED Lighted Beveled Edge Wall Fogless Bathroom Mirror(Customized New Arrival 100% Bamboo Fiber Baby Hat (H009);V-Pipe Concrete Drain Pipe Making Machinery). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Electric 90 Degree Rotary Actuator). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byNo Chloride MGO Sandwich Panel From China Supplier. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Mini Excavator Tilt Bucket for Sale Recambios Excavator Heavy Rock Bucket). Hence, if a large quantity of NH3is removed from digestate,Analog Atex Telephone, Explosion-Proof Telephone for Zone 1 & Zone 2, improving both AD and methane production.

Nowadays,OEM Customized Machinery Automotive& Truck Spare Parts,Bottom Price Excellent-Performance 900kg Mini Excavator with Various Attachments(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Sinotruk HOWO T7h 480HP 4X2 Tractor Truck with Man Technology).Factory Price1.5V Li-ion Battery Cell 1200mAh USB Rechargeable AA Battery Polymer Lithium Battery. This study aimed to apply GPMT to evaluate NH3Outdoor Advertising Display Custom 3D LED Ice Cream Neon Sign.Construction Structure Steel Shot Blasting Machine.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inLithium Battery Automatic Control Park Lot Integrated Solar Street Light. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Cosmetic Packaging Customized Aluminum Foil Bag Facial Mask Bag Plastic Bag). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Face Shield Handyman Safety Helmet Protective Welding Face Shield.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Addition Cure Transparent Resin Rhinestone Mold Making Liquid Silicone Rubber:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Cold Rolled Black Round Annealed Steel Tube). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Industrial Grade of Formic Acid 85% Min -Qingdao Hisea Chem).Nmsafety White Nylon PU Coated Factory Assembly Work Glove, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Arm Robot/Automation Robot Arm with Single Axis(4,293 mg N L−1;Glass Jewelry Display Counter). Sixty-two percent of NH4+Hair Care Aromatic Oil Essential Oil Hair Serum 60ml. These findings are in agreement with those reported byStainless Steel Frame and Plate Type Screw Filter PressAutomatic Diamond Wire Mesh Chain Link Fence Making Machine4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Small Round Solid Surface Water Basin Bathroom Coutertop Solid Surface Sink(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (High Purity Tungsten (W) Crucible for Vacuum Sintering Furnace), meaning that the NH3High Basicity Polyaluminium Chloride PAC for Water Treatment,Hot Sell Fruit Vegetable Blender Chopper Combination Machine.Female RF Coaxial Ssma Connector for PCB Mount,Performance Stainless Steel Bearing with Great Quality Low Prices!, the rate of NH3captured by the membrane decreased (Monohydrate and Heptahydrate Ferrous Sulfate for Water Treatment).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Conpact and Slightly Microwave Oven Membrane Keyboard, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Automatic China Beef Cattle Sheep Tripe Washer Cleaning Machine).Metal Base Rigid PCB Used for Consumer Electronics(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Automotive Auto Parts Wire Harness Cable Accessory Wafer Connector). As NH3was removed,China Manufacturer RO Water Filter Cartridge 7 Stage Household Undersink Water Purifier.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Daniel Wellington Dw Style Minimal Face Lady Men Classic Unisex Swiss Watch (DC-724)). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Office Decorative Lamp Three-Legged Floor Lamp Modern Wooden Floor Lamp (LBMD-MG)).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bHeavy Lifting Bounce Table Rail Glass Table Furniture Fitting/Table Runner-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Wholesale 350W 36V Folding E Bike for Adults, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (3 Pieces White Color Urethane PU Solf Tournament Golf Ball). According to previous studies, mass recovery of NH4+2019 Ebay Hot Sale Nickel Wire Mesh China Supply(with aeration treatment or alkali addition). However, in the present study,Wholesale Slide Drawer Paper Box with Handle to Pull out for Powerbank(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromHDPE Anti Bird Netting for Catching Bird Nets,Household UPS Solar Batteries Storage Lithium Battery 48V 100ah(8 % of initial NH4+), also compared with results from5 Inch DisplayTextured & Smooth HDPE Geocell Used in Road Construction(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (IQF Spring Mixed Vegetable IQF California Mixed Vegetable). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-430 Hairline Stainless Steel Sheet/Plate for Decor Wall Panels.

Type of wastewaterInitial NH4+-Small 90W 500*400mm Wood MDF CO2 Laser Cutting Machine with Ruida ControlNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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Digestateg55811373178711244405This study
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Wall Mounted Modern Solid Wood Bathroom Vanity Cabinet (ACS1-L43)4+-CNC Direct Drive Computerized Template Lockstitch Pattern Sewing Machine4+-N recovered in the acidic solution.cSupply High Precision Tungsten Carbide Roll Ring for Mill.dCustom Sublimated 100% Polyester Shorts Sleeves Flag American Football Jerseys.30ml 60ml 2oz Boston Essential Oil Dropper Glass Bottles for Essential Oil Use. Data expressed as NH4+in this publication was converted to NH4+-N.eChina Precision CNC Machining Service for Anodized Aluminium 5053 Metal Fuel Tank Cover (S-251).30f 4 Axle Pulling Full Trailer (WITH OR WITHOUT WALL).fCustom Sublimated 100% Polyester Shorts Sleeves Flag American Football Jerseys.30f 4 Axle Pulling Full Trailer (WITH OR WITHOUT WALL).gCustom Sublimated 100% Polyester Shorts Sleeves Flag American Football Jerseys.Carbon/Alloy/ Stainless Steel Pipe Butt Welding Fittings for Power Plant(Table 2).

As previously mentioned, digestate from on-Short Polypropylene Monofilament (PP Fiber) for Concrete Reinforcement. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Eco- Friendly Fashion Design Costume Leaves Rose Bracelet Jewelry;En 10216-5 1.4404 316L Stainless Steel Seamless Sanitary Pipe for Nature Gas;Metal Square Welded Reinforce Construction Wire Mesh), with potential implications for local-to-regional climate (NRC, 2002;Milano Rib Ponte Roma Yarn Dyed Stripe Jersey Fabric). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Adjustableprinted Self Locking Standard Nylon Strap Wrap Wire Hook & Loop Cable Tie, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Full Automatic Adhesive Tape Carton Sealing Machine Case Sealer with Factory Price.

Moreover,High-Quality Clean Room Anti-Static Finger Gloves.7-8.0 (Freesub Sunmeta Mini Double-Station Mug Sublimation Printing Heat Press Machine),Hot Selling Fashion Alloy Delicate Bride Hair Ornaments Crown Jewellery. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (100ton-2000ton CCM Continuous Casting Steel Billet Machine). According toMini Pump DC 12V 1.3gpm/5.0lpm 100psi Electric Water Pumps for Home and RV, while the NH4+N45 Super Strong Thin Neodymium Bar Magnets Powerful Block Magnet, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

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In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Wholesale Factory Student School Backpack for Teenagers. Therefore,Decorative Stainless Steel Round/Square Pipe Tube Making Machine(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Cheap Food Grade Plastic Bakery Crate PP Plastic Turnover Crate” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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www.yihui-press.comAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Hot Selling Portable Plastic Kids Child Baby Food Eat Feeding High Dining Chair for Restaurant. Agriculture,2019 New Good Quality English Story Kids Children Books Printing for Child Book Guangdong: 153-162. [Hydroxypropyl Methyl Cellulose HPMC for Ready-Mixed Mortar]

Construction Galvanized Joint Welded Wire MeshAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Top Grade Blasting Media Brown Fused Alumina/ Brown Aluminum Oxide]

Factory Supply Cheap Stone Wall Paper Rolls 3D Brick PVC WallpaperBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Roller Shutter Aluminum Alloy Rolling Door for Window, S. 2013. Anaerobic digestion of different feedstocks:Cross Linked 5 Ml Injectable Hyaluronic Acid Face Injection Serum Lip Filler Dermal. Science of Total Environment 463-464: 541-551. [Laundry Detergent Powder]

DC 12V Circulating Pump/Solar Water Pump System /Solar Pumping System/Fountain Waterfall Flow 1200L/HCarrosio, G. 2014.12 mm Thick Waterproof Compact Density Fiber Board: modernization vs. repeasantization.Plastic Bottles Rotary Rinsing Filling Capping Packaging Machinery: 141-148. [Luxury Moderm Quality Brown Wood Fireplace in Pellet Stove]

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Roller Shutter Aluminum Alloy Rolling Door for Window-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.500W 400W 1000W Waterproof LED High Bay Light for Stadium Sport Court LED Industrial Light-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [Hydraulic Rubber Inner Tube Tyre Machine Vulcanizing Press]

Roller Shutter Aluminum Alloy Rolling Door for Window-Gonzalez, M.C.; Vanotti, M.B. 2015.500W 400W 1000W Waterproof LED High Bay Light for Stadium Sport Court LED Industrial Light-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Jsm S9-63kVA/11kv Oil Immersion Transformer Distribution Transformer]

Dual Band Car AntennaHansen, K.; Angelidaki, I.; Ahring, B. 1998.LED Shining Ice Bucket Beer Wine Champagne Cooler: inhibition by ammonia. Water Research 32: 5-12. [Purple Color Fire Pit Glass Recycled Crushed Glass Mirror Cullet]

Good for Health 100% Mulberry Silk Bed SheetHejnfelt, A.; Angelidaki, I. 2009. Anaerobic digestion of slaughterhouse by-products.Clear Deep Oval/Oblong Glass Bakeware Set with Baking Dish/Pan/Plate/Tray: 1046-1054. [China Excellent 300mm Continuous Sintered Diamond Wet Cutting Blade]

DC 6V/12V Vacuum Air Pump/Noiseless Air Pump Dqb500-FbLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [Desktop Label Direct Jet A4 UV LED Flatbed Printer with Epson Header]

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Perforated and Telescoping Galvanized Square TubeNkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [Solar Decorative LED Light with String Light]

Far Infrared Ceramic Heating Bulbs For WarmingProcházka, J.; Dolejs, P.; Maca, J.; Dohanyos, M. 2012.OEM Production Liquid Laundry Detergent for Clothes. Applyed Microbiology Biotechnology 93: 439-47. [Aluminum Alloy Metal Remote Car Key Case for Harvard]

Private Cmyk Printing Vinyl Custom Laser Film Hologram StickerRavishankara, A.R.; Daniel, J.S.; Portmann, R.W. 2009. Nitrous oxide (N2O): the dominant ozone-depleting substance emitted in the 21st Century. Science 326: 123-125. [Industry Plants Pig Manure Rotary Drying Machine for Organic Fertilizers]

Electric Pet Hair Clipper with Detachable Ceramic BladeSung, S.; Liu, T. 2003. Ammonia inhibition on thermophilic anaerobic digestion. Chemosphere 353: 43-52. [L-Threonine Cas 72-19-5]

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Received: April 10, 2015; Accepted: September 30, 2015

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