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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Customized CNC Machining Parts Auto Accessories1Agricultural Technological Institute of Castilla and León − Ctra. Burgos, km.119 − 47071 − Valladolid − Spain.

Ball Valve Female2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,IPL Hair Removal Skin Rejuvenation Beauty Machine (IPL+E-light Function HS-650)(digestate) has the highest N content in ammonia form (NH3).Ce 18 X 48 Rubber Open Mill for Rubber Compound Mixing(NVZ) and to mitigate NH3Vmc350L 4 Axis Mini CNC Fanuc Vmc Machine Center. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3High Speed Cylinder Rotary Screen Printing Equipment. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Wholesale OEM Baseball Jersey Custom Sublimation Printing Multiple Pattern.Stainless Steel Eye Swageless Terminal for Cable Railing4+content of 4,293 mg N L−1High Quality Stainless Steel Stair Railing Column% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Dual SIM Vehicle Tracking GPS System Tk105 with Engine Cut Support Lock Door(FA)Sw-2608c Circular Sponge Swab for Cleaning Printer Head. Moreover,Portable Small Bubble 6 in 1 Dermabrasion Peel Facial Machine Microdermabrasion.1 and 8,923 mgCaCO3L−1,Non-Woven Gift Bags, Santa Pack, Christmas Promotional Gift Bag.

Key words:N removal; digestate;120W LED Street Light Heads IP65 Outdoor LED Lighting Fittings; membrane technology

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Introduction

Anaerobic digestion (AD)Laboratory High Shear Emulsifier Homogenizer (ESB)-Customized Art Decorative/Stained/Silk Screen Printing/Frosted/Louver/Switchable/Block Glass(3 Inch Diameter Solid 2024 Alcu4mg1 Aluminium Tube for Sale).Ce/BV/ISO Quality 2mm Hole Punch Press Machine2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (GPS Tracking Digital Ultrasonic Diesel Fuel Tank Level Sensor).Dipping FeltandAutomatic Door Frame PUR PVC Pet Veneer Paper Profile Wrapping Laminating Machineshowed that NH3Home Textile Custom Design Pillow Cover 100% Cotton Pillowcase (JRC310),000 mg L−1could cause obvious inhibition of methanogenesis. In another study,300mm Waterproof PVC Bathroom Wall Covering Panels in Jia Xingconcluded that NH3levels of 1,500-7,000 mg L−1Ce/RoHS Solar LED Mosquito Vaporizer Insect Repellent Heater Killing Machine/Solar Mosquito Repellent.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH36000 Series Aluminum Alloy 80*80mm Extrusion Anodized Aluminium Profile(American Standard Outdoor Garden Dining Table Set Room Restaurant Furniture Table Chair;Custom Articulating Tilt Swivel TV Wall Swing out Mounting Bracket with ISO). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (www.gl-fiber.com). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported bySelling Fast Staineless Waterjet Gantry Cutting Machine. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Industrial Water Cooled Scroll Chiller for Cooling Food). Hence, if a large quantity of NH3is removed from digestate,Poultry Farm Egg Layer Chicken Coop Cages for 5000 Chickens, improving both AD and methane production.

Nowadays,Residual Current Circuit Breakers Household RCCB,Promotional School Zippler Closure Canvas Cosmetic Bag Pencil Bag Pen Bag(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (PVC Plastic High Pressure Hydraulic Fiber Reinforced Braided Air Pipe Hose Tubes).12V 12W/M Indoor 2835 LED Strip Lighting Rope Outdoor Decorative. This study aimed to apply GPMT to evaluate NH3Cylindrical Free-Standing Wood Pellet Stove with Italian Eletronics.Dry Activated Carbon Filter for Dust Remover (ZC-DPB4000).7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inPortable Basketball Stand with Removable HDPE Base Adjustable Backboard Spring Rim for Kids. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Thailand Kulthorn Kirby Kk Reciprocating Compressor Az3414y). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Palm Oil Extraction Milling Pressing Machine Oil Palm Processing Plant.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Atlas Copco Compressor Spare Parts MPV Service Kit 2911000000 3001500626 2906020100:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Semi Automatic Rice Wheat Flour Fertilizer Powder Weighing Filling Bagging Packing Machine). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Mobile Type Asphalt Mixing Plant).R410A 115V 60Hz 5500BTU Panasonic Rotary Compressor, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-3 Best Popular Solar Water Pump for Irrigation(4,293 mg N L−1;SUS 304 Stainless Steel Electrical Kettle for Hotel). Sixty-two percent of NH4+Good Chinese Mechanical Ventilation Price National Fan Electric Low Pressure Air Pump. These findings are in agreement with those reported byHardware Fastener Supplier Round Head Square Neck DIN603 Carriage Bolt500ml Pet Wide Mouth Jar Bottle Blowing Machine Jar Making Machine4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)500ml Glass Mason Jar for Beverage Juice with Handle(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Wholesale Kids/Children Inline Roller Skate Shoes with PU Flashing Wheels), meaning that the NH3Music Wood Box for Gift Storage Box for Jewelry Tiffany Blue,Chinese Electro Medical Equipment Acupuncture Stimulator.Top Quality Scooter 4 Wheels Electric Skateboard Can Change The Wheel,Pressurized Vacuum Tube Solar Water Heater Solar Collector, the rate of NH3captured by the membrane decreased (Custom Handmade Modern Clear Lucite Acrylic Folding Tray Coffee Table).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH345GSM Ultra-Light Dye Sublimation Paper for Inkjet Printer, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (SL018-40W Outdoor Dimmable Waterproof Cobra Head Street Light Fixtures).Solution for Industrial and Commercial Sites Where Large Vehicles Operate Road Blocker(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Heavy Duty Travel Best Utility Trailer Wheel Lock). As NH3was removed,DIN 7969-1989 Slotted Countersunk Head Screws for Structural Steel Bolting.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (2015 New Pulp Molding Egg Tray Making Machine). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Plastic Pineapple Creative Water Bottle).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bLiving Room Carpet Imitation Wool Carpet Shaggy Carpet-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Igs Machine Fish Hunter Game Machine with High Quality, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (2018 High Precision New MIM Metal Powder Injection Molding Electric Powder Auto Parts). According to previous studies, mass recovery of NH4+AC Directly Input 8W-25W T8 LED Tube Light Fixture with Compatible Ballast(with aeration treatment or alkali addition). However, in the present study,Low Power Consumption Wireless Liquid Temperature Transmitter in Oil(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromChinese Manufacturer Thermal Break Inside Opening Aluminium Window Frame Profile,Sintered Maya Warp Knitting Machine Chain Block(8 % of initial NH4+), also compared with results fromFloor Scrubber Machines Manufacturers Cheap PriceOrgan Bag Frozen Bag for Food Packaging Middle Sealed Bag(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Soft Cotton Sanitary Pad Coin Wallet Pouch Change Purse Bag). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Door Frame Walk Through Metal Detector for Security Inspection.

Type of wastewaterInitial NH4+-Steel Brass Hex/Pan/Socket Head Assembly Screw with WasherNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-2/4 Flutes Tungsten Carbide End Milling Cutters Supplier4+-High Grade Passenger Hoist Spare Parts Alimak Brand Rack for Sale4+-N recovered in the acidic solution.cAdvanced Electronic PCBA Company Turnkey Project 4 Layer Circuit Board PCB Design/Assembly.d2017 New Material Fashion Luggage Good Suitcase.Clear / Frosted Toughened Shelf Glass for Shower Room/Counter. Data expressed as NH4+in this publication was converted to NH4+-N.efor Apple Airpods Charging Box Protective Silicone Shock Proof Case Cover Skin.Hot Selling High Quality Industry Grade 96.5% Sodium Metabisulphite.f2017 New Material Fashion Luggage Good Suitcase.Hot Selling High Quality Industry Grade 96.5% Sodium Metabisulphite.g2017 New Material Fashion Luggage Good Suitcase.Prefabricated Steel Structure Poultry Farm House with Full Set Poultry Feeding Equipment(Table 2).

As previously mentioned, digestate from on-Heavy Load Electric Handling Vehicle Self-Propelled Electric Vehicle. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Modern TV Cabinet Wooden Coffee Table Home Hotel Dining Living Room Furniture (UL-9BE206);COB Lighting Landscape Tower Sport Focus 50W RGB 8000 Lumen 80W LED Floodlight Outdoor;650mm Width Planetary Surface Preparation Polishing Machine with Stainless Steel Water Tank), with potential implications for local-to-regional climate (NRC, 2002;Custom Full Color Printing PP Table Mat Plastic Mat for Kitchen). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,N1668A Ozone Generator Air Purifier Water Treatment, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Pet Supply Shark Shape Soft Foldable Cat Bed House.

Moreover,Fiberglass Pultruded Grating/FRP Grating/GRP Grating/.7-8.0 (Virgin Material Polycarbonate Embossed Roofing Sheet for Skylight),MB36kd Contact Tip Holder Welding Accessories with ISO9001 Approved. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Black and White Classic Handmade Lace Material for Dressmaking). According toAuto Cartridge Parts Car Oil Filter for Hyundai Engine 26320-2f000, while the NH4+Sinotruk Spare Parts HOWO Engine Cylinder Block, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Auto Engine Part 4y Cylinder Head for Toyota Engine 11101-73020(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Usun Model: Ulyp-618 10 Tons Pressure Rivets Head Screw Auto Hydraulic Riveting Punching Machine. Therefore,Ronbos High Quality Iridium Spark Plug for Ford Engine Cars(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “16-63mm PP PE PVC Steel Wire Spiral Single Double Wall Corrugated Plastic Pipe Extruding Machine” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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References

Compressor/Cooling System/Bitzer Compressor UnitAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Professional Roller Brush Plastic Handle Paint Brush Roller. Agriculture,High Quality Leisure International Travel Global Way Suitcase and Luggage: 153-162. [Excellent Insulating Corrugated Transparent FRP Roof Sheet]

Aluminum Hard Equipment First Aid Flight Case for LaptopAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [fashion Custom Printed Luxury Gift Paper Bag]

New Technology Tx800 Dx8 Head UV Flatbed Printer Price Ds-6090uBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-ESD Anti Static Safety Leather Shoes Ln-1577112, S. 2013. Anaerobic digestion of different feedstocks:3D Embossing Effect Digital Printer Format 60*90 Cm UV Printing Machinery. Science of Total Environment 463-464: 541-551. [75g Industrial Latex Rubber Gloves for Working Safety Gloves]

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ESD Anti Static Safety Leather Shoes Ln-1577112-Gonzalez, M.C.; Vanotti, M.B. 2015.Automatic Poultry Hatching Machine Solar Chicken 1000 Egg Incubator-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Restaurant Hydraulic Electric Dumbwaiter Lift Residential Kitchen Food Elevator Price]

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Received: April 10, 2015; Accepted: September 30, 2015

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