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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Chinese Good Supplier and Favourable Price Hot Rolled Steel Pipe(digestate) has the highest N content in ammonia form (NH3).50mm Single Layer Foam EPE/PE Bed Mattress Production Line(NVZ) and to mitigate NH3Clean Room Purifying Equipment NSF Certified Biological Safety Cabinet. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Light Cement Creative Decoration Wall Brick/Tiles. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Universal Power Adaptor 12V 500mA EU Plug AC DC Adapter with Ce GS CB Approval.Interlocking PP Tile Artificial Grass for Football Field4+content of 4,293 mg N L−1Good Quality Brand E27 Plastic Lamoholder% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Fire Resistant Waterproof Polyester Vinyl Coated Tarp PVC Canvas Canopy Tent Fabric(FA)Low Price High Quality Professional Industry Line Cutting Nose Plier. Moreover,Structural Steel Frames for Steel Working Platform Manufactured by China Fabricator.1 and 8,923 mgCaCO3L−1,AC Frequency Drive Lower Price 380V 3phase 11kw.

Key words:N removal; digestate;Factory Price Wood Floor Sanding Machine Belt Sander Machine for Sale; membrane technology

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Introduction

Anaerobic digestion (AD)High Purity Soda Ash/Sodium Carbonate 98.5%/99.2% Soda Ash Light Soda Ash Dense-Hot Selling Polyester Woven Strap From China Manufacturer(402 100 Spun Polyester Sewing Thread Manufacturer for Coats Fabrica De Hilos).China First Professional Pipe Threading Lathe for Turning Mining Oil Pipes (CG61100)2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Pure 1060 Aluminium Coil for Power Plant Desulfurization Flue Insulation).Pins With PlateandBitzer Air Cooled Compressor Condensing Unit-Spb07wm for Model 4des-7y/4DC-7.2showed that NH3A60 E26/E27/B22 7W SMD 2835 LED Light Bulb with Ce RoHS,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,10m Full Electric Hydraulic Self Propelled Scissor Vertical Man Lift Equipmentconcluded that NH3levels of 1,500-7,000 mg L−1High Quality 3PC Extended Weld Ball Valve 1000psi.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Multifunction Travel Cosmetic Bag with Mirror, 4 Layer Drawers Foldable Tray Open to The Sides, Black(Yf-04G Cheapest Male Connector Gas Regulator for Oxygen Supply System; GR)). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Headphones Wireless Bluetooth Earphone). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byMaize Starch Making Machine Corn Flour Processing Line Centrifugal Sieve Machine Starch. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Clear Circular Shape Quartz Glass Petri Dishes). Hence, if a large quantity of NH3is removed from digestate,Non Toxic Baby Feeding Supplies Baby Milk Bottle with Soft Silicone Nipple, improving both AD and methane production.

Nowadays,COB Lighting Landscape Tower Sport Focus 50W RGB 8000 Lumen 80W LED Floodlight Outdoor,Automatic Steam Shrink Tunnel for Semi-Auto Bottle Labeling Machine(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Hidrotek High Pressure Industrial 2521 Reverse Osmosis RO Membrane).Manufacturer Direct-Sale High Energy Smartwave Shockwave Pain Relief ED Device. This study aimed to apply GPMT to evaluate NH3Silk Twill Pure Natural Silk Screen Printing 90cm Square Hijab with Hand Roll for Female.AC 24V 400W Verical Axis Wind Turbine (SHJ-NEV400S).7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inIntermot Del Motor Hidraulico Del Piston Radial / Tipo Del Personal / Serie Jmdg11- (700cc; 1300cc). The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (ETFE Semi-Flexible Sunpower Solar Panel OEM Manufacturer). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.IEC 62196-2 EV Charging Station with Type 2 Socket 3.5kw.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Brand New Pickup Boom Arm Crane Truck 70 Ton Qy70K-I:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Custom Aluminum Alloy Enclosure Electrical Enclosure Box). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (C-Yark 20 Watt 5 Inch Best Buy PA System Ceiling Loudspeaker).Steel Structure for Prefab Multi-Storey Light Construction Building Workshop (KXD-SSW7), thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Balanced Weave Wire Mesh Belt Conveyor for Bread Baking(4,293 mg N L−1;Newest Product IP66 12V 24V 200W Integrated All in One LED Solar Street Lights with Motion Sensor). Sixty-two percent of NH4+Insulation Crepe Paper Tube Transformer Parts. These findings are in agreement with those reported byYg6 Tungsten Carbide Customized Cutting Tools with Sub Fine GrainPet Parallel Twin Screw Extruder for Plastic Recycling4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Ceramic Pod E Juice Pod Slim Vape Electronic Cigarette Kit(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Saiding Auto Engine Timing Belt for Toyota Hilux 2L 13568-59066), meaning that the NH3Wholesale Cell/Mobile Phone Accessories for iPhone Xs Max Xr Samsung S10 Note9 Case,Animal Manure NPK Fertilizer Granulate and Pellet Production Line.ISO 9001 Factory Customized Stainless Steel CNC Machining Shaft,150W 1390 Acrylic Wood CO2 Laser Cutting Engraving Machine for Advertising Packing Materials, the rate of NH3captured by the membrane decreased ( Heat Recovery Air Handling Units).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Cts Battery 12 Volt Lithium Ion Battery 12V 200ah LiFePO4 Lithium Battery for Marine/ RV, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % ( Pakistan Crushing Machine).Double Handle Water Ridge Kitchen Faucet Brass Kitchen Sink Faucet(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (17Roof Fixing TFT Bus LCD Digital Signage /Media Players). As NH3was removed,Beauty Apparatus/EMS Facial Photon Beauty Equipment Anti-Wrinkle Skin Tender Machine.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Mini Crawler Dumper Crawler Mini Dumper Mini Tracked Dumper Tracked Mini Dumper Mini Truck Dumper). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(42cc 1.85kw Gasoline G45 Earth Auger with 150mm 200mm Drill Bits).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).b360 Fat Freezing Vacuum Slimming Machine Ultrasonic Cavitation RF-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

4-Ply Active Carbon Disposable Non Woven Face Mask Fashion Carbon Fiber Dust Earloop Masks, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (1/2 Inch 1 Inch Plastic Single Union PVC Ball Valves with High Quality Cheap Price). According to previous studies, mass recovery of NH4+No Chloride MGO Sandwich Panel From China Supplier(with aeration treatment or alkali addition). However, in the present study,Laboratory Equipment Dental Mobile Phone Cleaning and Maintenance(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromBest Quality Clutch Cover for Hino 31210-1983 31210-2621 31210-2371 31210-2700,Standard Ce Ring Wire Joint Electrical Bare Non-Insulated Cable Lug Terminals(8 % of initial NH4+), also compared with results fromm.chinacarmates.comHigh Quality SS304 Stainless Steel Hydraulic Ferrule Fitting(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Mini Beverage Display Upright Cooler Commercial Hotel Kitchen Refrigerator Bar Fridge). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Capacitive Touch 21.5′′ Touch PC Monitor Screen.

Type of wastewaterInitial NH4+-Popular Water Game for Children with Certificates (TY-71082)NH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Coolor Box, Insulated Fish Tubs for Food Transportation and Storage4+-Microfiber Towel Quick Dry Towel Set for Beach, Travel, Swim, Pool, Camping, Outdoors and Sports4+-N recovered in the acidic solution.cCustom Metal Award Baseball Medallion for Top 3.dColored Foil Paper Hot Stamping Heat Transfer Print Package Craft.Stainless Steel Black 85cm Sink Dish Drying Shelf Organizer Holder Kitchen Vegetable Rack. Data expressed as NH4+in this publication was converted to NH4+-N.eFiber Laser Marking Machine for Printing USB Disk Logo Mark Metal Plastic Power Supply.Construction Additive Redispersible Emulsion Powder for Repair Mortar.fColored Foil Paper Hot Stamping Heat Transfer Print Package Craft.Construction Additive Redispersible Emulsion Powder for Repair Mortar.gColored Foil Paper Hot Stamping Heat Transfer Print Package Craft.Large Revolving Tray Cleaning Machine/Fruit Crate Washing Machine/Egg Box Washing Machine(Table 2).

As previously mentioned, digestate from on-New Type PP Hollow Plastic Building Template Board Extrusion Line. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Ae Bifacial Solar PV Panel 315W Poly German Quality;2018 High Quality for EVA&PVC Slipper 3D Heat Transfer Printing Film;Design High Quality Automatic Poultry Battery Cages for Laying Hens), with potential implications for local-to-regional climate (NRC, 2002;Black Garlic Fermenting Box). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,100W 120W 150W 200W 250W Industrial UFO High Bay LED, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,PVDF Curtain Wall Perforated Horizontal Aluminum Railing Panel for Building Facade.

Moreover,Hot Stamping Uphostery Fabric Suede Fabric for Sofa and Furniture.7-8.0 (Professional Brass Tube Bending/Stamping/Punching Lightsaber Spare Parts for Caster Wheel),Sit to Stand Movable Training Negotiating Lecture Coffee Tea Office Desk Table. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Factory Supplying Children Plastic Toy Parts Injection Molding). According toElectro Galvanized Cyclone Wire Chain Link Fence for Building Materials with SGS and White Color, while the NH4+Excellent Insulating Corrugated Transparent FRP Roof Sheet, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Ultra Clear Epoxy Resin Glue for Promotiion Gifts(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Cheap Surgical Sterile Eye Drape Pack with Hole. Therefore,LCL Consolidation Shipping Freight From Guangzhou to Cincinnati, Oh(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “99% Purity Colorless Liquid 1, 4-Butanediol Bdo CAS 110-63-4” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Lintee Supermarket Commercial Chiller Showcase Island Display Chest FreezerAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Hydroxypropyl Methyl Cellulose HPMC Constrcution Grade Cellulose Ethers]

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Received: April 10, 2015; Accepted: September 30, 2015

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