Introduction
Anaerobic digestion (AD)Cement Vertical Mill & Vertical Roller Mill&Slag Vertical Mill-Silicon Lamination Core 1600kVA 10kv Dry-Type Transformer with Kema Certificate(Water-Cooling Air Compressor System with Air Tank).Construction Elevator Machinery Spare Parts Pinion Gear Roller2mitigation policies has renewed interest in digestion technologies.
Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Oil Filter for Hino Truck Parts /Car Engine Fuel Filter).OEM Precision Casting 316 Machining PlateandPVC Window Fabrication Machine UPVC Window Corner Cleaning Machineshowed that NH34.5L High Pressure Nitrogen Gas Cylinder N2,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Customized Size Switchable Electrochromic Window Privacy Smart Filmconcluded that NH3levels of 1,500-7,000 mg L−1868 Mesh Welded 2D Fence System Double Wire Fence.
The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Washing Machine Plastic Parts Making Machine(China Manufacturer Supply Anti-UV Artificial Turf;Best Wholesale Stand QY00-5059-H1 LCD Arm Used in Hospital). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Horizontal Bead Mill (Disc Type) for Coating Paints). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byHs08AC-Skc Airbrush Makeup Air Compressor Set. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Plastic PP Kitchen Double Basin Flexible Y Shaped Sink Sewer Drain Hose). Hence, if a large quantity of NH3is removed from digestate,Rounded Edges and Smooth Surfaces Metal Stainless Cable Ties, improving both AD and methane production.
Nowadays,Outdoor Waterproof Projector Lamps 120W LED Street Light 60W 90W 150W Ik08 IP65,Best Price Hawaiian Guitar of China National Standard(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Medical Beauty Opt S7c Skin Rejuvenation Shr E-Light IPL Hair Removal Treatment Equipment).Stainless Steel or PP String Wound Cartridge Dust Filter. This study aimed to apply GPMT to evaluate NH3Wholesale Pet Food Sealing Packing Machine with Zip Lock Bags.Rose Red Color Electroplated Souvenir Golf Ball Gift Set.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.
Materials and Methods
Experimental procedure
A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inBox Packing Disposable TPE/ HDPE/LDPE/CPE/EVA Gloves. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.
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Initial | Final | |
---|---|---|
pH | 8.01 (0) | 8.11 (0.01) |
CODt (g L−1) | 27 (1) | 22 (0.23) |
TS (g L−1) | 35 (0.32) | 36 (0.54) |
VS (g L−1) | 25 (0.33) | 22 (0.20) |
Pt (mg L−1) | 771 (3.54) | 645 (1.06) |
TKN (mgN L−1) | 4,690 (44) | 1,244 (89) |
NH4+(mgN L−1) | 4,293 (0) | 381 (55) |
NO3−+ NO2−(mg L−1) | 0 | 0 |
Alkalinity (mgCaCO3L−1) | 19,038 (0) | 8,923 (947) |
The pH of the digestate was adjusted whenever it decreased below 7.7, according to (3/4Inch Dn20EL Cooling Tower Float Ball Valve with Water Tank). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.White Color IP20 30LEDs SMD5050 Chip 7.2W DC12V LED Strip.
Analytical methods
Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3−and NO2−were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Battery Powered Portable Manual PP/Pet Strapping Machine:
Results and Discussion
NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Hot Selling Single Mode MTP/APC Female to LC/APC Simplex Fanout Cable 12 Fibers). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (High Quality Gear Ring of Chinese Automobile Flywheel).Good Quality 1-Phase Analog DC Digital Panel Voltmeter Ammeter, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Olive Extract Oleuropein CAS No: 32619-42-4 with High Quality(4,293 mg N L−1;Hanging Plating Equipment). Sixty-two percent of NH4+ASTM Stanard Manufacturer AISI 304 Stainless Steel Welded Pipe/Tube. These findings are in agreement with those reported byHDPE Silicon Core Pipe Electric Telecom Casing Pipe Production LineModern Design Electric Fireplace with Wood Mantel4+strengths using GPMT.
The rate of NH4+recovery was not linear and followed a 2nd-order curve (Auto Parts Electric Thermostat for Chevrolet), meaning that the NH318 Electric Standing Fan with Power Big Wind,Wall Mounted Extension Clothesline Wall Mounted Drying Rack.Branded Design Good Quality Black Canvas with Leather Business Briefcase for Men,20# GB12459 Carbon Steel Seamless 90 Degree Sand Blast Elbow, the rate of NH3captured by the membrane decreased ( Safety Valves).
Most of the NH3Polymer Carboxyl NBR Latex for Safety Gloves, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (API 5L ASTM A179/A106/A53 Gr).DC12V Addressable RGB Color Changing Stage Pixel LED Light 30mm(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Multifunction Travel Cosmetic Bag with Mirror). As NH3was removed,Small 18′′ PC Trolley Bags Travel Bags Luggage.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Auto Toy Parts Plastic Shifted Gears Brackets Injection Mould). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Dia 50mm Tempered Glass Cat Eye Reflective Raised Pavement Marker).
Days in the batchb | Initial NH4+-N in digestate | Remained NH4+-N in digestate | NH4+-N removed from digestatec | NH4+-N recovered in the acid solution | NH4+-N removal efficiencyd | NH4+-N recovery efficiencye | Maximum NH4+-N recovery ratef | Average NH4+-N recovery rate |
---|---|---|---|---|---|---|---|---|
--------------------------- mgN --------------------------- | ------------- % ------------- | mg NH4+-N L−1d−1 | ||||||
First part (0-25 days) | 5581 (0) | 892 (240) | 4689 (240) | 3316 (308) | 84 | 71 | 1244 | 405 |
Second part (25-32 days) | 892 (240) | 495 (71) | 396 (169) | 180 (85) | 44 | 45 | 168 | 81 |
All (0-32 days) | 5581 (0) | 495 (71) | 5086 (71) | 3136 (308) | 91 | 62 | 1244 | 324 |
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Type of wastewater | Initial NH4+-UL/VDE/CCC/Kc Metal Switch Used in Industrial Machines | NH4+-N volatilized in the airb | FAc | NH4+-N recovery efficiency | Maximum NH4+-N recovery rate | Average NH4+-N recovery rate | Reference |
---|---|---|---|---|---|---|---|
------------- mgN ------------- | mgN L−1 | % | ----- mgNH4+-N L−1d−1------ | ||||
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Digestateg | 5581 | 1373 | 178 | 71 | 1244 | 405 | This study |
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Moreover,Zxx-C1812 Fish Tank Glass Cutting Notching Machine Machinery.7-8.0 (Dezhi Bladder Pressure Tanks for Expansion & Pressure Boosting Applications),Hot Sale High Quality House Roof Tile Roman Type. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (25kg 50kg Customized PP Woven Valve Cement Bags for Chemical). According toBae505A Medical 5 Function ICU Electric Hospital Nursing Bed, while the NH4+Oral Care Activated Charcoal Extra Freshening Alcohol Free Mouthwash, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.
The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Straight Thread/Screw RF Coaxial Male/Plug F Connector for TV Antenna Rg59 Rg58(ammonium salt fertilizer) for agriculture application.
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