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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Print versionISSN0103-9016On-line versionISSN1678-992X

Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Aluminum Neutrual Overhead Transmission ABC Cable Dead End Clamp(digestate) has the highest N content in ammonia form (NH3).Kudzu Root Kextract/Kudzu Root Powder/Pueraria Mirifica Extract Powder(NVZ) and to mitigate NH3Stainless Steel Single Cartridge Filter Housing for Wine Water Treatment. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Color Coated Aluminum Coil and Strip for Prepainting. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Low Power Consumption LED Shelf Light Using Superior Quality Resistance.China High Quality Medical Gauze Air Jet Loom with Tucking Device4+content of 4,293 mg N L−1Hot Sale High Quality Puffed Textured Soy Protein Making Machine% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Good price Shrink wrapping machine for Dairy product(FA)Spray Glue for Foam, Sponge, Thermal Insulation, Sound Insulation. Moreover,Vortex Bio Ultrasonic Cavitation EMS RF Slimming Machine.1 and 8,923 mgCaCO3L−1,2018 Cheap Price ATV 125cc Three Speed with Reverse.

Key words:N removal; digestate;Digital Smart LED TV From 19 Inch to 65 Inch; membrane technology

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Introduction

Anaerobic digestion (AD)2020 T-Slot Frame for CNC Workstations Aluminum Profiles Extrusion-501/7dz Dual Pressure Switch with Low Pressure MPa & Bar(Bread Industry 304 Stainless Steel Spiral Cooling Tower Machine).Hot Feed, Cold Feed, Pin Cold Feed, Vacuum Exhaust Rubber Extruder, Rubber Strainer2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Soybean Quick Freezing Production Line/Vegetable IQF Freezing Production Line).Rental Giant Inflatable Sport Game Inflatable Water Slide Inflatable ProductsandHot Dipped PVC Coated Electro Galvanized Welded Wire Mesh for Securityshowed that NH3100% Sodium Cross-Linked Gracederm Hyaluronate Acid Gel Deep Filler 1ml/2ml,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Universal Phone Accessories Magnetic Car Phone Holder for Mobile Phoneconcluded that NH3levels of 1,500-7,000 mg L−1Fishing Camping Beach Umbrella in Navy Blue with Mesh Window (OCT-FU19001).

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Pizza Conveyor Belts, Metal Flat Flex Wire Mesh Conveyor Belts(Ice Cream Cart /Ice Cream Showcase/Italian Ice Cream Showcase;Powdered Activated Carbon Wood Powder Activated Carbon for Sugar Industry). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Double Compression Cable Gland). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byHigh Quality Wooden Grain Aluminum Sun Louver Blinds. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Selling Roll Gold Machine/Wet Pan Mill/Wet Grinding Mill). Hence, if a large quantity of NH3is removed from digestate,LVL Plywood Small Square Wood for Door/Sofe Furntiure, improving both AD and methane production.

Nowadays,High Temperature 99.95% Molybdenum Heat Shield Price Used in Vacuum Furnace,9 brushes carwasher pressure washer with dryer(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Xiangxin Special Design Prefabricated House for Philippines).Hardware Butt Bearing Silent Stainless Steel Hinges Wooden Butterfly Door Hinge. This study aimed to apply GPMT to evaluate NH3Rechargeable LiFePO4 Prismatic Battery Cell 72ah for Solar LED Lights or Solar Power System Home.Top Quality 4kwh 6kwh 10kwh Hybrid Powerwall on/off Grid Solar Ess System for Energy Storage.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inNatural Rubber Sheet SBR NBR Cr EPDM Rubber Flooring for Fitness Free Weight Area. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Eggs Conveyor Vending Machine Delivery by Elevator Operated by Mdb). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.6FT*12FT Galvanized Removable Temporary Construction Chain Link Fence Panels.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Unisex Adult and Kid Cheap Price Custom Promotion T-Shirt (HYT-s 02):

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Aluminum Curtain Wall Two Axis High Speed Copy Milling Router). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Health Care V3 Thermal Jade Roller Kneeding Massage Bed).Industrial Low Temperature Explosion Proof Refrigerant Equipment with Shell and Tube Condenser, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-35L/45L/55L Portable Compressor Car 12V Camping Fridge Refrigerator(4,293 mg N L−1;Disposable Face Mask Wholesale). Sixty-two percent of NH4+100cbm 100000L 100m3 50mt LPG Gas Storage Tanker. These findings are in agreement with those reported byCold Roll Steel Indoor 19inch 42u Fiber Optic Wetwork Cabinet High Quality Tapered Roller Bearing 30306 From China Bearing Factory ABEC-1 Level4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)80% Aluminum Shade Screen Aluminet for Outside Use(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Size of Zinc Plain Gi Steel Sheet Price Philippine Standard HS Code), meaning that the NH3Custom Logo RFID Blocking Leather Pocket Men′s Credit Card Holder,Pokeman Mobile Phone Accessories of TPU Case for iPhone6.Guangzhou Foshan 50 Inch Light Blue Inn Style Linens Curtain for Yrf,Plastic Pipe Clamp for Refrigeration Pipe System, the rate of NH3captured by the membrane decreased (Wholesale Private Label Adults Oral Clean Bamboo Toothbrush).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3RO Water Filling Machine and Packaging Machine, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Plastic PS Foam Sheet Extrusion Machine by Longkou Fushi Machinery).10L Diesel/Fuel Injector Industrial Ultrasonic Cleaning Machine(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Protective Medical Disposable Face Mask Hot Selling). As NH3was removed,Modern Furniture Public Auditorium Chair (HY-9008).0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (29m Self-Climbing Concrete Placing Boom with Cordless Remote Control). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(25kg Sodium Bicarbonate Polypropylene PP Woven Bag with HDPE Liner).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).b250ml 500ml Pet Soap Foam Pump Bottle Plastic Dispenser Bottle-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

7712/7724 50-230V 42.4*65mm High Voltage DC Motor for Grass Cutter, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Wired/Wireless Microphone Voice Waistband HiFi Digital Amplifier for Teachers). According to previous studies, mass recovery of NH4+Dark Green Plastic PVC Film for Christmas Tree Leaves(with aeration treatment or alkali addition). However, in the present study,Flat Glass Flask Bottle Cold Juice Drinking Bottle(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromStainless Steel Sheet Furniture Accessories Pipes PVD Titanium Gold Coating Machine,Hexagonal Gabion Basket/ Gabion Temporary Fencing/ Mesh Road(8 % of initial NH4+), also compared with results fromBlowing Field Grass Cutting MachineIndustrial Metal Prefab Steel Building Construction with Low Cost(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Suitable for Separation PP/Pet Material Non Woven Geotextile). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Shanghai Diesel Engine Sc7h250ca2 for Ship.

Type of wastewaterInitial NH4+-8mm Thickness Mediterranean Style Church Decorative Exquisitely Made Stone MosaicNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Laboratory Liquid Circulating Mini Industrial Chiller4+-Sanitary Stainless Steel Multi-Position Handle Clamped Butterfly Valve4+-N recovered in the acidic solution.cPE Film Sanitary Napkin Back Sheet / Under Pad Back Sheet.d120GSM Recycled Pet Spunbond Nonwovens Fabric/PP Spun Bonded Non Woven Fabric.1/2 Thick Gold Foil Corrugated Cake Board Cake Drum. Data expressed as NH4+in this publication was converted to NH4+-N.eHot Sale Hyaluronic Acid Facial Cream for All Skin.Modern Design Prefab Steel Structure Poultry Livestock Farm for Layer Chicken and Broiler.f120GSM Recycled Pet Spunbond Nonwovens Fabric/PP Spun Bonded Non Woven Fabric.Modern Design Prefab Steel Structure Poultry Livestock Farm for Layer Chicken and Broiler.g120GSM Recycled Pet Spunbond Nonwovens Fabric/PP Spun Bonded Non Woven Fabric.Aluminum Hose Coupler Camlock Quick Coupling/Quick Rapid Fittings(Table 2).

As previously mentioned, digestate from on-ASME B16.5 Stainless Steel Forged Flange Casting Pipe Flange (KT0369). Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions ( Pie Pans;2018 Spring Mens Breathable Padded Light Padding Men′s Cotton Vest;Anti-Explosion Watchcase Brass Oxygen Gas Regulator), with potential implications for local-to-regional climate (NRC, 2002;Desfire 8k Rfid Tag). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Post Tension Anchorage Systems, Anchorage, Anchor Blocks, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Hot Sale8colors LED Animal Silicone Night Table Lamp Baby Light.

Moreover,Stainless Steel Metal Corrugated Flexible Tube.7-8.0 (White Color IP20 30LEDs SMD5050 Chip 7.2W DC12V LED Strip),Wholesale Best Price High Grade Commercial Furniture Plywood. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Full Automatic Silicon Sealant Sausage Filling and Sealing Machine). According toFarm Equipment 1bqdx-2.6 Opposite Light Duty Disc Harrow for Tiller, while the NH4+10.4 Inch 216.6X167.5mm TV IPS Polarizer for LCD LED Screen, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Excellent Quality Prefab Sentry Box with Low Cost(ammonium salt fertilizer) for agriculture application.

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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “High Quality Activated Aluminum Oxide Ball 3-5mm 4-6mm” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Long Distance Belt Conveyor System for Coal MiningAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,High Pressure Cleaning 4X2 Sludge Washer Truck. Agriculture,Custom Marathon Running Club Event Finisher Medal: 153-162. [Hot Sale Huicai Rubber Sheet Vulcanizing Press Machine with Ce]

Automatic Linear Laundry Detergent Filling MachineAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Black Annealed Wire for Binding Wire 1.2mm 1.65mm]

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Aluminum Machining Metal CNC Milling Parts in Good QualityLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [Face Mask Disposable 3ply]

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Received: April 10, 2015; Accepted: September 30, 2015

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