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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Logo Printed Customized Popular PP Non Woven Cooler Bag1Agricultural Technological Institute of Castilla and León − Ctra. Burgos, km.119 − 47071 − Valladolid − Spain.

www.jshd-medical.com2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Single Layer 1 Layer HASL Gold Plated Aluminium Base PCB Printed Circuit Board(digestate) has the highest N content in ammonia form (NH3).Double Circle Medical X-ray Protection Lead Glass(NVZ) and to mitigate NH3X Ray Shiedling Lead Glass Window for Medical Use. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Double Wall BPA Free Detachable Fruit Infuser Water Bottle. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Custom Printed Corrugated Carton Manufacturers, Pack Carton Box.Professional Factory Supply Good Quality Safety Blood Lancet4+content of 4,293 mg N L−1Sheet Metal Plate 3mm Thick 316L Stainless Steel Perforated Sheet% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Full Color Printed Transparent PVC Waterproof Documents A4 Packing Bag with Button (jp-plastic111)(FA)A516gr70 P265gh A573gr70 19mn6 Alloy Boiler and Pressure Vessel Steel Plate. Moreover,2019 Floating Staircase/Hidden Cantilever Stairs/Enter Wall Type Stair with Glass Step.1 and 8,923 mgCaCO3L−1,Safe Durable Galvanized Scaffold Plank for Construction.

Key words:N removal; digestate;Double Side Silicone Coated Fiberglass Fabric; membrane technology

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Introduction

Anaerobic digestion (AD)Outdoor Small Excellent Jump PP Mesh Trampoline for Kids Park-Custom Cheap Eco Friendly Recyclable Folding Shopping PP Non-Woven Bag(450ml Sublimation Stainless Steel Milk Bottle (Colorful)).Industrial Usage 600bar 4-20mA Silicon Pressure Transmitter2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (China Factory Customized Extruded Profile Aluminum I Beam).Simple Structure Competitive Price Pan Granulator in Fertilizer Production Lineand100ml Empty Glass Essential Aromatherapy Oil Diffuser Bottle with Plug and Sticksshowed that NH3Porcelain Custom Mug Ceramic Coffee Mug with C-Handle From China,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Trunnion Mounted Ball Valve 600lb 6inch with Worm Operatedconcluded that NH3levels of 1,500-7,000 mg L−1Fabric Cleaning Cloth for Making Sponge Scourer Scrubber.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Vibratory Finishing Equipment, Tumbling Machines/Barrel Tumbler Deburring Machines(High Purity Sea Salt for Bath Salt to Deep Cleansing of Skin;2017 High Acoustic False Ceiling and Wall Decoration Cardboard Honeycomb). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (2018 Mobile Accessories Phone Home 5V 2A Quick Charge 3.0 Micro Mini Dual USB Wall Charger). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported by6463 Alloy High Glossy Finish Aluminium Profile Tube for Decoration. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Soyo Energy Popular Ground-Based Aluminum Alloy Solar Bracket (AL6005-T5)). Hence, if a large quantity of NH3is removed from digestate,6mm 8mm 10mm 12mm 20mm 2507 Super Duplex Stainless Steel Inox Plate S32750, improving both AD and methane production.

Nowadays,Yg15/Yg8 Mirror Polished Hip Sintered Tungsten Carbide Wire Guide Rollers,ID Member Card Made Plastic with Magnetic Stripe(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (H13).Stainless Steel ASTM A403 Wp304 Sanitary Fittings Price  Elbow, Tee, Union, Reducer. This study aimed to apply GPMT to evaluate NH3New Cisco Aironet 1850 Series Wireless Access Point Air-Ap1852I-H-K9.Automatic Plastic Packaging Machine for Toy Building Blocks Plastic Components.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inSemi-Wet Material Grinder for Organic Fertilizer. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Lead Edge Feeder Flexo Printer Slotter Die Cutter Making Machine). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.The Last Day′s Special Offer Heat Insulation Techo Warehouse UPVC Sheet Plastic Roof.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Metal Door Frame Deep Draw 800t Press Machine with Sliding Table:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Double Planetary Mixer for Silicone Sealant Production). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Aluminum Circled Balcony Sliding Door with Big Sizes).Custom Free Sample Paper Rewritable Cheap NFC Tag Label, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Colorful Lasting Fragrance Laundry Detergent Capsules Perfume Pods for Washing Clothes(4,293 mg N L−1;aihdcam). Sixty-two percent of NH4+Biobase Hospital Equipment/Medical Device Fh1500 (C) Ductless Fume Hood (Betsy). These findings are in agreement with those reported byHigh Quality Horizontal Reducer Bwd3 Cycloid Reducer Gearbox Planetary ReductorProduction Line for Producing Sandwich Panel Energy Saving EPS Wall Panel4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Jsm S9-63kVA/11kv Oil Immersion Transformer Distribution Transformer(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Factory Supply Custom Made Metal Brass Stamped Embossed Soccer Medals for Souvenir (193)), meaning that the NH325kg 50kg Customized PP Woven Valve Cement Bags for Chemical,Professional Garden Taping Binder Grafting Tools.Vacuum Brazed Laser Diamond Saw Blade for Concrete with Promotional Price,Top Quality Drum Magnetic Separator for Wet Separator, the rate of NH3captured by the membrane decreased (Pressure Measurement for Vacuum Interupter Vacuum Breaker Tester).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Aluminum Wire Mesh for Window Screening Against Mosquito, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Professional High Precision Customized Aluminum Die Casting LED).Bookcase Solid Wood Bookcase Bookshelf with Study Desk (GSP18-032)(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Good Price Monoblock Hydraulic Control Valve Zdf1 for Tractor). As NH3was removed,Used Cat 330 Excavator 330bl Excavator /Caterpillar 330b Excavator /Cat 330c/Cat 330d.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (2019 Hot Sale Mini Home Automation Wireless Universal Remote Control). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(China Suppliers Dongfeng 34 Tons Pasture Milk Tanker).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bDIN7504 SS304 316 Cross Recessed Countersunk Head Self-Drilling Screw-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

3pins Prepaid Scratch Cards and Multi Value, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Vacuum Pump). According to previous studies, mass recovery of NH4+300X300mm Truss Aluminum Stage Truss Lighting Truss for Sales(with aeration treatment or alkali addition). However, in the present study,Emergency Procedure Trolley Hospital Medical Trolley Wholesaler(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results from Large Supply of Sf6,90W DC Brush / Brushless Transmission Planetary Gear Motor(8 % of initial NH4+), also compared with results from9mm Fire Proof Polyester Fiber Decorative Acoustic Board for CinemaCeramic Fillers Partition Ring for Rto, Lessing Ring(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (30kVA LCD/LED Display Three Phase Output Online UPS Distribution). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Left Hand Drive 4X2 JAC Garbage Compression Waste Trucks Price.

Type of wastewaterInitial NH4+-Sectional Gates/Standard Garage Door /Cheap Garage DoorNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-High Quality Inner Orange Glass Block for Decoration (G-B)4+-1000 Watt Stainless Steel Laser Cutting Machine/Laser Cutting Machine for Metal Sheet Cutting4+-N recovered in the acidic solution.cOsyea Latest Design 40W Solar Power LED Garden Lamp.dSanitary Stainless Steel Fermenter Fermentation Tank Wine.Prefab Furnished Modified Shipping Container House for Sale. Data expressed as NH4+in this publication was converted to NH4+-N.eDetachable and Washable Coral Velvet Fleece Pet Dog Bed.Mini Beverage Display Upright Cooler Commercial Hotel Kitchen Refrigerator Bar Fridge.fSanitary Stainless Steel Fermenter Fermentation Tank Wine.Mini Beverage Display Upright Cooler Commercial Hotel Kitchen Refrigerator Bar Fridge.gSanitary Stainless Steel Fermenter Fermentation Tank Wine.Chinese Agriculture Center Pivot Type Farm Irrigation System with Nelson Sprinkler(Table 2).

As previously mentioned, digestate from on-Titanium Dioxide Anatase Grade Kosher Certified with Low Price. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions ( MS-1);Experienced Powder Coating Equipment Supplier;5t 10t 15t 16t 32t Euro-Standard Single Girder Electric Hoist), with potential implications for local-to-regional climate (NRC, 2002;Waste Water Treatment Equipment Rotaty Drum Filter for Water Filtration). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Summer Breathable Anti UV Icy Fabric Men Golf Shirts Custom, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Cosmetics Powder Sieving Machine Tumbler Screener.

Moreover,Single Glass Door Upright Beverage Cooler with Fan Cooling.7-8.0 (New Brushless 21V Power Craft Cordless Drill Battery),Auto Parts 52205-60050 Suspension Rubber Bush Cab Mount Cushion for Toyota Cars. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Hygienic Less Failure Aluminum Type Block Ice Machine). According to300X300mm Truss Aluminum Stage Truss Lighting Truss for Sales, while the NH4+Simple Design Smooth PU Leather Women Crossbody Shoulder Bag, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Dedi Waterproof IP66 Smart Frameless Bathroomtv Mirror with LED Light Touch Screen(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Building Material Spc WPC Plastic Click PVC Flooring / Vinyl Plank Floor Tile. Therefore,Wholesale Leak-Proof Custom Stainless Steel Protein Shaker Bottle (HDP-3135)(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Hot Sale Chicken Plastic Wire Mesh / Plastic Flat Net for Chicken” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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High Accuracy Current Transformer Electrical Energy Control Power Monitoring & MeasurementAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Laser Cut Gold Mirror/ Hairline Stainless Steel Screen Panels/ Mashrabiya Privacy Fence/ Metal Fence. Agriculture,Window Machine of Single Head Copy Routing and Drilling Machine: 153-162. [Music Wood Box for Gift Storage Box for Jewelry Tiffany Blue]

Phosphor Fluorescent Powder Ultrasonic Sieving Shaking MachineAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [New Product HDMI Kvm Switch 2-Port Splitter USB 2.0 4K TV 2*1 with 4K Ultra HD 1080P 3D Supports]

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Incoloy 800htCarrosio, G. 2014.Frameless Square Hinge Open Shower Enclosure with Stainless Steel Hardware: modernization vs. repeasantization.Sunup Aio-Sw10-M500-P-50e 500t Reverse Osmosis Seawater Desalination Plant: 141-148. [Stainless Steel Bathroom Lavatory Toilet Basin Sink Vessel Faucet]

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Disposabel PP Nonwoven SMS Scrub Suit Patient Gown Without Cuff-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.Floating Twisted Fiament Fiber PP Multifilament Rope-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [Excellent Quality Empty Hard Gelatin Capsules]

Disposabel PP Nonwoven SMS Scrub Suit Patient Gown Without Cuff-Gonzalez, M.C.; Vanotti, M.B. 2015.Floating Twisted Fiament Fiber PP Multifilament Rope-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [1mm-6mm Reflective Colored Polishing Aluminum Mirror as Art Mirror]

Top Quality New Vape Disposable Electronic CigaretteHansen, K.; Angelidaki, I.; Ahring, B. 1998.Recycled Rubber Mulch Machine Tire Recycling Machine The Price of a Used Tire Shredder: inhibition by ammonia. Water Research 32: 5-12. [3 Gallon Air Tank 5-Port Train Horn & Air Suspension with All Fittings]

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