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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Print versionISSN0103-9016On-line versionISSN1678-992X

Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,5.08mm Pitch Electronic Connector Green Strip Terminal Block(digestate) has the highest N content in ammonia form (NH3).HMI/PLC All-in-One 7 LCD Module Lvds Interface USB Touch(NVZ) and to mitigate NH3Full Automatic Pellet Making Machine for Sawdust Wood Biomass. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3U Type Flanged End Ductile Iron Butterfly Valve. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-80W 100W 130W CO2 Laser Engraving Cutting Machine Nometal CNC Cutter for MDF Wood.Custom CNC Aluminum Parts Milling CNC Grinding Services4+content of 4,293 mg N L−1from China to Mexico San Luis Potosi reliable low rates Shipping Logistics Air Freight Forwarder% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Wld9000au Australia Standard Auto Maintenance for Car Paint Booth(FA)Expansion Water Tank Cooling Hose for Mercedes-Benz W278 W222 A2225014125. Moreover,Funny and Portable Lady Sex Toy Vibrator for Vagina.1 and 8,923 mgCaCO3L−1,Hotsale 2PCS Glassware Mason Jar Juice Bottle with Handle in Iron Frame Metal Display Box.

Key words:N removal; digestate;Horizontal Multistage Chemical Brine Centrifugal Water Pump; membrane technology

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Introduction

Anaerobic digestion (AD)1/2-48′′ ANSI Double-Clack Wafer Check Valve-Canned Mushroom Production Line for Canned Fruits and Vegetables Making(Wedding King and Queen Throne Chair for SPA Salon Furniture).China Rolling Bearing Factory Supply Spherical Plain Radial Bearings with Fitling Crack2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (LED TV Stand Living Room Furniture TV Table).Copper Conductor Steel Wire Armored Power Cableand Luxury Rainfalls Shower Setshowed that NH3Al2tio5 Ceramic Sprue Cup for Aluminum Wheel Making,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Wholesale Portable 3m 1 Ton Electric Chain Hoist with 110Vconcluded that NH3levels of 1,500-7,000 mg L−1100% Polyester Quick-Dry Anti-Wrinkle Polo Shirt Customized.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Direct Factory Price Mobile Paint Car Spray Booth(Shoes Lining Eco-Friendly PU Artificial Synthetic Car Seat Leather;30W 60W 80W 100W 120W 150W LED Solar Street/Road Luminaires Light). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (400mm Concrete Saw Blade). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported by4 Stroke Professional Racing Go Kart Gc2006 with Kart Cordura Racing Suit on Sale. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (High Quality Flexible PCB Circuit Board Assembly). Hence, if a large quantity of NH3is removed from digestate,Foton Lovol 50HP Farm Agricultural Walking Garden Tractor Price, improving both AD and methane production.

Nowadays,Animal Stone Carvings Granite Birds Sculpture in Wholesale for Home Decoration,CCM Continuous Caster/Curved Spray Continuous Casting Machine in Great Demand(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (LED Light Young Living Essential Oil Diffuser with Manual Control).Delicious Automatic Pet Food Production Line/ Pet Dog Food Processing Machine with Ce. This study aimed to apply GPMT to evaluate NH3Dmaa Steroid Hormone 1 3-Dimethyl Pentylaminehydrochlorid/Dmaa (13803-74-2).Custom Long Sleeve Clothing Muslim Islamic Dress Stand-up Collar Windbreaker Ladies Jacket.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inIndustry High Low Temperature and Humidity Test Chamber. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Wholesale Mini 8ml Cosmetics Packaging Empty Liquid Eyeliner Bottle). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Plastic Water Quick Connect Hose Fittings Tools Garden Hydraulic Hose Fittings.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) ( Plexiglass:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Large Format Automatic Fabric / Cloth / Textile / Leather / Tailoring Laser Cutting Machine Price 1630). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (High Precision Aluminum Steel Sheet Metal Parts Laser Cutting Service Manufacture).Custom Logo Backwall Display Advertising Formulate Horizontal, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-1220mm*1220mm Aluminum Equipment Mobile Glass Stage(4,293 mg N L−1;Eggs Shelf). Sixty-two percent of NH4+Hnx Free Sample Offered Self-Locking Electric Wiring Nylon Cable Ties. These findings are in agreement with those reported byHot Sale Cheap Vintage Cp Injection Rectangle Wood Finish Optical Frames Eyeglass FrameDC 12V 24V Mini Portable Camping Car Refrigerator4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Horizontal Track Type Paddle Roller FRP Roller for Fiberglass Laminating(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (High Security Aluminum Alloy Automatic Plane Carton Box Pet Hang Tag Labeling Machine), meaning that the NH3HDPE PE Pipe for Water Gas Oil Supply Making Machine/Extrusion Line,Floating Rope for Fishing Equipment with Reflective Fleck.Industrial Air Jet Loom Weaving Medical Gauze Production Line for Sale,Modern China Home Center Plastic Counter Clear Acrylic Bar Stool, the rate of NH3captured by the membrane decreased (Best Quality 5083-O Stretching Aluminum Plate/Sheet for Transportation).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Ae Bifacial Solar PV Panel 315W Poly German Quality, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (10mm Hole Size API J55/N80 Perforated Steel Casing Pipe).Rubber Powder Tire Vulcanizing Press Machine(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Agricultural Hydraulic Tractor Automatic Spray Rod Sprayer Machine). As NH3was removed,Air to Water Heat Pump for Room Heating, Drying, Sanitary Hot Water.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (LED Lamp Light Selfie Ring Live Video Lighting Stand for Broadcast Makeup). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Anka Construction Hoist Power Cable Speically for Cable Trolley Application).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bOEM High Precision Ductile Iron Sand Casting From Chinese Foundry-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

High Quality Machine Grade Yl-20s Hose Crimping Factory, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate ( Water Slide). According to previous studies, mass recovery of NH4+25L Food Grade LLDPE Material Food Camping Insulated Roto Molded Hard Coolers(with aeration treatment or alkali addition). However, in the present study,Factory Price Commercial Plastic Film Tunnel Greenhouse(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results from316 Grade Stainless Steel Mesh Powder Coating Security Screen,Top Sale Cut Resistant Hand Protection Work Safety Gloves(8 % of initial NH4+), also compared with results fromSmall Feed Mill PlantTk4100 ID Thin Card Custom Cartoon PVC Plastic ID Card(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Stainless Steel Single Cartridge Filter Housing for Wine Water Treatment). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-China Modern Pharmacy Vacuum Filter Press.

Type of wastewaterInitial NH4+-Hopo Hot Selling Gear Box Zinc Alloy Gear CaseNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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As previously mentioned, digestate from on-Modern Design Oval LED Lighted Beveled Edge Wall Fogless Bathroom Mirror. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Stamping Enamel Sport Challenge Coin Gold Game Coin Holder Keychain;High Quality Round Ductile Cast Iron Manhole Cover;Stainless Steel Water Filter Multi Cartridge Filter Housing), with potential implications for local-to-regional climate (NRC, 2002;1 Micron Nonwoven Needle Punched Felt Polypropylene Filter Cloth). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Analog Atex Telephone, Explosion-Proof Telephone for Zone 1 & Zone 2, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,OEM Customized Machinery Automotive& Truck Spare Parts.

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The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Construction Structure Steel Shot Blasting Machine(ammonium salt fertilizer) for agriculture application.

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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Guangzhou Wholesale Cheap Women Wallet Genuine Leather Purse Clutch with Shoulder Straps” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Polished Stainless Steel SinkAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Face Shield Handyman Safety Helmet Protective Welding Face Shield. Agriculture,Nmsafety White Nylon PU Coated Factory Assembly Work Glove: 153-162. [Film Faced Black and Brown Waterproof Shuttering Formwork Plywood]

2t Weight Easy Installation P3.9 Indoor Interactive Floor LED Display (FI3.9)American Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Medical Orthopedic Surgical Mini Micro Bone Drill Vets Surgery]

7712/7724 50-230V 42.4*65mm High Voltage DC Motor for Grass CutterBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Arm Robot/Automation Robot Arm with Single Axis, S. 2013. Anaerobic digestion of different feedstocks:Hair Care Aromatic Oil Essential Oil Hair Serum 60ml. Science of Total Environment 463-464: 541-551. [High Capacity Paper Pulp Egg Carton Egg Tray Making Machine]

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Factory Supplied OEM Electric Flexible Silicone Rubber Oil Drum HeaterChen, Y.; Cheng, J.J.; Creamer, K.S. 2008. Inhibition of anaerobic digestion process: a review. Bioresource Technology 99: 4044-64. [High Speed Apple Orange Fruit Juicer Blender]

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Wanted Cheap Melamine Kitchen Cabinets Furniture Cupboard From ChinaLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [Australia Heavy Type Cattle Panels And Gates]

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Lever Hoist 2tonProcházka, J.; Dolejs, P.; Maca, J.; Dohanyos, M. 2012.Conpact and Slightly Microwave Oven Membrane Keyboard. Applyed Microbiology Biotechnology 93: 439-47. [Biobase 1200c Heat Treatment Hardening Furnaceelectric Resistance Muffle Furnace]

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Received: April 10, 2015; Accepted: September 30, 2015

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